Cetyltrimethylammonium Bromide Capped 9-Anthraldehyde Nanoparticles for Selective Recognition of Phosphate Anion in Aqueous Solution Based on Fluorescence Quenching and Application for Analysis of Chloroquine

2014 ◽  
Vol 25 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Prasad G. Mahajan ◽  
Netaji K. Desai ◽  
Dattatray K. Dalavi ◽  
Dhanaji. P. Bhopate ◽  
Govind B. Kolekar ◽  
...  
The Analyst ◽  
2018 ◽  
Vol 143 (20) ◽  
pp. 4870-4886 ◽  
Author(s):  
Jingwen Xiong ◽  
Zongzhi Li ◽  
Jihua Tan ◽  
Shaomin Ji ◽  
Jianwei Sun ◽  
...  

Two novel highly selective quinoline-based fluorescent probes with an aggregation induced emission (AIE) feature are used for rapid analysis of Cu2+ in aqueous media and on paper strips with a fluorescence quenching mechanism.


Chemosensors ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 65
Author(s):  
Minji Lee ◽  
Donghwan Choe ◽  
Soyoung Park ◽  
Hyeongjin Kim ◽  
Soomin Jeong ◽  
...  

A novel thiosemicarbazide-based fluorescent sensor (AFC) was developed. It was successfully applied to detect hypochlorite (ClO−) with fluorescence quenching in bis-tris buffer. The limit of detection of AFC for ClO− was analyzed to be 58.7 μM. Importantly, AFC could be employed as an efficient and practical fluorescent sensor for ClO− in water sample and zebrafish. Moreover, AFC showed a marked selectivity to ClO− over varied competitive analytes with reactive oxygen species. The detection process of AFC to ClO− was illustrated by UV–visible and fluorescent spectroscopy and electrospray ionization–mass spectrometry (ESI–MS).


Langmuir ◽  
2011 ◽  
Vol 27 (10) ◽  
pp. 6091-6098 ◽  
Author(s):  
Shuqing Wu ◽  
Liu Shi ◽  
Lucas B. Garfield ◽  
Rico F. Tabor ◽  
Alberto Striolo ◽  
...  

1982 ◽  
Vol 35 (7) ◽  
pp. 1357 ◽  
Author(s):  
TJ Broxton

The hydrolysis of 2-acetyloxybenzoic acid in the pH range 6-12 has been studied in the presence of micelles of cetyltrimethylammonium bromide (ctab) and cetylpyridinium chloride (cpc). In the plateau region (pH 6-8) the hydrolysis is inhibited by the presence of micelles, while in the region where the normal BAC2 hydrolysis (pH > 9) occurs the reaction is catalysed by micelles of ctab and cpc. The mechanism of hydrolysis in the plateau region is shown to involve general base catalysis by the adjacent ionized carboxy group both in the presence and absence of micelles. This reaction is inhibited in the presence of micelles because the substrate molecules are solubilized into the micelle and water is less available in this environment than in normal aqueous solution.


2018 ◽  
Vol 96 (4) ◽  
pp. 363-370 ◽  
Author(s):  
You-Ming Zhang ◽  
Xiao-Peng Chen ◽  
Guo-Yan Liang ◽  
Kai-Peng Zhong ◽  
Hong Yao ◽  
...  

The selective recognition of target ions in water is very important and the development of novel water-soluble chemosensor is still an intriguing challenge. Herein, a novel water-soluble fluorescent sensor based on aspartic acid (Asp) functionalized 1,8-naphthalimide derivative (Asp-NI) has been designed and synthesized. The sensor Asp-NI could dissolve in water and successively detect Fe3+ and H2PO4− in water solution with high selectivity and sensitivity. The detection limits are 4.97 × 10−7 mol/L for Fe3+ and 5.27 × 10−6 mol/L for H2PO4−. Other coexistent competitive metal ions (Hg2+, Ag+, Ca2+, Cu2+, Co2+, Ni2+, Cd2+, Pb2+, Zn2+, Cr3+, and Mg2+) showed no interference in the Fe3+ detection process. The sensor Asp-NI could act as a Fe3+ and H2PO4− controlled “On–Off–On” fluorescent switch. More interestingly, the Fe3+ induced fluorescence quenching process could be totally reversed by the addition of H2PO4−, this “On–Off–On” switching process could be repeated several times with little fluorescence loss. Notably, the actual usage of sensor Asp-NI was further demonstrated by test kits.


1997 ◽  
Vol 13 (08) ◽  
pp. 747-751
Author(s):  
Lin Li-Rong ◽  
◽  
Jiang Yun-Bao ◽  
Huang Xian-Zhi ◽  
Chen Guo-Zhen

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