Study on Manufacturing Environmentally Friendly Alkyd Paint

The article presents results of studying and manufacturing environmentally friendly alkyd paint. By producing a polysaccharide intermediate emulsion (LPR), about 20% of water to total paint volume was added. Mechanical properties (impact resistance, flexural strength, adhesion) of paint films were studied. In addition, the paper presents results of thermal stability, 10-cycle UV-thermo-humidity complex stability of paint film. Ability of films to withstand 03-cycle heat shocking of films at temperatures of + 50 oC and -50 oC was investigated. The properties of studying paint were compared with those of an alkyd paint of Hanoi Synthetic Paint Company. Results show that the environmentally friendly alkyd paint has less volatile organic compounds (VOC), uses a smaller amount of toxic solvents, while its properties are comparable to common alkyd paint.

New coating formulation based on synthesized benzodiazepine derivatives as double function additives for industrial application

Purpose The purpose of this study is to develop a new protective coating formulation for industrial use, using benzodiazepine derivatives as double function additives. Design/methodology/approach Benzodiazepine’s derivatives of types (3–5) were prepared and confirmed by infrared, Mass, 1H-Proton nuclear magnetic resonance (NMR) and 13C NMR spectra. The synthesized compound was physically incorporated in the alkyd paint formulation by pebble mill grinding until all particulates are smaller than 20 ums. The prepared coatings were applied by air spray on steel panels. The physical, mechanical characteristics, corrosion resistance and antimicrobial test of the prepared coatings were studied to evaluate the prepared compounds drawbacks. Findings The results of the mechanical and physical properties of the paint formulation revealed that the paint formulation incorporating benzodiazepines derivatives 3–5 performed best and improved corrosion-resistance and antibacterial activity tests. Research limitations/implications In alkyd paint, heterocyclic compounds are the most used antibacterial additives. Other functionalities of these compounds, such as corrosion inhibitors, might be studied to see if they are suited for these applications. Practical implications Because of the activity of various benzodiazepine derivatives, which may be attributable to the presence of some function groups such as sulfonamide aromatic amino NH2 group, and elements such as Sulphur, Nitrogen, Chlorine, in its chemical structure. As a result, paint compositions including these compounds as additives can be used as dual-purpose paint and for a variety of industrial applications. Originality/value The research demonstrates how a low-cost paint composition based on synthesized benzodiazepine derivatives 3–5 may be used as a dual-function paint for industrial use.

Substrate Cleaning Threshold for Various Coated Al Alloys Using a Continuous-Wave Laser

In this study, different coatings (gray epoxy primer, white epoxy varnish and red alkyd paint) of 7075 aluminum alloy are cleaned with a 500 W continuous-wave (CW) fiber laser. We analyzed the influence of the laser power density on the temperature evolution and target surface morphology. Under the condition of continuous laser irradiation for 1 s, the experimental results indicated that the suitable cleaning thresholds of epoxy primer, epoxy primer and epoxy varnish, as well as epoxy primer, epoxy varnish and alkyd paint were 177.74, 192.89 and 147.44 W/mm2. The results show that the cleaning threshold of thicker three-layer paint target was smaller than the single-layer paint layer, and we analyze the mechanism of this phenomenon.

Optimization of titanium dioxide wetting in alkyd paint and varnish materials in the presence of surfactants

This paper reports the results of studying the influence of surfactants (SAS) on the wetting of titanium dioxide in alkyd paint and varnish materials (PVM), based on pentaphthalic (PPh) and alkyd-urethane (AU) film-forming substances. Edge wetting angle (θ°) and adhesion work (Wa) were used as the criteria for assessing the wettability of titanium dioxide. Three additives were used as SAS: the original product AS-1, obtained from waste of oil refining (with low cost), and industrial additives: "Telaz" and polyethylene polyamine (PEPA). All the studied additives in PPh and AU PVM improve the wetting of titanium dioxide. At the 30 % content of AS film-forming substance in the composition, the maximum decrease in θ° for AS-1 is 4.5°, for PEPA and Telaz it is 4°. For pentaphthalic composition under similar conditions, a decrease in edge wetting angle for AS-1 is 10 °, for Telaz 8.6°, and for PEPA 5.9°. According to the relative change in edge wetting angle for both systems, the maximum decrease in θ° is about 10 %. The introduction of SAS into the composition of AU ambiguously affects the adhesion work, for PPh, the introduction of SAS causes a decrease in adhesion work (Wa). AS-1 is the SAS that minimally reduces adhesion work. The compositions of the PVM by the method of probabilistic-deterministic planning, which ensures maximum wetting of titanium dioxide with film-forming solutions, were analyzed. The equations for calculating the edge angle of wetting of titanium dioxide depending on the content of solvent and the SAS in the PVM were derived. The effectiveness of the AS-1 product as a wetting additive for alkyd paints and varnishes was proven. The wetting ability of the original SAS – AS-1 is close to industrial additives PEPA and Telaz.

Study and Use of Rice Husk Ash as a Source of Aluminosilicate in Refractory Coating

The utilisation of rice husk ash (RHA) as an aluminosilicate source in fire-resistant coating could reduce environmental pollution and can turn agricultural waste into industrial wealth. The overall objective of this research is to develop a rice-husk-ash-based geopolymer binder (GB) fire-retardant additive (FR) for alkyd paint. Response surface methodology (RSM) was used to design the experiments work, on the ratio of RHA-based GB to alkyd paint. The microstructure behaviour and material characterisation of the coating samples were studied through SEM analysis. The optimal RHA-based GB FR additive was formulated at 50% wt. FR and 82.628% wt. paint. This formulation showed the result of 270 s to reach 200 °C and 276 °C temperature at equilibrium for thermal properties. Furthermore, it was observed that the increased contents of RHA showed an increment in terms of the total and open porosities and rough surfaces, in which the number of pores on the coating surface plays an important role in the formation of the intumescent char layer. By developing the optimum RHA-based GB to paint formulation, the coating may potentially improve building fire safety through passive fire protection.

