One dimensional curved wire chamber for powder X-ray crystallography

AbstractCo-crystallization of C-propyl-pyrogallol[4]arene (PgC3) with 4,4′-bipyridine (bpy) in ethanol afforded a multi-component complex (PgC3) · 3(bpy) ·(EtOH) (1) that consists of a one-dimensional brick-wall framework, which was formed by four pyrogallol[4]arene molecules and two juxtaposed bpy molecules, entrapping two other bpy molecules as guests within each cavity. Heating a mixture of PgC3 and trans-1,2-bis-(4-pyridyl)ethylene (bpe) in an ethanol-water mixed solvent allowed the isolation of a multi-component complex (PgC3) ·(bpe) · 2(EtOH) ·(H2O) (2), which has a two-dimensional wave-like polymer structure with the bpe molecules embedded in the wave trough between two PgC3 molecules. Single-crystal X-ray crystallography was utilized to investigate the hydrogen bonding networks of the multi-component complexes 1 and 2.

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The Synthesis and Characterization of a Novel One-Dimensional Bismuth (III) Coordination Polymer as a Precursor for the Production of Bismuth (III) Oxide Nanorods

Crystals ◽

10.3390/cryst12010113 ◽

2022 ◽

Vol 12 (1) ◽

pp. 113

Author(s):

Younes Hanifehpour ◽

Babak Mirtamizdoust ◽

Jaber Dadashi ◽

Ruiyao Wang ◽

Mahboube Rezaei ◽

...

Keyword(s):

Single Crystal ◽

Coordination Compound ◽

Organic Ligand ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography ◽

Oxide Nanorods ◽

Pure Phase ◽

3D Framework

A novel Bi (III) coordination compound, [Bi(HQ)(Cl)4]n ((Q = pyridine-4-carbaldehyde thiosemicarbazone), was prepared in this research using a sonochemical technique. SEM, infrared spectroscopy (IR), XRD, and single-crystal X-ray analysis were utilized to analyze the Bi(III) coordination compound. The structure determined using single-crystal X-ray crystallography indicates that the coordination compound is a 1D polymer in solid state and that the coordination number of bismuth (III) ions is six, (BiSCl5), with one S donor from the organic ligand and five Cl donors from anions. It is equipped with a hemidirectional coordination sphere. It is interesting that the ligand has been protonated in the course of the reaction with a Cl- ion balancing the charge. This compound’s supramolecular properties are directed and regulated by weak directional intermolecular interactions. Through π–π stacking interactions, the chains interact with one another, forming a 3D framework. Thermolysis of the compound at 170 °C with oleic acid resulted in the formation of pure phase nanosized Bi (III) oxide. SEM technique was used to examine the morphology and size of the bismuth (III) oxide product produced.

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APPLICATION OF A ONE-DIMENSIONAL POSITION SENSITIVE CHAMBER ON SYNCHROTRON RADIATION

International Journal of Modern Physics Conference Series ◽

10.1142/s2010194514601422 ◽

2014 ◽

Vol 27 ◽

pp. 1460142

Author(s):

HUIRONG QI ◽

MEI LIU

Keyword(s):

Synchrotron Radiation ◽

Low Cost ◽

Large Area ◽

Position Resolution ◽

One Dimensional ◽

X Ray ◽

High Position ◽

Standard Data ◽

Wire Chamber ◽

The One

In the last few years, wire chambers have been frequently used for X-ray detection because of their low cost, large area and reliability. X-ray diffraction is an irreplaceable method for powder crystal lattice measurements. A one-dimensional single-wire chamber has been developed in our lab to provide high position resolution for powder diffraction experiments using synchrotron radiation. There are 200 readout strips of 0.5 mm width with a pitch of 1.0 mm in the X direction, and the working gas is a mixture of Ar and CO2 (90/10). The one-dimensional position of the original ionization point is determined by the adjacent strip's distribution information using the center of gravity method. Recently, a study of the detector's performance and diffraction image was completed at the 1W1B laboratory of the Beijing Synchrotron Radiation Facility (BSRF) using a sample of SiO2. Most of the relative errors between the measured values of diffraction angles and existing data were less than 1%. The best position resolution achieved for the detector in the test was 71 μm (σ value) with a 20 μm slit collimator. Finally, by changing the detector height in incremental distances from the center of the sample, the one-dimensional detector achieved a two-dimensional diffraction imaging function, and the results are in good agreement with standard data.

