Effect of sodium hydroxide and sodium silicate solutions on strengths of alkali activated high calcium fly ash containing Portland cement

2016 ◽  
Vol 21 (6) ◽  
pp. 2202-2210 ◽  
Author(s):  
Tanakorn Phoo-ngernkham ◽  
Sakonwan Hanjitsuwan ◽  
Nattapong Damrongwiriyanupap ◽  
Prinya Chindaprasirt
2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Ganesan Lavanya ◽  
Josephraj Jegan

This study presents an investigation into the durability of geopolymer concrete prepared using high calcium fly ash along with alkaline activators when exposed to 2% solution of sulfuric acid and 5% magnesium sulphate for up to 45 days. The durability was also assessed by measuring water absorption and sorptivity. Ordinary Portland cement concrete was also prepared as control concrete. The grades chosen for the investigation were M20, M40, and M60. The alkaline solution used for present study is the combination of sodium silicate and sodium hydroxide solution with the ratio of 2.50. The molarity of sodium hydroxide was fixed as 12. The test specimens were150×150×150 mm cubes,100×200 mm cylinders, and100×50 mm discs cured at ambient temperature. Surface deterioration, density, and strength over a period of 14, 28, and 45 days were observed. The results of geopolymer and ordinary Portland cement concrete were compared and discussed. After 45 days of exposure to the magnesium sulfate solution, the reduction in strength was up to 12% for geopolymer concrete and up to 25% for ordinary Portland cement concrete. After the same period of exposure to the sulphuric acid solution, the compressive strength decrease was up to 20% for geopolymer concrete and up to 28% for ordinary Portland cement concrete.


2018 ◽  
Vol 10 (10) ◽  
pp. 3538 ◽  
Author(s):  
Sol Park ◽  
Hammad Khalid ◽  
Joon Seo ◽  
Hyun Yoon ◽  
Hyeong Son ◽  
...  

The present study investigated geopolymerization in alkali-activated fly ash under elevated pressure conditions. The fly ash was activated using either sodium hydroxide or a combination of sodium silicate solution and sodium hydroxide, and was cured at 120 °C at a pressure of 0.22 MPa for the first 24 h. The pressure-induced evolution of the binder gel in the alkali-activated fly ash was investigated by employing synchrotron X-ray diffraction and solid-state 29Si and 27Al MAS NMR spectroscopy. The results showed that the reactivity of the raw fly ash and the growth of the zeolite crystals were significantly enhanced in the samples activated with sodium hydroxide. In contrast, the effects of the elevated pressure conditions were found to be less apparent in the samples activated with the sodium silicate solution. These results may have important implications for the binder design of geopolymers, since the crystallization of geopolymers relates highly to its long-term properties and functionality.


2015 ◽  
Vol 27 (5) ◽  
pp. 04014158 ◽  
Author(s):  
Patimapon Sukmak ◽  
Pre De Silva ◽  
Suksun Horpibulsuk ◽  
Prinya Chindaprasirt

2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Fotini Kesikidou ◽  
Stavroula Konopisi ◽  
Eleftherios K. Anastasiou

This study investigated the use of concrete sludge, a by-product of the ready-mix concrete industry, in combination with high-calcium fly ash in binary cementless binders. Concrete sludge was used in substitution rates ranging from 0% to 60% in test fly ash-based mortars to determine potential synergy. The mortars were tested for fresh and hardened properties; workability, viscosity, strength development, open porosity, early-age shrinkage, and analytical tests were carried out. A mortar with 50% fly ash and 50% limestone filler as binders was used for comparison purposes. Furthermore, a series of mortars with fly ash and concrete sludge were alkali-activated in order to determine potential strength gain. In the activated mortars, two fractions of concrete sludge were used, under 75 μm and 200 μm, due to different silicon oxide contents, while one mortar was cured at 40°C to investigate the effect of heating on alkali activation. Results show that sludge contributes to the formation of C-S-H and strength development when used in combination with high-calcium fly ash even at high replacement rates. The alkali activation of fly ash-concrete sludge system contributed to early-age strength development and to early-age shrinkage reduction.


2020 ◽  
Vol 841 ◽  
pp. 9-13
Author(s):  
Teewara Suwan ◽  
Peerapong Jitsangiam ◽  
Prinya Chindaprasirt

Nanotechnology is receiving widespread attention in many industrial sectors, including construction material industry. One of the nano-scale admixtures, which has the potential to enhance the performance of cement and concrete, is known as Nano-silica (n-SiO2). In general, fly ash (FA) is currently used in cement and concrete industry for replacing the consumption of Portland cement (OPC) to reduce its production cost as well as to improve some specific required properties, e.g., workability or low internal heat liberation. However, the strength of hardened Portland cement is normally decreased when a higher amount of fly ash is presented. This research article is therefore pointed on the influence of nano-silica dosage on the properties of cement paste incorporating with high calcium fly ash. Seven different proportions of OPC:FA were prepared viz. 100:0, 80:20, 60:40, 50:50, 40:60, 20:80 and 0:100 by weight. The commercial grade nano-silica (in liquid form) was used as an admixture in those mixes by 0.0, 0.5, 1.0 and 1.5 wt% of the mixing water with a water-to-binder (w/b) ratio of 0.30. The results indicated that the addition of n-SiO2 improved the compressive strength of all mixtures (with and without high calcium FA) as the presence of n-SiO2 can be a source of silica and easily contribute to an additional formation of CSH in the cementing system, confirmed by the results of XRD analysis. The main findings show a potential approach of using n-SiO2 as an admixture for cement and concrete construction.


2015 ◽  
Vol 1103 ◽  
pp. 29-36 ◽  
Author(s):  
Prinya Chindaprasirt ◽  
Kiatsuda Somna

This research aims to study the effect of addition of microsilica and nanoalumina on compressive strength and products of high calcium fly ash geopolymer with low NaOH concentration. Microsilica and nanoalumina were added in the mixture in order to adjust the Si/Al ratios which resulted in the change of product form of geopolymer pastes. Geopolymer was synthesized using high calcium fly ash and 2 molar sodium hydroxide (NaOH). Microsilica and/or nanoalumina were added as additional sources of silica and alumina in the mixtures. Compressive strengths of pastes were investigated at the age of 7, 28 and 60 days. The products of geopolymer pastes were characterized by FTIR and salicylic acid with methanol (SAM leaching test). The results showed that the mix (2Si10Al0) with additional 10% of microsilica gave the highest compressive strength of 14 MPa at the age of 60 days. The products of geopolymer pastes were CSH gel, CASH gel, NASH gel and zeolite which were characterized by FTIR and SAM leaching test.


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