scholarly journals Reusability test of Silica - Titania Catalyst on Biodiesel Production from Waste Cooking Oil in Various Temperatures

2019 ◽  
pp. 116-123
Author(s):  
Fiona Rachma Annisa ◽  
Indang Dewata ◽  
Hary Sanjaya ◽  
Latisma Dj ◽  
Ananda Putra ◽  
...  
Keyword(s):  
Flow Rate ◽  
Acid Value ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Tetrahedral Coordination ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
Ftir Characterization ◽  
Density Flow

This work has investigated the reusability of silica-titania in various temperatures (50 – 70°C) of biodiesel production from waste cooking oil. The reused silica-titania catalyst collected from silica-titania catalyst waste produced from the process of separating the catalyst from biodiesel products from palm oil and used cooking oil at various temperatures. The 1st and 2nd reused SiO2-TiO2 were characterized by DR UV-Vis and the spectra were deconvoluted for calculate the fraction of titanium in tetrahedral coordination. In addition the biodiesel products were characterized using FTIR, and several properties of biodiesel such as density, flow rate and acid value were analyzed in order to get the information about catalytic activity reused SiO2-TiO2. The results show the titanium tetrahedral fraction in reused catalyst (1st) and (2nd) are found to be 24,98% and 24.65%, respectively. The FTIR characterization of biodiesel products and waste cooking oil are almost similar. The analysis of waste cooking oil converted to biodiesel shows an optimum temperature of 50oC that at this temperature the lowest density or highest flow rate gave highest conversion of 47.82% using BCR1 and 39.13% using BCR2.

Synthesis and characterization of coal fly ash supported zinc oxide catalyst for biodiesel production using used cooking oil as feed

2021 ◽  
Vol 170 ◽  
pp. 302-314
Author(s):  
Adeyinka S. Yusuff ◽  
Aman K. Bhonsle ◽  
Jayati Trivedi ◽  
Dinesh P. Bangwal ◽  
Lok P. Singh ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Fly Ash ◽  
Oxide Catalyst ◽  
Coal Fly Ash ◽  
Biodiesel Production ◽  
Synthesis And Characterization ◽  
Cooking Oil ◽  
Used Cooking Oil

scholarly journals KRITERIA RUMAH MAKAN SUPPLIER MINYAK JELANTAH DALAM RANGKA PERENCANAAN BAHAN BAKU BIODIESEL

2019 ◽  
Vol 1 (1) ◽  
pp. 27-33
Author(s):  
D.U.M. Susilo ◽  
Th. Candra Wasis A.S. ◽  
Zakwan .
Keyword(s):  
Raw Materials ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Biodiesel Production ◽  
Analytic Hierarchy ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
A Value ◽  
Many Sources ◽  
The City

The using of biodiesel as an environmentally friendly fuel has received attention from consumers to producers. So, a lot of research was done on the potential raw material to become biodiesel. One of the raw materials for biodiesel was waste cooking oil. Pontianak City have many sources including waste cooking oil from restaurants. Therefore restaurants in the city of Pontianak might be used as suppliers of waste cooking oil in biodiesel production. This study aims to determine the priority of criteria and sub-criteria for restaurants as suppliers and determine good restaurants as suppliers of used cooking in Pontianak City . Purposive technique sampling using a sample of 61 house dining, interviewed to obtain alternative data suppliers. Expert survey questionnaire contains priority weighting of criteria and supplier criteria, analyzed using AHP ( Analytic Hierarchy Process ). Grouping of restaurants based on alternative supplier values ​​is used to determine good restaurants to be suppliers. The priority criteria for restaurants as consecutive suppliers are experience (0.289), quality (0.279), capacity (0.231), service (0.148) and price (0.053). Sub-criteria priority of restaurants as suppliers in a row is the time span of used cooking oil sold(0.161), length of time used cooking oil (0.155), income (0.129), type of cooking oil (0.107), type of fried food products (0.092), volume of cooking oil (0.090), frying volume (0.085), transaction convenience (0.082), subject to used cooking oil (0.056), used cooking oil price (0.030) and ease of payment (0.013). A value of ≥ 0.325 is a dining value that shows a very better priority as a supplier. The number of restaurants as suppliers is 8 % of the population of restaurants in the city of Pontianak..

scholarly journals Production of Biodiesel from High Acid Value Waste Cooking Oil Using an Optimized Lipase Enzyme/Acid-Catalyzed Hybrid Process