A Photolabile Fe Catalyst for Light-Triggered Alkyd Paint Curing

In search for cobalt replacements for alkyd paint curing we show that the photo-active complex [(Cp)Fe(C₆H₆)]+ (Cp = cyclopentadienyl) acts as a latent catalytic drier that allows for photochemical control over the onset of curing, without the need for anti-skinning agents such as the volatile MEKO normally used to prevent curing during paint storage. The highly soluble neutral complex [(Cp)Fe(Ch)] (Ch = cyclohexadienyl) readily converts to the photo-active complex [(Cp)Fe(C₆H₆)]⁺ upon oxidation in alkyd, allowing the latter to be dosed in a wide range of concentrations. Infrared and Raman studies show similar spectral changes of the alkyd paint matrix as have been observed in alkyd curing mediated by the known commercial cobalt- and manganese-based driers Durham NUODEX® Cobalt 10 Neo and NUODEX® DryCoat. The new [(Cp)Fe(Ch)] / [(Cp)Fe(C₆H₆)]⁺ system performs equally well as both commercial paint driers in terms of drying time, and outperforms NUODEX® DryCoat by showing a hardness development (increase) similar to the cobalt-based drier. Based on an observed light-dark on/off effect and EPR studies we propose that photolysis of [(Cp)Fe(C₆H₆)]+ generates short-lived active Fe^II species, explaining the excellent latency. The novel alkyd curing system [(Cp)Fe(Ch)] / [(Cp)Fe(C₆H₆)]⁺ presented herein is the first example of an intrinsically latent paint curing catalyst that is: (1) based on an abundant and harmless transition metal (Fe), (2) doesn’t require any anti-skinning agents, and (3) shows excellent performance in terms of drying times and hardness development. <br>

A Photolabile Fe Catalyst for Light-Triggered Alkyd Paint Curing

In search for cobalt replacements for alkyd paint curing we show that the photo-active complex [(Cp)Fe(C₆H₆)]+ (Cp = cyclopentadienyl) acts as a latent catalytic drier that allows for photochemical control over the onset of curing, without the need for anti-skinning agents such as the volatile MEKO normally used to prevent curing during paint storage. The highly soluble neutral complex [(Cp)Fe(Ch)] (Ch = cyclohexadienyl) readily converts to the photo-active complex [(Cp)Fe(C₆H₆)]⁺ upon oxidation in alkyd, allowing the latter to be dosed in a wide range of concentrations. Infrared and Raman studies show similar spectral changes of the alkyd paint matrix as have been observed in alkyd curing mediated by the known commercial cobalt- and manganese-based driers Durham NUODEX® Cobalt 10 Neo and NUODEX® DryCoat. The new [(Cp)Fe(Ch)] / [(Cp)Fe(C₆H₆)]⁺ system performs equally well as both commercial paint driers in terms of drying time, and outperforms NUODEX® DryCoat by showing a hardness development (increase) similar to the cobalt-based drier. Based on an observed light-dark on/off effect and EPR studies we propose that photolysis of [(Cp)Fe(C₆H₆)]+ generates short-lived active Fe^II species, explaining the excellent latency. The novel alkyd curing system [(Cp)Fe(Ch)] / [(Cp)Fe(C₆H₆)]⁺ presented herein is the first example of an intrinsically latent paint curing catalyst that is: (1) based on an abundant and harmless transition metal (Fe), (2) doesn’t require any anti-skinning agents, and (3) shows excellent performance in terms of drying times and hardness development. <br>

First Evidence of Retrospective Findings of Microplastics in Harbour Porpoises (Phocoena phocoena) From German Waters

Microplastic ingestion by lower trophic level organisms is well known, whereas information on microplastic ingestion, egestion and accumulation by top predators such as cetaceans is still lacking. This study investigates microplastics in intestinal samples from harbour porpoises (Phocoena phocoena) found along the coastline of Schleswig-Holstein (Germany) between 2014 and 2018. Out of 30 individuals found along the North Sea (NS) and the Baltic Sea (BS) coast, 28 specimens contained microplastic. This study found a relationship between the nutritional status of cetaceans and the amount of found microplastics. Harbour porpoises with a good or moderate nutritional status contained a higher number of microplastics, when compared with specimens in a poor nutritional status. In addition, when individuals died accidently due to suspected bycatch in gillnets, where a feeding event is highly assumed or a pharyngeal entrapment happened, the microplastic burden was higher. In total, 401 microplastics (≥100 μm), including 202 fibres and 199 fragments were found. Intestines of the specimens of the BS contained more microplastics than the ones from the NS. Differences in the share of fibres could be revealed: for BS fibres constituted 51.44% and for NS, fibres constituted 47.97%. The polymers polyester, polyethylene, polypropylene, polyamide, acrylic (with nitrile component) and an acrylic/alkyd paint chip (with styrene and kaolin components) were identified. This is the first study investigating the occurrence of microplastics in harbour porpoises from German waters and will, thus, provide valuable information on the actual burden of microplastics in cetaceans from the North and Baltic Seas.