scholarly journals Oligomerization of fatty acids as a possible source for high molecular weight hydrocarbons and sulphur-containing compounds in sediments

1992 ◽  
Vol 18 (6) ◽  
pp. 869-880 ◽  
Author(s):  
J.C. Del Rio ◽  
R.P. Philp
1950 ◽  
Vol 28b (9) ◽  
pp. 556-560 ◽  
Author(s):  
F. A. Vandenheuvel ◽  
P. Yates

The Arndt–Eistert reaction offers a convenient method for the synthesis of the higher members of the aliphatic carboxylic acid series. Nonadecanoic acid, eicosanoic acid, and heneicosanoic acid have been prepared successively from stearic acid in good yields. An efficient method of purification of the synthetic products is described. The ultraviolet absorption maxima for some diazoketones derived from the higher members of the aliphatic carboxylic acid series are recorded.


1979 ◽  
Vol 46 (4) ◽  
pp. 633-639 ◽  
Author(s):  
Peter W. Parodi

SummaryNo relationship was found between the trisaturated glyceride content and the softening point (SP) of milk fat. Inter-esterification of milk fat increased its SP, but did not change the trisaturated glyceride content or the fatty acid composition of the trisaturated glyceride fraction. Inter-esterification increased the amount of both low and high and decreased the amount of medium molecular weight triglyceride species in the trisaturated glyceride fraction. The increase in the amount of high molecular weight triglyceride species was up to 3 times greater than the increase in the amount of low molecular weight triglycerides.The triglyceride species composition of the trisaturated glyceride fraction of milk fat was found to vary seasonally. Excellent correlation was found between SP and groups of low molecular weight triglycerides, groups of high molecular weight triglycerides and some individual triglyceride species. Correlation coefficients were higher than those previously reported between groups of fatty acids and SP.


1996 ◽  
Vol 32 (10) ◽  
pp. 1781-1787 ◽  
Author(s):  
A.S. Soydan ◽  
I.A. Tavares ◽  
P.K. Weech ◽  
N.M. Tremblay ◽  
A. Bennett

1965 ◽  
Vol 18 (7) ◽  
pp. 1059 ◽  
Author(s):  
F Radler ◽  
DHS Horn

The cuticle wax of the grape is composed of a soft wax (30%) readily removed by light petroleum and a hard wax (30%), mainly oleanolic acid, removed by chloroform. The soft wax of the fresh grape is composed chiefly of long-chain alcohols together with smaller amounts of aldehydes, esters, fatty acids, hydrocarbons, oleanolic acid, and small amounts of high molecular weight substances. The soft wax of dried grapes is similar in composition but contains no aldehydes and larger amounts of high molecular weight substances and oxidation products. The aldehydes, unusual wax components, are straight chain and range from C16 to C32 with the even chain-lengths predominating. They were destroyed by neutral alumina but can be chromatographed on silicic acid.


2020 ◽  
Vol 3 ◽  
pp. 10-17
Author(s):  
Oleksiy Udovenko ◽  
Fedir Gladkiy ◽  
Ivan Shkredov ◽  
Kateryna Havriushenko ◽  
Olena Litvinenko ◽  
...  

The increased popularity of deep-fried foods has put health and safety concerns on the agenda. Factors that affect the quality and safety of culinary (frying) fats include the fatty acid profile, as well as cooking modes and time, especially when renewal rates are low. The industry is currently facing a top-of-mind technology challenge: to reduce the “oil content” of fried foods by developing a frying fat that would meet up-to-date food production standards. In other words, there is a need for a frying fat, which should last as long as possible without oxidizing and changing colour. Furthermore, its uptake by foods, fried in it, must be 40–50 % less than that of conventional fats. To this end, the authors put forward an innovative technology for producing culinary (frying) fats through esterification of fatty acids with high molecular weight alcohols. The research work that has been carried out so far prove the possibility of producing specialty fats by such modification to the applicable regulatory requirements: the melting range is between 29.6 and 34.65 °С, the acid value is up to 0.4 mg КОН/g. The viscosity of modified fats is lower than that of oils, which is due to the fat structure, and this circumstance will have a positive effect on the fat content in a finished product. The researchers has identified a numerical relationship (expressed as a regression model) of the yield of the desired fraction of a modified fat versus the ratio of reagents, reaction time, and process temperature, as well as calculated rational process parameters. The aim of the research is to develop the technology of obtaining culinary (frying) fats by esterification of fatty acids with high molecular weight alcohols


Author(s):  
B. N. Galkin ◽  
M. O. Finogenova ◽  
А. S. Semenets ◽  
M. B. Galkin ◽  
T. O. Filipova

Marine microorganisms have unique metabolic and physiological characteristics and are an important source of new biomolecules such as biosurfactants. Low molecular weight surfactants are glycolipids, phospholipids, fatty acids, lipopeptides and lipoproteins, and high molecular weight surfactants are mixtures of heteropolysaccharides, lipopolysaccharides, lipoproteins and proteins. The main general of bacteria that synthesize biosurfactants are Pseudomonas, Bacillus, Acinetobacter, Antarctobacter, Rhodococcus, Halomonas, Alcanivorax, Pseudoalteromonas and Marinobacter. This review examines the structure and function of biosurfactants isolated from marine microorganisms.


Sign in / Sign up

Export Citation Format

Share Document