2009 ◽  
Vol 6 (s1) ◽  
pp. S485-S495 ◽  
Author(s):  
N. Saifuddin ◽  
A. Z. Raziah ◽  
H. Nor Farah
Keyword(s):  
Acid Value ◽  
Reaction Rates ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Hybrid Process ◽  
Initial Reaction ◽  
Cooking Oil ◽  
High Acid ◽  
Lipase Enzyme ◽  
Acid Catalyzed

The present study is aimed at developing an enzymatic/acid-catalyzed hybrid process for biodiesel production using waste cooking oil with high acid value (poor quality) as feedstock. Tuned enzyme was prepared using a rapid drying technique of microwave dehydration (time required around 15 minutes). Further enhancement was achieved by three phase partitioning (TPP) method. The results on the lipase enzyme which was subjected to pH tuning and TPP, indicated remarkable increase in the initial rate of transesterification by 3.8 times. Microwave irradiation was found to increase the initial reaction rates by further 1.6 times, hence giving a combined increase in activity of about 5.4 times. The optimized enzyme was used for hydrolysis and 88% of the oil taken initially was hydrolyzed by the lipase. The hydrolysate was further used in acid-catalyzed esterification for biodiesel production. By using a feedstock to methanol molar ratio of 1:15 and a sulphuric acid concentration of 2.5%, a biodiesel conversion of 88% was obtained at 50 °C for an hour reaction time. This hybrid process may open a way for biodiesel production using unrefined and used oil with high acid value as feedstock.

Thermodynamic and kinetic approach of biodiesel production from waste cooking oil using nano-catalysts

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Saima Noreen ◽  
Iqra Sahar ◽  
Nasir Masood ◽  
Munawar Iqbal ◽  
Muhammad Zahid ◽  
...  
Keyword(s):  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Precipitation Method ◽  
Optimum Conditions ◽  
Reaction Conditions ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
Optimum Reaction ◽  
Co Precipitation ◽  
Nano Catalysts

Abstract This study focusses on the production of biodiesel by reacting the heterogeneous based nano-catalysts with used cooking oil in the presence of methanol. The CZO nanoparticles (NPs) were synthesized by co-precipitation method and characterized by different techniques. Biodiesel was characterized by the gas chromatograph (GC) and Fourier Transform Infra-red Spectroscopy (FTIR). Optimum conditions for the maximum biodiesel yield (90%) were 0.2% (w/w) catalyst dose, 3:1 methanol to oil ratio, 50 °C reaction temperature, 150 min reaction time and 136 rpm stirring speed. The kinetic modeling and the thermodynamic factors like enthalpy (ΔH), activation energy (Ea), entropy (ΔS) and free energy (ΔG) were operated on all the data. Mean and standard deviation was used for analysis of data. The results indicate the maximum biodiesel yield under the optimum reaction conditions, which is promising to reduce the pollution such as air pollution and greenhouse effect for sustainable environmetal development.

scholarly journals Study on Biodiesel Production and Characterization for Used Cooking Oil

2020 ◽  
pp. 76-86
Author(s):  
M. S. Dulawat ◽  
J. M. Makavana ◽  
S. V. Kelaiya ◽  
M. J. Gojiya ◽  
G. A. Gadhiya ◽  
...  
Keyword(s):  
Waste Cooking Oil ◽  
Diesel Oil ◽  
Environmental Benefits ◽  
Biodiesel Production ◽  
Biodiesel Fuel ◽  
Potential Candidate ◽  
Ample Evidence ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
The Cost

The increasing awareness of the depletion of fossil fuel resources and the environmental benefits of biodiesel fuel has made it more attractive in recent times. Its primary advantages deal with it being one of the most renewable fuels currently available and it is also non-toxic and biodegradable. It can also be used directly in most diesel engines without requiring extensive engine modifications. However, the cost of biodiesel is the major hurdle to its commercialization in comparison to petroleum-based diesel fuel. Biodiesel is proved to be a potential candidate for partial substitute of mineral diesel oil. The environmental issues associated with the use of fossil-based energy sources have informed the search for more sustainable energy alternatives. This work investigated the potential of producing biodiesel from waste cooking oil (WCO). The work gives ample evidence that oil from eateries in WCO could be used in producing high quality biodiesel in an easy, one-step transesterification reaction without the need for acid esterification which increases the overall cost of the production process.

scholarly journals Analisis Minyak Jelantah Sebagai Bahan Bakar Biodiesel dengan Proses Transesterifikasi

