The impact of liquefied petroleum gas usage on air quality in Mexico City

Abstract. The impact of Mexico City (MCMA) emissions is examined by studying its effects on air quality, photochemistry, and on ozone production regimes by combining model products and aircraft observations from the MILAGRO experiment during March 2006. The modeled influence of MCMA emissions to enhancements in surface level NOx, CO, and O3 concentrations (10–30% increase) are confined to distances <200 km, near surface. However, the extent of the influence is significantly larger at higher altitudes. Broader MCMA impacts (some 900 km Northeast of the city) are shown for specific outflow conditions in which enhanced ozone, NOy, and MTBE mixing ratios over the Gulf of Mexico are linked to MCMA by source tagged tracers and sensitivity runs. This study shows that the "footprint" of MCMA on average is fairly local, with exception to reactive nitrogen, which can be transported long range in the form of PAN, acting as a reservoir and source of NOx with important regional ozone formation implications. The simulated effect of MCMA emissions of anthropogenic aerosol on photochemistry showed a maximum regional decrease of 40% in J[NO2→NO+O], and resulting in the reduction of ozone production by 5–10%. Observed ozone production efficiencies are evaluated as a function of distance from MCMA, and by modeled influence from MCMA. These tend to be much lower closer to MCMA, or in those points where modeled contribution from MCMA is large. This research shows that MCMA emissions do effect on regional air quality and photochemistry, both contributing large amounts of ozone and its precursors, but with caveat that aerosol concentrations hinder formation of ozone to its potential due to its reduction in photolysis rates.

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Urban Leakage of Liquefied Petroleum Gas and Its Impact on Mexico City Air Quality

Science ◽

10.1126/science.269.5226.953 ◽

1995 ◽

Vol 269 (5226) ◽

pp. 953-956 ◽

Cited By ~ 210

Author(s):

D. R. Blake ◽

F. S. Rowland

Keyword(s):

Air Quality ◽

Mexico City ◽

Liquefied Petroleum Gas

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Basin-scale wind transport during the MILAGRO field campaign and comparison to climatology using cluster analysis

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-7-13035-2007 ◽

2007 ◽

Vol 7 (5) ◽

pp. 13035-13076 ◽

Cited By ~ 1

Author(s):

B. de Foy ◽

J. D. Fast ◽

S. J. Paech ◽

D. Phillips ◽

J. T. Walters ◽

...

Keyword(s):

Air Pollution ◽

Cluster Analysis ◽

Air Quality ◽

Mexico City ◽

Atmospheric Chemistry ◽

Quality Data ◽

Field Campaign ◽

Urban Impacts ◽

Basin Scale ◽

The Impact

Abstract. The MILAGRO field campaign was a multi-agency international collaborative project to evaluate the regional impacts of the Mexico City air pollution plume as a means of understanding urban impacts on the global climate. Mexico City lies on an elevated plateau with mountains on three sides and has complex mountain and surface-driven wind flows. This paper asks what the wind transport was in the basin during the field campaign and how representative it was of the climatology. Surface meteorology and air quality data, radiosoundings and radar wind profiler data were collected at sites in the basin and its vicinity. Cluster analysis is used to identify the dominant wind patterns both during the campaign and within the past 10 years of operational data from the warm dry season. Our analysis shows that March 2006 was representative of typical flow patterns experienced in the basin. Six episode types were identified for the basin scale circulation providing a way of interpreting atmospheric chemistry and particulate data collected during the campaign. Decoupling between surface winds and those aloft had a strong influence in leading to convection and poor air quality episodes. Hourly characterisation of wind circulation during the MILAGRO, MCMA-2003 and IMADA field campaigns will enable the comparisons of similar air pollution episodes and the evaluation of the impact of wind transport on measurements of the atmospheric chemistry taking place in the basin.