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Synthesis, X-ray crystallography, thermogravimetric analysis and spectroscopic characterization of isostructural one-dimensional coordination polymers as sorbents for some anions

CrystEngComm ◽

10.1039/c7ce02017a ◽

2018 ◽

Vol 20 (13) ◽

pp. 1783-1796 ◽

Cited By ~ 2

Author(s):

Bahram Ghanbari ◽

Leila Shahhoseini ◽

Agata Owczarzak ◽

Maciej Kubicki ◽

Reza Kia ◽

...

Keyword(s):

Thermogravimetric Analysis ◽

Coordination Polymers ◽

Spectroscopic Characterization ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography

A new series of coordination polymers capable of adsorbing anions have been synthesized by employing a dipyridine substituted diazacrown macrocycle as linker.

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Catalytic Activity of Polynuclear vs. Dinuclear Aroylhydrazone Cu(II) Complexes in Microwave-Assisted Oxidation of Neat Aliphatic and Aromatic Hydrocarbons

Molecules ◽

10.3390/molecules24010047 ◽

2018 ◽

Vol 24 (1) ◽

pp. 47 ◽

Cited By ~ 13

Author(s):

Manas Sutradhar ◽

Tannistha Barman ◽

Armando Pombeiro ◽

Luísa Martins

Keyword(s):

Catalytic Activity ◽

Aromatic Hydrocarbons ◽

Catalytic Performance ◽

Antiproliferative Agents ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography ◽

Mild Conditions ◽

Microwave Assisted ◽

Aliphatic And Aromatic Hydrocarbons

One-dimensional (1D) polynuclear Cu(II) complex (1) derived from (5-bromo-2-hydroxybenzylidene)-2-hydroxybenzohydrazide (H2L) is synthesized and characterized by elemental analysis, IR spectroscopy, ESI-MS, and single crystal X-ray crystallography. Its catalytic performance towards the solvent-free microwave-assisted peroxidative oxidation of aliphatic and aromatic hydrocarbons under mild conditions is compared with that of dinuclear Cu(II) complexes (2 and 3) of the same ligand, previously reported as antiproliferative agents. Polymer 1 exhibits the highest activity, either for the oxidation of cyclohexane (leading to overall yields, based on the alkane, of up to 39% of cyclohexanol and cyclohexanone) or towards the oxidation of toluene (selectively affording benzaldehyde up to a 44% yield), after 2 or 2.5 h of irradiation at 80 or 50 °C, respectively.

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Synthesis, Characterization and Crystal Structure of Coordination Polymers Developed as Anion Receptor

Solid State Phenomena ◽

10.4028/www.scientific.net/ssp.273.134 ◽

2018 ◽

Vol 273 ◽

pp. 134-139

Author(s):

M.A. Kadir ◽

Christopher J. Sumby

Keyword(s):

Coordination Polymer ◽

Coordination Polymers ◽

Cadmium Nitrate ◽

Two Dimensional ◽

Anion Receptor ◽

Slow Evaporation ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography ◽

Good Potential

Reaction of diamide ligand, namelyN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide (L) with cadmium nitrate and cadmium perchlorate has given rise to the formation of two types coordination polymers. Compound (CP1-Cd) with formula molecule {[Cd (L)2(H2O)2](NO3)2·6H2O}nis a one-dimensional coordination polymer while compound (CP2-Cd), with formula molecule {[Cd (L)2(H2O)2](ClO4)2·31⁄2H2O.CH3OH}n, is a two dimensional coordination polymer. These coordination polymers were preparedviaslow evaporation methods and completely characterized by combination of solid state techniques such as Fourier Transform Infrared (FTIR) spectroscopy, elemental analysis and X-ray crystallography. This study revealed that coordination polymers derived fromN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide can accommodate anions with different sizes, showing good potential as anion receptor.

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Synthesis of novel α-aminoecdysteroids via regio- and stereoselective oximation/hydrogenation of 20-hydroxyecdysone derivatives

Canadian Journal of Chemistry ◽

10.1139/cjc-2016-0413 ◽

2017 ◽

Vol 95 (2) ◽

pp. 130-133 ◽

Cited By ~ 3

Author(s):

Rimma G. Savchenko ◽

Svetlana A. Kostyleva ◽

Ekaterina S. Meshcheryakova ◽

Leonard M. Khalilov ◽

Lyudmila V. Parfenova ◽

...

