scholarly journals A simple method for extraction of Ricinus communis L. oil and its application for biodiesel production by ethylic route

2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Jana Eduarda Alberto Vasco ◽  
Paulino Sabite ◽  
Estevão Clavel ◽  
Esau Carlos Bandali ◽  
Geraldo Alfredo Gueze ◽  
...  

AbstractBiodiesel is a clean fuel, and an alternative to the environmental complications ascribed to fossil fuels. However, the forms of its production are still the object of research in the literature because some issues related to its process improvement and economical viability remain a challenge. Consequently, this research aims to produce biodiesel by the ethylic route from Ricinus communis L. oil extracted with a simple solid liquid extraction method without the use of the soxhled extractor and inspired from rural communities practices. In this sense, Ricinus communis L. was extracted by n-hexane as solvent, obtaining biodiesel through ethyl transesterification via alkaline catalysis. The characterization of biodiesel in terms of—acid value (AV), combustibility and corrosivity to copper. The results indicated that the yield of the extracted oil was 14% in relation to the mass of seeds used, the value of the AV was 0.96 mg NaOH/g, showing in this case that the oil can be used in the transesterification process to obtain biodiesel. The biodiesel yield obtained was 37% and the AV was 1.98 mg NaOH/g, being considered above the acceptable value for its use in diesel engines, and should be neutralized to at least 0.8 mg NaOH/g. Based on this work, biodiesel was obtained via ethyl esterification of Ricinus communis L. oil extracted from a simple and easy method.

2020 ◽  
Author(s):  
Jana Vasco ◽  
Paulino Sabite ◽  
Estevão Clavel ◽  
Esaú Bandali ◽  
Geraldo Gueze ◽  
...  

Abstract Biodiesel is a clean fuel, and an alternative to the environmental complications caused by fossil fuels. However, the forms of its production are still the object of research in the literature because some issues related to process improvement and economically viable remain a challenge. Therefore, this research aims to produce biodiesel by the ethylic route from Ricinus Communis L oil extracted with a simple solid liquid extraction method without the use of the soxhled extractor. In this sense, Ricinus Communis L was extracted by n-hexane as solvent, obtaining biodiesel through ethyl transesterification via alkaline catalysis. The characterization of biodiesel in terms of – acid value (AV), combustibility and corrosivity to copper. The results indicated that the yield of the extracted oil was 14% in relation to the mass of seeds used, the value of the AV was 0.96mgNaOH / g, showing in this case that the oil can be used in the transesterification process to obtain biodiesel. The biodiesel yield obtained was 37% and the AV was 1.98mgNaOH / g, being considered above the acceptable value for its use in diesel engines, and should be neutralized to at least 0.8mgNaOH / g. Based on this work, biodiesel was obtained via ethyl esterification of Ricinus Communis L oil extracted from a simple and easy method.


2021 ◽  
Vol 5 (1) ◽  
pp. 404-410
Author(s):  
L. M. Mustapha ◽  
M. I. Shago ◽  
R. H. Burhanudden ◽  
G. Suleiman

The global energy concern with the availability of recoverable fossil fuel reserves and the environmental problems caused by those fossil fuels, considerable attention has been given to biodiesel production as an alternative to petro diesel worldwide. In this research, the seed oil of Ricinus communis (castor bean) was investigated for its viability as a feedstock for biodiesel production. The oil was extracted from the seed using petroleum ether .The oil quality characteristics of the seed oil were; Acid values for both Ricinus communis oil  and biodiesel, 4.208 and3.93, and free fatty acids for both Ricinus communis and biodiesel were 1.2408 and 2.508, saponification value (SV) for both Ricinus communis and biodiesel,, 185.0 and 173.16, specific gravity (S.G) for both Ricinus communis and biodiesel, 0.976g/ml and 0.935g/ml. the PH value for both Ricinus communis and biodiesel, 6.67 and 6.8. Refractive index for both Ricinus communis and biodiesel, 1.37 and 1.191, moisture content of seed, 0.052. Colour for both and Ricinus communis oil and biodiesel is brown colour and amber colour, respectively. The oil was transesterified using methanol and concentrated sulphuric acid. And with other investigated oils from the literature and were found to fall within acceptable limits, this implies that Ricinus communis seed oil could be used as diesel in combustion engines in tropical climates like Nigeria.


2009 ◽  
Vol 1 (1) ◽  
pp. 237-239 ◽  
Author(s):  
Miklos Maximiliano Bajay ◽  
José Baldin Pinheiro ◽  
Carlos Eduardo Araújo Batista ◽  
Márcia Barreto Medeiros Nobrega ◽  
Maria Imaculada Zucchi

Catalysts ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 427 ◽  
Author(s):  
Muhammad Awais ◽  
Sa’ed A Musmar ◽  
Faryal Kabir ◽  
Iram Batool ◽  
Muhammad Asif Rasheed ◽  
...  

