scholarly journals Characterization of a bonding method for titanium-glass sealing

2020 ◽  
Vol 2 (12) ◽  
Author(s):  
Sebastian Winkler ◽  
Jan Edelmann ◽  
Andreas Schubert
Keyword(s):  
Bond Strength ◽  
Process Parameters ◽  
Medical Implants ◽  
Good Adherence ◽  
Low Leakage ◽  
Gas Leak ◽  
Bond Strengths ◽  
Bonding Method ◽  
Tensile Bond Strengths

AbstractApplications for smart medical implants require hermetic and mechanically strong seals between functional and biocompatible materials. Hermetic seals between titanium Ti6Al4V and silica-based glass can be produced using a novel bonding method based on glass pressing at temperatures around the softening point. This paper presents investigation results for the tensile bond strength and the gas leak rate depending on the manufacturing process parameters. Notably, when using blasted surfaces, the tensile bond strengths reached 12 MPa and good adherence with very low leakage due to the removed oxide layer and surface structure. The interface is analyzed and characterized by applying SEM methods related to the different adhesion mechanisms.

scholarly journals Shear and tensile bond strengths of autoclaved aerated concrete (AAC) masonry with different mortar mixtures and thicknesses

2021 ◽  
Vol 1 (1) ◽  
pp. 20-31
Author(s):  
Raghav Tandon ◽  
Sanjeev Maharjan ◽  
Suraj Gautam
Keyword(s):  
Bond Strength ◽  
Shear Bond Strength ◽  
Tensile Bond Strength ◽  
Cement Slurry ◽  
Interface Shear ◽  
Autoclaved Aerated Concrete ◽  
Bond Strengths ◽  
Aerated Concrete ◽  
Tensile Bond Strengths ◽  
Maximum Shear Strength

Autoclaved aerated concrete (AAC) blocks are commonly used for masonry walls. In order to understand the strength of AAC masonry, it is essential to assess the tensile and shear bond strengths of the AAC block-mortar interface for various mortar combinations. This research investigates the bond strength of AAC block mortar interface made up of a) polymer modified mortar (PMM) and b) ordinary cement sand mortar of 1:4 or 1:6 ratio with thickness of 10mm, 15mm or 20mm. A thin cement slurry coating was applied on the block surface before placing the cement sand mortar in the masonry. For all types of interface, shear bond strength of masonry was studied using a triplet test, while the tensile bond strength was determined through a cross-couplet test. Among the cement sand mortar used in this study, cement sand mortar of ratio 1:4 and thickness 15mm showed the maximum shear strength of 0.13MPa with the failure of blocks as the predominant failure while the PMM had shear bond strength of 0.12MPa with the failure of blocks as the predominant failure type. However, in case of the tensile bond strength testing, PMM showed the tensile bond strength of 0.19MPa, which was highest among all the test specimens used in this study. Considering both the tensile and shear bond strengths of the AAC masonry and based on the observed failure pattern, among all the combinations used in the experiment, either PMM or cement-sand mortar of ratio 1:4 and thickness of 15mm can be chosen for the AAC masonry.

scholarly journals Etching Patterns of Self-Etching Primers in Relation to Shear Bond Strength on Unground Enamel Samples

2021 ◽  
Vol 9 (11) ◽  
pp. 138
Author(s):  
Lorenz Brauchli ◽  
Markus Steineck
Keyword(s):  
Electron Microscopy ◽  
Shear Strength ◽  
Statistical Analysis ◽  
Bond Strength ◽  
Correlation Coefficient ◽  
Shear Bond Strength ◽  
Strength Testing ◽  
Post Test ◽  
Bond Strengths

It was the intention of the study to evaluate the etching effects of several self-etching primers on unground enamel and their relevance for shear bond strength testing. Seven self-etching primers (Clearfil SE, Futurabond NR, M-Bond, One Coat, Optibond, Transbond SEP+, Xeno III) and a conventional 35% phosphoric gel acid were applied to bovine incisors according to the manufacturer’s instructions. All specimens were analyzed by electron microscopy. A visual four-step grading was used for the characterization of the macroscopic (5000×) and microscopic (20,000×) etching patterns. In addition, shear bond strength for all the products was tested with an Instron 3344 after 1000 thermocycles between 5 °C and 55 °C. Statistical analysis was carried out using Kruskal–Wallis with Dunn’s post-test and Pearson’s correlation coefficient. Very strong etching patterns with well-defined prisms were found for the conventional etching, Transbond SEP+, and to a lesser degree, for Xeno III. Clearfil SE and Futurabond NR revealed moderate etching patterns, and M-Bond, One Coat, and Optibond revealed very weak etching patterns. The bond strength correlated well with the etching patterns. The highest shear strength was obtained with conventional etching and Transbond SEP+, followed by Clearfil SE. Moderate shear bond strengths were found for Xeno III, Futurabond NR, One Coat, and M-Bond, and the lowest were found with Optibond.

