Immobilization of Cr (VI) in stainless steel slag and Cd, As, and Pb in wastewater using blast furnace slag via a hydrothermal treatment

2017 ◽  
Vol 23 (3) ◽  
pp. 576-581 ◽  
Author(s):  
Soon-Jae Tae ◽  
Kazuki Morita
Keyword(s):  
Stainless Steel ◽  
Blast Furnace ◽  
Hydrothermal Treatment ◽  
Blast Furnace Slag ◽  
Steel Slag ◽  
Stainless Steel Slag ◽  
Furnace Slag

scholarly journals Property Comparison of Alkali-Activated Carbon Steel Slag (CSS) and Stainless Steel Slag (SSS) and Role of Blast Furnace Slag (BFS) Chemical Composition

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3307 ◽  
Author(s):  
Jinyan Liu ◽  
Cheng Yi ◽  
Hongguang Zhu ◽  
Hongqiang Ma
Keyword(s):  
Stainless Steel ◽  
Blast Furnace ◽  
Activated Carbon ◽  
Carbon Steel ◽  
Blast Furnace Slag ◽  
Steel Slag ◽  
Stainless Steel Slag ◽  
Solid Ratio ◽  
Furnace Slag ◽  
Alkali Activated

In order to compare the properties of alkali-activated carbon steel slag (CSS) and stainless steel slag (SSS), the effects of sodium hydroxide/sodium silicate solution mass ratio (NH/NS), liquid/solid ratio and blast furnace slag (BFS) dosage on the compressive strength, hydration products and hydration degree of CSS and SSS were studied. Furthermore, a combination of X-ray diffraction (XRD), thermo-gravimetric analysis coupled with differential thermal analysis (TGA-DTA), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscope-energy dispersive spectrometer (SEM-EDS) were used to characterize the morphology and structure of alkali-activated CSS-BFS and SSS-BFS cementitious materials. As the results revealed, the primary hydrate of alkali-activated CSS and SSS is C-(A)-S-H with Q2 [SiO4] units, which has a low Ca/Si ratio and includes inert phases like a CaO-FeO-MnO-MgO solid solution (RO) in CSS while cuspidine, magnesiochromite etc. in SSS. More active C3S and β-C2S promote the alkali activation of CSS, whereas the less active γ-C2S hinders the depolymerization of SSS. The incorporation of BFS does not change the hydrate, whose seed effect is helpful for accelerating the depolymerization and polycondensation of CSS and SSS, especially for SSS, and makes the hydrate increase significantly. Owing to the high SiO2 and Al2O3 contents of SSS, the C-(A)-S-H chain length is increased, thus facilitating the polycondensation effect. In this study, the optimal NH/NS of CSS and SSS is NH/NS= 1:2, and the optimal liquid/solid ratio is 0.29. Compared to CSS–BFS, the C-(A)-S-H gel produced by SSS–BFS has lower Ca/Si and Al/Si ratios. Unlike CSS, pure SSS is inappropriate as an alkali-activated precursor and needs to be co-activated with BFS.

scholarly journals Concrete Properties Comparison When Substituting a 25% Cement with Slag from Different Provenances

2018 ◽  
Author(s):  
María Eugenia Parrón-Rubio ◽  
María Dolores Rubio-Cintas ◽  
Francisca Pérez-García ◽  
Antonio Gonzalez-Herrera
Keyword(s):  
Blast Furnace ◽  
Environmental Sustainability ◽  
Blast Furnace Slag ◽  
Construction Material ◽  
Steel Slag ◽  
High Energy ◽  
Stainless Steel Slag ◽  
Concrete Properties ◽  
Furnace Slag ◽  
By Products

Concrete consumption greatly exceeds the use of any other material in engineering. This is due to its good properties as construction material and the availability of its components. Nevertheless, the present worldwide construction increase and the high-energy consumption for cement production means a high environmental impact. On the other hand, one of the main problem in iron and steel industry is waste generation and by-products that must be properly processed or reused to promote the environmental sustainability. One of these by-products are blast furnace slag. Cement substitution by slag strategy achieves two goals, raw materials consumption reduction and waste management. In the present work, four different concrete mixtures are evaluated. 25% cement is substituted by different blast furnace slag. Tests are made to evaluate the advantages and drawbacks of each mixture. Depending on the origin, characteristics and treatment of the slag, concrete properties change. Certain mixtures provide proper concrete properties. Stainless steel slag produces a fluent mortar that reduces the water consumption whit a slight mechanical strength loss. Mixture with electric arc slag furnace properties are better to the reference concrete (without slag) when slag is treated similarly to the cement.

scholarly journals Synergistic Excitation Mechanism of CaO-SiO2-Al2O3-SO3 Quaternary Active Cementitious System

2021 ◽  
Vol 8 ◽  
Author(s):  
Fusheng Niu ◽  
Yukun An ◽  
Jinxia Zhang ◽  
Wen Chen ◽  
Shengtao He
Keyword(s):  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Steel Slag ◽  
Cementitious Materials ◽  
Test Block ◽  
Hydration Reaction ◽  
Alkaline Environment ◽  
Granulated Blast Furnace Slag ◽  
Cementitious System ◽  
Furnace Slag

In this study, the influence of steel slag (SS) content on the strength of the cementitious materials was investigated. The quaternary active cementitious material (CaO-SiO2-Al2O3-SO3) was prepared using various proportions of steel slag (SS), granulated blast furnace slag (BFS), and desulfurized gypsum (DG). The mechanism of synergistic excitation hydration of the cementitious materials was examined using various techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectrometry (FTIR). The strength of the mortar test block was initially increased and decreased later with the increase of the SS content. Mortar test block with 20% steel slag, 65% granulated blast furnace slag, and 15% desulfurized gypsum with 0.35 water-binder ratio showed the highest compressive strength of 57.3 MPa on 28 days. The free calcium oxide (f-CaO) in the SS reacted with water and produced calcium hydroxide (Ca(OH)2) which created an alkaline environment. Under the alkaline environment, the alkali-activated reaction occurred with BFS. In the early stage of hydration reaction, calcium silicate hydrate (C-S-H) gel and fibrous hydration product ettringite (AFt) crystals were formed, which provided early strength to the cementitious materials. As the hydration reaction progressed, the interlocked growth of C-S-H gel and AFt crystals continued and promoted the increase of the strength of the cementitious system.

Study on Sulfate Resistance of Concrete with Compound Mineral Admixture

2011 ◽  
Vol 99-100 ◽  
pp. 420-425 ◽  
Author(s):  
Qian Rong Yang ◽  
Xiao Qian Wang ◽  
Hui Ji
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Steel Slag ◽  
Sulfate Attack ◽  
Mineral Admixture ◽  
Sulfate Resistance ◽  
Chemical Attack ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

The strength, expansion and amount of scaling of concrete with compound mineral admixture (CMA) from steel slag, granulated blast furnace slag and fly ash were studied. The result shows that damage by crystallization press from sulfate attack when concrete was exposed to sulfate environments under wetting–drying alternation is much larger than that from sulfate chemical attack. Adding CMA to concrete could reduce the damage from expansion of concrete caused by sulfate chemical attack, but the resistance of concrete to damage by crystallization press from sulfate attack was remarkably reduced.

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