Room-temperature processed tin oxide thin film as effective hole blocking layer for planar perovskite solar cells

2018 ◽  
Vol 434 ◽  
pp. 1336-1343 ◽  
Author(s):  
Hong Tao ◽  
Zhibin Ma ◽  
Guang Yang ◽  
Haoning Wang ◽  
Hao Long ◽  
...  
Coatings ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 314 ◽  
Author(s):  
Haiyan Ren ◽  
Xiaoping Zou ◽  
Jin Cheng ◽  
Tao Ling ◽  
Xiao Bai ◽  
...  

The hole blocking layer plays an important role in suppressing recombination of holes and electrons between the perovskite layer and fluorine-doped tin oxide (FTO). Morphological defects, such as cracks, at the compact TiO2 hole blocking layer due to rough FTO surface seriously affect performance of perovskite solar cells (PSCs). Herein, we employ a simple spin-coating SnO2 thin film solution to cover cracks of TiO2 hole blocking layer for PSCs. The experiment results indicate that the TiO2/SnO2 complementary composite hole blocking layer could eliminate the serious electrical current leakage existing inside the device, extremely reducing interface defects and hysteresis. Furthermore, a high efficiency of 13.52% was achieved for the device, which is the highest efficiency ever recorded in PSCs with spongy carbon film deposited on a separated FTO-substrate as composite counter electrode under one sun illumination.


A compact hole blocking layer is necessary for high efficient perovskite solar cell, which was usually fabricated by spin coating or spray pyrolysis with the followed annealing process, or vacuum deposition. Here, we deposited TiO2 compact layers by an in-situ room-temperature solvent method, which were applied as an effective hole blocking layer for hole-conductor-free perovskite solar cells with carbon electrodes. The thickness of the TiO2 compact layer can be easily regulated by the depositing time. By optimizing the TiO2 depositing time, the power conversion efficiency of hole-conductor-free perovskite solar cells was up to 10.66%.


Coatings ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 320 ◽  
Author(s):  
Wenhai Sun ◽  
Shuo Wang ◽  
Shina Li ◽  
Xu Miao ◽  
Yu Zhu ◽  
...  

Currently, tin oxide (SnO2) is a highly sought-after semiconductor material used in perovskite solar cells (PSCs) because of its good transmittance, the appropriate energy level, high electron mobility, high conductivity, ideal band gap and excellent chemical stability. In this study, SnO2 film was successfully prepared by radio frequency reactive magnetron sputtering (RS) under room temperature conditions. The obtained SnO2 thin films not only exhibited high transmittance in the visible region as well as the pure phase, but also had a suitable energy band structure and lower surface roughness than FTO (SnO2:F) glass substrate, which contributes to the improvement of the adjacent interface morphology. The SnO2 films prepared by reactive sputtering could effectively suppress carrier recombination and act as an electron transport layer. Moreover, the maximum efficiency of the device based on reactive sputtering of SnO2 as the electron transport layer (ETL) for planar perovskite solar cells (PSCs) was 14.63%. This study mainly described the preparation of SnO2 by reactive sputtering under room temperature conditions.


2012 ◽  
Vol 482-484 ◽  
pp. 394-397
Author(s):  
Ming Wei Li ◽  
Nan Hai Sun ◽  
Yun Wang Ge ◽  
Bo Lei Yao

This paper presents a new buffering layer(nickle oxide thin film) of organic solar cells. Nickle Oxide(NiO) thin film is a good alternative of hole tansporting layer. We investigates the film from physical and electrical aspects, such as morphology, deposition temperature, thickness etc. We find that the optimum fabrication conditions are: room temperature deposition, 10nm of thickness, and 30% oxygen proportion. The device strcture is Anode/NiO/P3HT[regioregular of poly(3-hexylthiophene)]: PCBM[(6,6)-phenyl C61 butyric acid methyl ester] /Al. And the best power conversion efficiency of device we got with NiO buffering layer is 2.49%, which is hundred times of ones without NiO buffering layer.


2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Weijun Ke ◽  
Guojia Fang ◽  
Jiawei Wan ◽  
Hong Tao ◽  
Qin Liu ◽  
...  

Solar RRL ◽  
2018 ◽  
Vol 2 (8) ◽  
pp. 1800072 ◽  
Author(s):  
Ming-Chung Wu ◽  
Ying-Han Liao ◽  
Shun-Hsiang Chan ◽  
Chun-Fu Lu ◽  
Wei-Fang Su

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