scholarly journals Analytical Investigation on the Effect of Test Setup on Bond Strength

CivilEng ◽  
2021 ◽  
Vol 2 (1) ◽  
pp. 14-34
Author(s):  
Konstantinos Tsiotsias ◽  
Stavroula J. Pantazopoulou
Keyword(s):  
Bond Strength ◽  
Pullout Test ◽  
Analytical Investigation ◽  
Strength Increase ◽  
Confining Stress ◽  
Direct Tension ◽  
Bond Slip ◽  
Test Setup ◽  
Long Time

Experimental procedures used for the study of reinforcement to concrete bond have been hampered for a long time by inconsistencies and large differences in the obtained behavior, such as bond strength and mode of failure, depending on the specimen form and setup used in the test. Bond is controlled by the mechanics of the interface between reinforcement and concrete, and is sensitive to the influences of extraneous factors, several of which underlie, but are not accounted for, in conventional pullout test setups. To understand and illustrate the importance of specimen form and testing arrangement, a series of computational simulations are used in the present work on eight distinct variants of conventional bar pullout test setups that are used routinely in experimental literature for the characterization of bond-slip laws. The resulting bond strength increase generated by unaccounted confining stress fields that arise around the bar because of the boundary conditions of the test setup is used to classify the tests with respect to their relevance with the intended use of the results. Of the pullout setups examined, the direct tension pullout test produced the most conservative bond strength results, completely eliminating the contributions from eccentricity and passive confinement.

scholarly journals Numerical Characterization of Cohesive and Non-Cohesive ‘Sediments’ under Different Consolidation States Using 3D DEM Triaxial Experiments

Processes ◽  
2020 ◽  
Vol 8 (10) ◽  
pp. 1252
Author(s):  
Hadar Elyashiv ◽  
Revital Bookman ◽  
Lennart Siemann ◽  
Uri ten Brink ◽  
Katrin Huhn
Keyword(s):  
Mechanical Response ◽  
Burial Depth ◽  
Cohesive Sediments ◽  
Third Order ◽  
First Order ◽  
Numerical Characterization ◽  
Response To Stress ◽  
Bond Strengths ◽  
Individual Bond

The Discrete Element Method has been widely used to simulate geo-materials due to time and scale limitations met in the field and laboratories. While cohesionless geo-materials were the focus of many previous studies, the deformation of cohesive geo-materials in 3D remained poorly characterized. Here, we aimed to generate a range of numerical ‘sediments’, assess their mechanical response to stress and compare their response with laboratory tests, focusing on differences between the micro- and macro-material properties. We simulated two endmembers—clay (cohesive) and sand (cohesionless). The materials were tested in a 3D triaxial numerical setup, under different simulated burial stresses and consolidation states. Variations in particle contact or individual bond strengths generate first order influence on the stress–strain response, i.e., a different deformation style of the numerical sand or clay. Increased burial depth generates a second order influence, elevating peak shear strength. Loose and dense consolidation states generate a third order influence of the endmember level. The results replicate a range of sediment compositions, empirical behaviors and conditions. We propose a procedure to characterize sediments numerically. The numerical ‘sediments’ can be applied to simulate processes in sediments exhibiting variations in strength due to post-seismic consolidation, bioturbation or variations in sedimentation rates.

scholarly journals Conjuring up a ghost: structural and functional characterization of FhuF, a ferric siderophore reductase from E. coli

2021 ◽  
Author(s):  
I. B. Trindade ◽  
G. Hernandez ◽  
E. Lebègue ◽  
F. Barrière ◽  
T. Cordeiro ◽  
...  
Keyword(s):  
Functional Characterization ◽  
Paramagnetic Nmr ◽  
E Coli ◽  
The Past ◽  
Internal Cavities ◽  
Structural Differences ◽  
Bond Strengths ◽  
Redox Bohr Effect ◽  
Micromolar Range