Keyword(s):

Nmr Spectroscopy ◽

Two Dimensional ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography ◽

C Nmr

Oximation of 20-hydroxyecdysone oxo derivatives proceeds regio- and stereoselectively and provides (E)-configured oximes in quantitative yields. The Ni–Ra-catalyzed hydrogenation of the oximes affords novel α-aminoecdysteroids with the unchanged 14α-hydroxy-7-en-6-on native chromophore of ecdysteroids. The structures of synthesized compounds were confirmed by the means of homo- and heteronuclear one-dimensional and two-dimensional 1H and 13C NMR spectroscopy and X-ray crystallography.

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Syntheses and Spectroscopic Studies of Some New Diazaphospholes and Diazaphosphorinanes. Crystal Structure of 4

Zeitschrift für Naturforschung B ◽

10.1515/znb-2005-1001 ◽

2005 ◽

Vol 60 (10) ◽

pp. 1021-1026 ◽

Cited By ~ 12

Author(s):

Khodayar Gholivand ◽

Zahra Shariatinia ◽

Mehrdad Pourayoubi ◽

Sedigheh Farshadian

Keyword(s):

Crystal Structure ◽

Ir Spectroscopy ◽

Spectroscopic Studies ◽

Coupling Constants ◽

Crystalline Lattice ◽

Polymeric Chain ◽

Ring Strain ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography

New diazaphospholes and diazaphosphorinanes with formula were synthesized and characterized by 1H, 13C, 31P NMR and IR spectroscopy and elemental analysis. The structure of compound 1 has been determined by X-ray crystallography. A one-dimensional polymeric chain was observed in the crystalline lattice produced by intermolecular -P=O. . .H-N- and -C=O. . .H-N-hydrogen bonds. Compounds 1 and 2 contain five-membered rings and show high values for 2J(PNH) and 2J(P,C) coupling constants due to the ring strain. These constants are reduced seriously in compounds with six-membered rings. In compound 6 with CCl3C(O)NH moiety, all phosphorus-hydrogen couplings are zero.

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New Tetramic Acid Derivatives From the Deep-Sea-Derived Fungus Penicillium sp. SCSIO06868 With SARS-CoV-2 Mpro Inhibitory Activity Evaluation

Frontiers in Microbiology ◽

10.3389/fmicb.2021.730807 ◽

2021 ◽

Vol 12 ◽

Author(s):

Xiaoyan Pang ◽

Weihao Chen ◽

Xin Wang ◽

Xuefeng Zhou ◽

Bin Yang ◽

...

Keyword(s):

Deep Sea ◽

Optical Rotation ◽

Ionization Mass ◽

Tetramic Acid ◽

Specific Optical Rotation ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography ◽

Nmr Data ◽

Main Protease

Three new tetramic acid derivatives (1–3) and a new polyketide (4) along with eight known compounds (5–12) were isolated from cultures of the deep-sea-derived fungus Penicillium sp. SCSIO06868. Four new structures were elucidated by analysis of one-dimensional/two-dimensional nuclear magnetic resonance (NMR) data and high-resolution electrospray ionization mass spectrometry. Their absolute configurations were established by X-ray crystallography analysis and comparison of the experimental and reported electronic circular dichroism (ECD) values or specific optical rotation. Compound 3 exhibited potent, selective inhibitory activities against Staphylococcus aureus and methicillin-resistant S. aureus with minimum inhibitory concentration values of both 2.5 μg/ml. Also, compound 3 showed weak antiviral activity against severe acute respiratory syndrome coronavirus 2 main protease, which was responsible for the coronavirus disease 2019 pandemic.

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Why crystal structure analysis works: a one-dimensional crystallography teaching tool

Journal of Applied Crystallography ◽

10.1107/s1600576715007116 ◽

2015 ◽

Vol 48 (3) ◽

pp. 901-905 ◽

Cited By ~ 1

Author(s):

A. Alan Pinkerton

Keyword(s):

Crystal Structure ◽

Structure Analysis ◽

Crystal Structure Analysis ◽

Teaching Tool ◽

One Dimensional ◽

X Ray ◽

X Ray Crystallography ◽

Scientific Calculator ◽

Hypothetical Structure

A teaching tool is proposed to help beginner students of crystallography understand how crystallographic calculations work. Examples of the most important methods taught in X-ray crystallography courses have been adapted to a one-dimensional hypothetical structure. All calculations can be carried out in class with a scientific calculator or by using a simple spreadsheet.

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