Biodiesel is a renewable fuel usually produced from vegetable oils and animal fats. This study investigates the extraction of oil and its conversion into biodiesel by base-catalyzed transesterification. Firstly, the effect of various solvents (methanol, n-hexane, chloroform, di-ethyl ether) on extraction of oil from non-edible crops, such as R. communis and M. azedarach, were examined. It was observed that a higher concentration of oil was obtained from R. communis (43.6%) as compared to M. azedarach (35.6%) by using methanol and n-hexane, respectively. The extracted oils were subjected to NaOH (1%) catalyzed transesterification by analyzing the effect of oil/methanol molar ratio (1:4, 1:6, 1:8 and 1:10) and varying temperature (20, 40, 60 and 80 °C) for 2.5 h of reaction time. M. azedarach yielded 88% and R. communis yielded 93% biodiesel in 1:6 and 1:8 molar concentrations at ambient temperature whereas, 60 °C was selected as an optimum temperature, giving 90% (M. azedarach) and 94% (R. communis) biodiesel. The extracted oil and biodiesel were characterized for various parameters and most of the properties fulfilled the American Society for Testing and Materials (ASTM) standard biodiesel. The further characterization of fatty acids was done by Gas Chromatography/Mass Spectrometer (GC/MS) and oleic acid was found to be dominant in M. azedarach (61.5%) and R. communis contained ricinoleic acid (75.53%). Furthermore, the functional groups were analyzed by Fourier Transform Infrared Spectroscopy. The results suggested that both of the oils are easily available and can be used for commercial biodiesel production at a cost-effective scale.


Biomolecules ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 616
Author(s):  
Bakari Hamadou ◽  
Djomdi ◽  
Ruben Zieba Falama ◽  
Cedric Delattre ◽  
Guillaume Pierre ◽  
...  

The aim of this work is to study the influence of the physicochemical characteristics of neem seeds, according to their mass and oil content, on the production of biodiesel. After the physical characterization of the seeds and extraction of the oil (triglycerides), biodiesel was produced from crude neem seed oil by transesterification with ethanol in the presence of sodium hydroxide. This study shows that the physicochemical characteristics of these seeds vary according to the origin of the samples. The seeds from Zidim, with a mass average of 200 seeds evaluated at 141.36 g and an almond content of 40.70%, have better characteristics compared to those collected in the city of Maroua, with average values evaluated at 128.00 g and 36.05%, respectively. Almonds have an average lipid content of 53.98 and 56.75% for the Maroua and Zidim samples, respectively. This study also reveals that neem oil, by its physicochemical characteristics, has a satisfactory quality for a valorization in the production of biodiesel. However, its relatively high free fatty acid content is a major drawback, which leads to a low yield of biodiesel, evaluated on average at 89.02%, and requires a desacidification operation to improve this yield. The analysis of biodiesel indicates physicochemical characteristics close and comparable to those of petrodiesel, particularly in terms of calorific value, density, kinematic viscosity, acid value, evaluated at 41.00 MJ/kg, 0.803, 4.42 cSt, and 0.130 mg/g, respectively.


Lipids ◽  
2014 ◽  
Vol 49 (8) ◽  
pp. 853-853
Author(s):  
José María Arroyo-Caro ◽  
Tarik Chileh ◽  
Diego López Alonso ◽  
Federico García-Maroto

Author(s):  
Fiona Rachma Annisa ◽  
Indang Dewata ◽  
Hary Sanjaya ◽  
Latisma Dj ◽  
Ananda Putra ◽  
...  

This work has investigated the reusability of silica-titania in various temperatures (50 – 70°C) of biodiesel production from waste cooking oil. The reused silica-titania catalyst collected from silica-titania catalyst waste produced from the process of separating the catalyst from biodiesel products from palm oil and used cooking oil at various temperatures. The 1st and 2nd reused SiO2-TiO2 were characterized by DR UV-Vis and the spectra were deconvoluted for calculate the fraction of titanium in tetrahedral coordination. In addition the biodiesel products were characterized using FTIR, and several properties of biodiesel such as density, flow rate and acid value were analyzed in order to get the information about catalytic activity reused SiO2-TiO2. The results show the titanium tetrahedral fraction in reused catalyst (1st) and (2nd) are found to be 24,98% and 24.65%, respectively. The FTIR characterization of biodiesel products and waste cooking oil are almost similar. The analysis of waste cooking oil converted to biodiesel shows an optimum temperature of 50oC that at this temperature the lowest density or highest flow rate gave highest conversion of 47.82% using BCR1 and 39.13% using BCR2.


2015 ◽  
Vol 77 (5) ◽  
Author(s):  
C. S. Abdullah ◽  
N. Baluch ◽  
S. Mohtar

Biodiesel is a form of biofuel; diesel fuel manufactured from vegetable oils, animal fats, or recycled greases. Biodiesel is produced through a process called transesterification which involves taking naturally occurring carbon chain molecules, known as triglycerides, found in such feed stocks as seed oils and animal fats, and converting them into methyl esters, which is the chemical term for biodiesel. The conventional transesterification of the triglycerides to fatty methyl esters and glycerin is slow and not complete. During the conversion process not all fatty acid chains are turned into alkyl esters (biodiesel) reducing biodiesel quality and yield, significantly. In considering a new biodiesel facility or an upgrade of existing biodiesel plant, it is imperative that ultrasonic mixing technology be considered; it is efficient and ideal for micro scale biodiesel processing. This paper infers the efficiency of Ultrasonics for the ultrasonication of liquids and gleans that Ultrasonic cavitational mixing is the most advanced means to form fine-size emulsions at micro processing scale.  The paper construes the innovative ascendancy of ‘Ultrasonic Reactor’ for micro scale production of biodiesel and demonstrates that there is a direct link between methanol droplet size, biodiesel yield, and conversion speed which makes ultrasonic reactors the most productive technology in the biodiesel industry. The paper concludes that biofuels are sustainable alternative to fossil fuels and biodiesel is a green energy source for agriculture, transport and power generation at micro level use in rural communities. 


Sign in / Sign up

Export Citation Format

Share Document