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Assessing the regional impacts of Mexico City emissions on air quality and chemistry

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-8-20283-2008 ◽

2008 ◽

Vol 8 (6) ◽

pp. 20283-20309 ◽

Cited By ~ 2

Author(s):

M. Mena-Carrasco ◽

G. R. Carmichael ◽

J. E. Campbell ◽

D. Zimmerman ◽

Y. Tang ◽

...

Keyword(s):

Air Quality ◽

Mexico City ◽

Ozone Production ◽

Anthropogenic Aerosol ◽

Mixing Ratios ◽

Regional Impacts ◽

Photolysis Rates ◽

Discernible Effect ◽

Regional Air Quality ◽

The Impact

Abstract. The impact of Mexico City (MCMA) emissions is examined by studying its effects on air quality, photochemistry, and on ozone production regimes by combining model products and aircraft observations from the MILAGRO experiment. The influence of MCMA emissions to enhancements in surface level NOx, CO, and O3 concentrations are confined to distances <200 km. However, the extent of the influence is significantly larger at higher altitudes. Broader MCMA impacts (some 900 km Northeast of the city) are shown for specific outflow conditions in which enhanced ozone, NOy, and MTBE mixing ratios over the Gulf of Mexico are linked to MCMA by source tagged tracers and sensitivity runs. This study shows that the "footprint" of MCMA on average is fairly local, with exception to reactive nitrogen, which can be transported long range in the form of PAN, acting as a reservoir and source of NOx with important regional ozone formation implications. The simulated effect of MCMA emissions of anthropogenic aerosol on photochemistry showed a maximum regional decrease of 40% in J[NO2→NO+O], and resulting in the reduction of ozone production by 5–10%. Observed ozone production efficiencies and photolysis rates are evaluated as a function of distance from MCMA, and by modeled influence from MCMA. These tend to be much lower closer to MCMA, and with higher MCMA influence. This research shows that MCMA emissions have a discernible effect on regional air quality and photochemistry, both contributing large amounts of ozone and its precursors, but with caveat that aerosol concentrations hinder formation of ozone to its potential due to its reduction in photolysis rates.

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Impact of the COVID-19 Lockdown on Air Quality and Resulting Public Health Benefits in the Mexico City Metropolitan Area

Frontiers in Public Health ◽

10.3389/fpubh.2021.642630 ◽

2021 ◽

Vol 9 ◽

Author(s):

Iván Y. Hernández-Paniagua ◽

S. Ivvan Valdez ◽

Victor Almanza ◽

Claudia Rivera-Cárdenas ◽

Michel Grutter ◽

...

Keyword(s):

Air Quality ◽

Mexico City ◽

Air Pollutant ◽

Satellite Observations ◽

Phase 2 ◽

Phase 3 ◽

Pollutant Concentrations ◽

Long Term Trends ◽

The Impact

Meteorology and long-term trends in air pollutant concentrations may obscure the results from short-term policies implemented to improve air quality. This study presents changes in CO, NO2, O3, SO2, PM10, and PM2.5 based on their anomalies during the COVID-19 partial (Phase 2) and total (Phase 3) lockdowns in Mexico City (MCMA). To minimise the impact of the air pollutant long-term trends, pollutant anomalies were calculated using as baseline truncated Fourier series, fitted with data from 2016 to 2019, and then compared with those from the lockdown. Additionally, days with stagnant conditions and heavy rain were excluded to reduce the impact of extreme weather changes. Satellite observations for NO2 and CO were used to contrast the ground-based derived results. During the lockdown Phase 2, only NO2 exhibited significant decreases (p < 0.05) of between 10 and 23% due to reductions in motor vehicle emissions. By contrast, O3 increased (p < 0.05) between 16 and 40% at the same sites where NO2 decreased. During Phase 3, significant decreases (p < 0.05) were observed for NO2 (43%), PM10 (20%), and PM2.5 (32%) in response to the total lockdown. Although O3 concentrations were lower in Phase 3 than during Phase 2, those did not decrease (p < 0.05) from the baseline at any site despite the total lockdown. SO2 decreased only during Phase 3 in a near-road environment. Satellite observations confirmed that NO2 decreased and CO stabilised during the total lockdown. Air pollutant changes during the lockdown could be overestimated between 2 and 10-fold without accounting for the influences of meteorology and long-term trends in pollutant concentrations. Air quality improved significantly during the lockdown driven by reduced NO2 and PM2.5 emissions despite increases in O3, resulting in health benefits for the MCMA population. A health assessment conducted suggested that around 588 deaths related to air pollution exposure were averted during the lockdown. Our results show that to reduce O3 within the MCMA, policies must focus on reducing VOCs emissions from non-mobile sources. The measures implemented during the COVID-19 lockdowns provide valuable information to reduce air pollution through a range of abatement strategies for emissions other than from motor vehicles.

