Polymer-graphene composites as flame and fire retardant materials

2022 ◽  
pp. 743-776
Author(s):  
Prashant Gupta ◽  
Subhendu Bhandari
Keyword(s):  
Author(s):  
A. R. Horrocks ◽  
D. Price
Keyword(s):  

Author(s):  
A R Horrocks ◽  
D Price
Keyword(s):  

Author(s):  
Jamey Moss ◽  
Sam Subramanian ◽  
Vince Soorholtz ◽  
Michael Thomas ◽  
Mark Gerber ◽  
...  

Abstract Several hundred units were subjected to autoclave stress as part of the qualification of a new fast static RAM. Many units failed after autoclave stress, and these parts recovered after conventional depotting using nitric acid and a hot plate. Based on the recovery of the units, the failures were determined to be fuse-related because the nitric acid cleared the fuse cavities during depotting. Chemical analysis after thermally extracting the die from the package revealed an antimony-rich material in failing fuse cavities. Source of the antimony was linked to antimony trioxide added to the plastic package as a fire retardant. However, it was unclear whether the antimony-rich material caused the failure or if it was an artifact of thermal depotting. A new approach that did not thermally or chemically alter the fuse cavities was employed to identify the failing fuses. This approach used a combination of back-side grinding, dimpling, and back-side microprobing. The antimony-rich material found in the fuse cavity was confirmed using SEM and TEM-based EDS analysis, and it is believed to be a major contributing factor to fuse failures. However, it is unclear whether the short was caused by the antimony-rich material or by a reaction between that material and residual aluminum (oxide) left in the fuse cavity after the laser blows.


1990 ◽  
Author(s):  
Michelle H. Cooper ◽  
Maurice Roy
Keyword(s):  

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3440
Author(s):  
Mohd Na’im Abdullah ◽  
Mazli Mustapha ◽  
Nabihah Sallih ◽  
Azlan Ahmad ◽  
Faizal Mustapha ◽  
...  

The utilisation of rice husk ash (RHA) as an aluminosilicate source in fire-resistant coating could reduce environmental pollution and can turn agricultural waste into industrial wealth. The overall objective of this research is to develop a rice-husk-ash-based geopolymer binder (GB) fire-retardant additive (FR) for alkyd paint. Response surface methodology (RSM) was used to design the experiments work, on the ratio of RHA-based GB to alkyd paint. The microstructure behaviour and material characterisation of the coating samples were studied through SEM analysis. The optimal RHA-based GB FR additive was formulated at 50% wt. FR and 82.628% wt. paint. This formulation showed the result of 270 s to reach 200 °C and 276 °C temperature at equilibrium for thermal properties. Furthermore, it was observed that the increased contents of RHA showed an increment in terms of the total and open porosities and rough surfaces, in which the number of pores on the coating surface plays an important role in the formation of the intumescent char layer. By developing the optimum RHA-based GB to paint formulation, the coating may potentially improve building fire safety through passive fire protection.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1282
Author(s):  
M.J. Suriani ◽  
Fathin Sakinah Mohd Radzi ◽  
R.A. Ilyas ◽  
Michal Petrů ◽  
S.M. Sapuan ◽  
...  

Oil palm empty fruit bunches (OPEFB) fiber is a natural fiber that possesses many advantages, such as biodegradability, eco-friendly, and renewable nature. The effect of the OPEFB fiber loading reinforced fire retardant epoxy composites on flammability and tensile properties of the polymer biocomposites were investigated. The tests were carried out with four parameters, which were specimen A (constant), specimen B (20% of fiber), specimen C (35% of fiber), and specimen D (50% of fiber). The PET yarn and magnesium hydroxide were used as the reinforcement material and fire retardant agent, respectively. The results were obtained from several tests, which were the horizontal burning test, tensile test, and scanning electron microscopy (SEM). The result for the burning test showed that specimen B exhibited better flammability properties, which had the lowest average burning rate (11.47 mm/min). From the tensile strength, specimen A revealed the highest value of 10.79 N/mm2. For the SEM morphological test, increasing defects on the surface ruptured were observed that resulted in decreased tensile properties of the composites. It can be summarized that the flammability and tensile properties of OPEFB fiber reinforced fire retardant epoxy composites were reduced when the fiber volume contents were increased at the optimal loading of 20%, with the values of 11.47 mm/min and 4.29 KPa, respectively.


2021 ◽  
Vol 11 (6) ◽  
pp. 2521
Author(s):  
Feng Jiang ◽  
Jianyong Liu ◽  
Wei Yuan ◽  
Jianbo Yan ◽  
Lin Wang ◽  
...  

Improving the fire resistance of the key cables connected to firefighting and safety equipment is of great importance. Based on the engineering practice of an oil storage company, this study proposes a modification scheme that entails spraying fire-retardant coatings on the outer surface of a cable tray to delay the failure times of the cables in the tray. To verify the effect, 12 specimens were processed using five kinds of fire-retardant coatings and two kinds of fire-resistant cotton to coat the cable tray. The specimens were installed in the vertical fire resistance test furnace. For the ISO 834 standard fire condition, a fire resistance test was carried out on the specimens. The data for the surface temperature and the insulation resistance of the cables in trays were collected, and the fireproof effect was analyzed. The results showed that compared with the control group, the failure time of the cable could be delayed by 1.57–14.86 times, and the thicker the fire-retardant coatings were, the better the fireproof effect was. In general, the fire protection effect of the fire-retardant coating was better than that of the fire-resistant cotton.


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