2018 ◽  
Vol 1 (1) ◽  
pp. 16 ◽  
Author(s):  
Hadrah Hadrah ◽  
Monik Kasman ◽  
Fitria Mayang Sari
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Sodium Hydroxide Solution ◽  
Quality Standard ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Cooking Oil ◽  
Used Oil ◽  
Used Cooking Oil ◽  
Biodiesel Quality

Waste cooking oil is used oil that has been used for domestic purposes and has undergone changes, both physically and chemically. One effort that can be done to reduce the adverse effects of used cooking oil is changed the material used cooking oil into biodiesel. In this study of biodiesel production from waste cooking oil is done by using biodiesel transesterification reaction as generally through a pretreatment in order to reduce the number of Free Fatty Acid in cooking oil. The high number of Free Fatty Acid will complicate the separation of glycerol from biodiesel so that production of biodiesel will be slight. Test parameters of biodiesel quality produced by  transesterification process refers to the Indonesian biodiesel quality standard ISO 7182: 2015. The production of biodiesel from used cooking oil in this experiment using variations methanol and sodium hydroxide solution ratio to the used cooking oil is 1: 2; 1: 4 and 1: 8. Test results showed that the quality of biodiesel is in compliance with ISO 7182: 2015 on the parameters of viscosity, density and flame test. While the Free Fatty Acids remained above the quality standard ISO 7182: 2015.Keywords :    Waste cooking oil, Transesterification, Biodiesel

scholarly journals Multi-Feedstocks Biodiesel Production from Esterification of Calophyllum inophyllum Oil, Castor Oil, Palm Oil and Waste Cooking Oil

2020 ◽  
Vol 9 (1) ◽  
pp. 119-123
Author(s):  
H Hadiyanto ◽  
Apsari Puspita Aini ◽  
Widayat Widayat ◽  
Kusmiyati Kusmiyati ◽  
Arief Budiman ◽  
...  
Keyword(s):  
Vegetable Oils ◽  
Palm Oil ◽  
Ricinus Communis ◽  
Acid Value ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Calophyllum Inophyllum ◽  
Cooking Oil

Biodiesel can be produced from various vegetable oils and animal fat. Abundant sources of vegetable oil in Indonesia, such as Calophyllum inophyllum, Ricinus communis, palm oil, and waste cooking oil, were used as raw materials. Multi-feedstock biodiesel was used to increase the flexibility operation of biodiesel production. This study was conducted to determine the effect of a combination of vegetable oils on biodiesel characteristics. Degumming and two steps of esterification were applied for high free fatty acid feedstock before trans-esterification in combination with other vegetable oils. Potassium hydroxide was used as a homogenous catalyst and methanol as another raw material. The acid value of C. inophyllum decreased from 54 mg KOH/gr oil to 2.15 mg KOH/gr oil after two steps of esterification. Biodiesel yield from multi-feedstock was 87.926% with a methanol-to-oil molar ratio of 6:1, temperature of 60 ℃, and catalyst of 1%wt. ©2020. CBIORE-IJRED. All rights reserved

scholarly journals Characterization of Biodiesel from Alkaline Refinement of Waste Cooking Oil

2020 ◽  
Vol 10 (1) ◽  
pp. 16-24
Author(s):  
Aliru Olajide Mustapha ◽  
Amina Abiola Adebisi ◽  
Bukola Opeyemi Olanipekun
Keyword(s):  
Fatty Acids ◽  
Low Cost ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Fuel Quality ◽  
Cooking Oil ◽  
Yield And Quality ◽  
American Standard

The waste cooking oil (WCO) is a low cost and prospective feedstock with no competitive food uses for biodiesel production, but the yield and quality have been greatly affected by impurities.  This study examined the chemical and fuel quality of biodiesel of both WCO and alkaline treated WCO.  The transesterification process using the alkaline treated cooking oil (ACO) methanol and sodium hydroxide as catalyst followed the Association of Officials of Analytical Chemists (AOAC) techniques. The pH values between 7.27 and 8.65 were found for alkaline treated cooking methyl ester (ACME), alkaline treated cooking oil (ACO) and WCO. Density of ACME, ACO and WCO varied between 0.89 and 0.93 (g/cm3). The fatty acids found were benzoic acid (3.77%), octanoic acid (8.35%), and palmitic acid (75.02%) – most abundant. Comparison of results with the American Standard for Testing Materials (ASTM) values showed quality enhancements of ACO in physicochemical and fuel properties over WCO. The biodiesels from ACO have enhanced emulsification, fuel and free fatty acids qualities over the WCO, showing the refinement methodology of WCO has overall improvement in the biodiesel purity and quality against the previous conflicting reports.

Sign in / Sign up

Export Citation Format

Share Document