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Basin-scale wind transport during the MILAGRO field campaign and comparison to climatology using cluster analysis

Atmospheric Chemistry and Physics ◽

10.5194/acp-8-1209-2008 ◽

2008 ◽

Vol 8 (5) ◽

pp. 1209-1224 ◽

Cited By ~ 114

Author(s):

B. de Foy ◽

J. D. Fast ◽

S. J. Paech ◽

D. Phillips ◽

J. T. Walters ◽

...

Keyword(s):

Air Pollution ◽

Cluster Analysis ◽

Air Quality ◽

Mexico City ◽

Atmospheric Chemistry ◽

Quality Data ◽

Field Campaign ◽

Urban Impacts ◽

Basin Scale ◽

The Impact

Abstract. The MILAGRO field campaign was a multi-agency international collaborative project to evaluate the regional impacts of the Mexico City air pollution plume as a means of understanding urban impacts on the global climate. Mexico City lies on an elevated plateau with mountains on three sides and has complex mountain and surface-driven wind flows. This paper asks what the wind transport was in the basin during the field campaign and how representative it was of the climatology. Surface meteorology and air quality data, radiosondes and radar wind profiler data were collected at sites in the basin and its vicinity. Cluster analysis was used to identify the dominant wind patterns both during the campaign and within the past 10 years of operational data from the warm dry season. Our analysis shows that March 2006 was representative of typical flow patterns experienced in the basin. Six episode types were identified for the basin-scale circulation providing a way of interpreting atmospheric chemistry and particulate data collected during the campaign. Decoupling between surface winds and those aloft had a strong influence in leading to convection and poor air quality episodes. Hourly characterisation of wind circulation during the MILAGRO, MCMA-2003 and IMADA field campaigns enables the comparisons of similar air pollution episodes and the evaluation of the impact of wind transport on measurements of the atmospheric chemistry taking place in the basin.

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The impact of measures to reduce ambient air PM<sub>10</sub> concentrations originating from road dust, evaluated for a street canyon in Helsinki

Atmospheric Chemistry and Physics ◽

10.5194/acp-19-11199-2019 ◽

2019 ◽

Vol 19 (17) ◽

pp. 11199-11212 ◽

Cited By ~ 1

Author(s):

Ana Stojiljkovic ◽

Mari Kauhaniemi ◽

Jaakko Kukkonen ◽

Kaarle Kupiainen ◽

Ari Karppinen ◽

...

Keyword(s):

