In this work, two carbazole- and benzo[d]oxazole-based novel multifunctional materials with hybridized local and charge-transfer (HLCT) characteristic, namely OCI and OCT, which could act as deep-blue fluorophors and phosphorescent hosts,...
ABSTRACTPolycerams are an emergent class of hybrid, multifunctional materials which combine the properties of organic and inorganic materials. Films have been prepared from silicon alkoxides and reactive, functionalized polymers such as triethoxysilyl modified polybutadiene (MPBD), (N-triethoxysilylpropyl)O polyethylene oxide urethane (MPEOU) and trimethoxysilylpropyl substituted polyethyleneimine (MPEI). Characterization of dielectric constant and tan δ of the films has been carried out over a range of frequency from 500 Hz to 100 kHz; and the results are used to consider the potential of Polycerams as dielectric materials.
A variety of molecular chemistry approaches are currently investigated for tailoring the physico-chemical properties of ultrathin transition metal dichalcogenides towards novel hybrid multifunctional materials and devices.