AbstractIron is a fundamental element for virtually all forms of life. Despite its abundance, its bioavailability is limited, and thus, microbes developed siderophores, small molecules, which are synthesized inside the cell and then released outside for iron scavenging. Once inside the cell, iron removal does not occur spontaneously, instead this process is mediated by siderophore-interacting proteins (SIP) and/or by ferric-siderophore reductases (FSR). In the past two decades, representatives of the SIP subfamily have been structurally and biochemically characterized; however, the same was not achieved for the FSR subfamily. Here, we initiate the structural and functional characterization of FhuF, the first and only FSR ever isolated. FhuF is a globular monomeric protein mainly composed by α-helices sheltering internal cavities in a fold resembling the “palm” domain found in siderophore biosynthetic enzymes. Paramagnetic NMR spectroscopy revealed that the core of the cluster has electronic properties in line with those of previously characterized 2Fe–2S ferredoxins and differences appear to be confined to the coordination of Fe(III) in the reduced protein. In particular, the two cysteines coordinating this iron appear to have substantially different bond strengths. In similarity with the proteins from the SIP subfamily, FhuF binds both the iron-loaded and the apo forms of ferrichrome in the micromolar range and cyclic voltammetry reveals the presence of redox-Bohr effect, which broadens the range of ferric-siderophore substrates that can be thermodynamically accessible for reduction. This study suggests that despite the structural differences between FSR and SIP proteins, mechanistic similarities exist between the two classes of proteins. Graphic abstract

scholarly journals Shear bond strength of orthodontic brackets to enamel after application of a caries infiltrant

2014 ◽  
Vol 85 (4) ◽  
pp. 645-650 ◽  
Author(s):  
Laura Mews ◽  
Matthias Kern ◽  
Robert Ciesielski ◽  
Helge Fischer-Brandies ◽  
Bernd Koos
Keyword(s):  
Statistical Analysis ◽  
Bond Strength ◽  
Shear Force ◽  
Shear Bond Strength ◽  
Orthodontic Brackets ◽  
Enamel Defects ◽  
Adhesive Remnant Index ◽  
Demineralized Enamel ◽  
Kolmogorov Smirnov ◽  
Bond Strengths

ABSTRACT Objective:  To examine differences in the shear bond strength of orthodontic brackets on differently mineralized enamel surfaces after applying a caries infiltrant or conventional adhesive. Materials and Methods:  A total of 320 bovine incisors were assigned to eight pretreated groups, and the shear force required for debonding was recorded. Residual adhesive was evaluated by light microscopy using the adhesive remnant index. Statistical analysis included Kolmogorov-Smirnov, analysis of variance (ANOVA), and Scheffé tests. Results:  The highest bond strength (18.8 ± 4.4 MPa) was obtained after use of the caries infiltrant. More residual adhesive and fewer enamel defects were observed on infiltrated enamel surfaces. Brackets on demineralized enamel produced multiple enamel defects. Conclusions:  Acceptable bond strengths were obtained with all material combinations. A caries-infiltrant applied before bracket fixation has a protective effect, especially on demineralized enamel.

Materials and Physical Properties of Novel High-k and Medium-k Gate Dielectrics

2001 ◽  
Vol 670 ◽  
Author(s):  
Ran Liu ◽  
Stefan Zollner ◽  
Peter Fejes ◽  
Rich Gregory ◽  
Shifeng Lu ◽  
...  
Keyword(s):  
Thin Film ◽  
Transition Metal Oxides ◽  
Gate Dielectrics ◽  
Low Leakage ◽  
Low Leakage Current ◽  
High K ◽  
Compositional Properties ◽  
Sharp Interfaces ◽  
Selection Of

ABSTRACTRapid shrinking in device dimensions calls for replacement of SiO2 by new gate insulators in future generations of MOSFETs. Among many desirable properties, potential candidates must have a higher dielectric constant, low leakage current, and thermal stability against reaction or diffusion to ensure sharp interfaces with both the substrate Si and the gate metal (or poly-Si). Extensive characterization of such materials in thin-film form is crucial not only for selection of the alternative gate dielectrics and processes, but also for development of appropriate metrology of the high-k films on Si. This paper will report recent results on structural and compositional properties of thin film SrTiO3 and transition metal oxides (ZrO2and HfO2).

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