Particulate Matter ◽

Air Quality ◽

Street Canyon ◽

Dust Emission ◽

Road Dust ◽

Ambient Air ◽

Air Quality Measurements ◽

Emission Models ◽

The Impact ◽

Quality Measurements

Abstract. We have numerically evaluated how effective selected potential measures would be for reducing the impact of road dust on ambient air particulate matter (PM10). The selected measures included a reduction of the use of studded tyres on light-duty vehicles and a reduction of the use of salt or sand for traction control. We have evaluated these measures for a street canyon located in central Helsinki for four years (2007–2009 and 2014). Air quality measurements were conducted in the street canyon for two years, 2009 and 2014. Two road dust emission models, NORTRIP (NOn-exhaust Road TRaffic Induced Particle emissions) and FORE (Forecasting Of Road dust Emissions), were applied in combination with the Operational Street Pollution Model (OSPM), a street canyon dispersion model, to compute the street increments of PM10 (i.e. the fraction of PM10 concentration originating from traffic emissions at the street level) within the street canyon. The predicted concentrations were compared with the air quality measurements. Both road dust emission models reproduced the seasonal variability of the PM10 concentrations fairly well but under-predicted the annual mean values. It was found that the largest reductions of concentrations could potentially be achieved by reducing the fraction of vehicles that use studded tyres. For instance, a 30 % decrease in the number of vehicles using studded tyres would result in an average decrease in the non-exhaust street increment of PM10 from 10 % to 22 %, depending on the model used and the year considered. Modelled contributions of traction sand and salt to the annual mean non-exhaust street increment of PM10 ranged from 4 % to 20 % for the traction sand and from 0.1 % to 4 % for the traction salt. The results presented here can be used to support the development of optimal strategies for reducing high springtime particulate matter concentrations originating from road dust.

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Ground-Based MAX-DOAS Observations of Tropospheric NO2 and HCHO During COVID-19 Lockdown and Spring Festival Over Shanghai, China

Remote Sensing ◽

10.3390/rs13030488 ◽

2021 ◽

Vol 13 (3) ◽

pp. 488

Author(s):

Aimon Tanvir ◽

Zeeshan Javed ◽

Zhu Jian ◽

Sanbao Zhang ◽

Muhammad Bilal ◽

...

Keyword(s):

Air Quality ◽

Anthropogenic Activities ◽

Anthropogenic Activity ◽

Hysplit Model ◽

Vertical Column ◽

Weekly Cycle ◽

Spring Festival ◽

Level 1 ◽

Reduced Mobility ◽

The Impact

Reduced mobility and less anthropogenic activity under special case circumstances over various parts of the world have pronounced effects on air quality. The objective of this study is to investigate the impact of reduced anthropogenic activity on air quality in the mega city of Shanghai, China. Observations from the highly sophisticated multi-axis differential optical absorption spectroscope (MAX-DOAS) instrument were used for nitrogen dioxide (NO2) and formaldehyde (HCHO) column densities. In situ measurements for NO2, ozone (O3), particulate matter (PM2.5) and the air quality index (AQI) were also used. The concentration of trace gases in the atmosphere reduces significantly during annual Spring Festival holidays, whereby mobility is reduced and anthropogenic activities come to a halt. The COVID-19 lockdown during 2020 resulted in a considerable drop in vertical column densities (VCDs) of HCHO and NO2 during lockdown Level-1, which refers to strict lockdown, i.e., strict measures taken to reduce mobility (43% for NO2; 24% for HCHO), and lockdown Level-2, which refers to relaxed lockdown, i.e., when the mobility restrictions were relaxed somehow (20% for NO2; 22% for HCHO), compared with pre-lockdown days, as measured by the MAX-DOAS instrument. However, for 2019, a reduction in VCDs was found only during Level-1 (24% for NO2; 6.62% for HCHO), when the Spring Festival happened. The weekly cycle for NO2 and HCHO depicts no significant effect of weekends on the lockdown. After the start of the Spring Festival, the VCDs of NO2 and HCHO showed a decline for 2019 as well as 2020. Backward trajectories calculated using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model indicated more air masses coming from the sea after the Spring Festival for 2019 and 2020, implying that a low pollutant load was carried by them. No impact of anthropogenic activity was found on O3 concentration. The results indicate that the ratio of HCHO to NO2 (RFN) fell in the volatile organic compound (VOC)-limited regime.

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Effects of Climatic Conditions, Season and Environmental Factors on CO2 Concentrations in Naturally Ventilated Primary Schools in Chile

Sustainability ◽

10.3390/su13084139 ◽

2021 ◽

Vol 13 (8) ◽

pp. 4139

Author(s):

Muriel Diaz ◽

Mario Cools ◽

Maureen Trebilcock ◽

Beatriz Piderit-Moreno ◽

Shady Attia

Keyword(s):

Air Quality ◽

Indoor Air Quality ◽

Indoor Air ◽

Primary Schools ◽

Co2 Concentration ◽

Building Design ◽

Climatic Conditions ◽

Indoor Environmental Quality ◽

Co2 Concentrations ◽

The Impact

Between the ages of 6 and 18, children spend between 30 and 42 h a week at school, mostly indoors, where indoor environmental quality is usually deficient and does not favor learning. The difficulty of delivering indoor air quality (IAQ) in learning facilities is related to high occupancy rates and low interaction levels with windows. In non-industrialized countries, as in the cases presented, most classrooms have no mechanical ventilation, due to energy poverty and lack of normative requirements. This fact heavily impacts the indoor air quality and students’ learning outcomes. The aim of the paper is to identify the factors that determine acceptable CO2 concentrations. Therefore, it studies air quality in free-running and naturally ventilated primary schools in Chile, aiming to identify the impact of contextual, occupant, and building design factors, using CO2 concentration as a proxy for IAQ. The monitoring of CO2, temperature, and humidity revealed that indoor air CO2 concentration is above 1400 ppm most of the time, with peaks of 5000 ppm during the day, especially in winter. The statistical analysis indicates that CO2 is dependent on climate, seasonality, and indoor temperature, while it is independent of outside temperature in heated classrooms. The odds of having acceptable concentrations of CO2 are bigger when indoor temperatures are high, and there is a need to ventilate for cooling.

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Association of temporary Environmental Protection Agency regulation suspension with industrial economic viability and local air quality in California, United States

Environmental Sciences Europe ◽

10.1186/s12302-021-00489-9 ◽

2021 ◽

Vol 33 (1) ◽

Author(s):

Emily Chang ◽

Kenneth Zhang ◽

Margaret Paczkowski ◽

Sara Kohler ◽

Marco Ribeiro

Keyword(s):

United States ◽

Air Quality ◽

Environmental Protection ◽

Environmental Protection Agency ◽

Manufacturing Industry ◽

Economic Viability ◽

Treatment Control ◽

Oil Refineries ◽

Pollution Levels ◽

The Impact

Abstract Background This study seeks to answer two questions about the impacts of the 2020 Environmental Protection Agency’s enforcement regulation rollbacks: is this suspension bolstering the economic viability of industries as oil and manufacturing executives claim they will and are these regulations upholding the agency’s mission of protecting the environment? Results To answer the former question, we utilized 6 months of state employment level data from California, United States, as a method of gauging the economic health of agency-regulated industries. We implemented a machine learning model to predict weekly employment data and a t-test to indicate any significant changes in employment. We found that, following California's state-issued stay-at-home order and the agency’s regulation suspension, oil and certain manufacturing industries had statistically significant lower employment values. To answer the latter question, we used 10 years of PM2.5 levels in California, United States, as a metric for local air quality and treatment–control county pairs to isolate the impact of regulation rollbacks from the impacts of the state lockdown. Using the agency’s data, we performed a t-test to determine whether treatment–control county pairs experienced a significant change in PM2.5 levels. Even with the statewide lockdown—a measure we hypothesized would correlate with decreased mobility and pollution levels—in place, counties with oil refineries experienced the same air pollution levels when compared to historical data averaged from the years 2009 to 2019. Conclusions In contrast to the expectation that the suspension would improve the financial health of the oil and manufacturing industry, we can conclude that these industries are not witnessing economic growth with the suspension and state shutdown in place. Additionally, counties with oil refineries could be taking advantage of these rollbacks to continue emitting the same amount of PM2.5, in spite of state lockdowns. For these reasons, we ask international policymakers to reconsider the suspension of enforcement regulations as these actions do not fulfill their initial expectations. We recommend the creation and maintenance of pollution control and prevention programs that develop emission baselines, mandate the construction of pollution databases, and update records of pollution emissions.

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