Rapid and efficient adsorption of tetracycline from aqueous solution in a wide pH range by using iron and aminoacetic acid sequentially modified hierarchical porous biochar

2022 ◽  
pp. 126672
Author(s):  
Xiumin Li ◽  
Jinlan Xu ◽  
Jingxin Shi ◽  
Xianxin Luo
1982 ◽  
Vol 37 (3) ◽  
pp. 262-265 ◽  
Author(s):  
Jerzy Grzywacz ◽  
Stanisława Taszner

Abstract Absorption and emission spectra of 6,7-dihydroxycoumarin [6,7-DHC] in aqueous solution over a wide pH range are reported. The absorption spectra proved to be strongly sensitive to the pH-value of the solution, whereas the emission spectra change in this range only insignificantly. An interpretation is attempted on the basis of the differences of the acid-base properties of the 6,7-DHC molecule in its ground and excited singlet state. For this purpose the pKa's and pKax's values have been calculated. It has been stated that in the excited state the phototautomer form is very unlikely.


The Analyst ◽  
2013 ◽  
Vol 138 (15) ◽  
pp. 4370 ◽  
Author(s):  
Selvan Sukanya Ravi ◽  
Lawrence Rene Christena ◽  
Nagarajan SaiSubramanian ◽  
Savarimuthu Philip Anthony

RSC Advances ◽  
2016 ◽  
Vol 6 (104) ◽  
pp. 102462-102471 ◽  
Author(s):  
Zhibin Zhang ◽  
Zhimin Dong ◽  
Ying Dai ◽  
Saijin Xiao ◽  
Xiaohong Cao ◽  
...  

Amidoxime-functionalized hydrothermal carbon (AO-HTC) has been synthesized and applied to adsorb U(vi) from aqueous solutions, exhibiting a high selectivity above 60% for a wide pH range from 1.0 to 5.0.


2013 ◽  
Vol 12 (3) ◽  
pp. 231-238

The mechanism of retention of vanadium oxo-species at the “titanium oxide/aqueous solution” interface was investigated over a wide pH range (4-9) and V(V) solution concentration (10-5-2×10-2 M) by combining equilibrium deposition experiments, potentiometric titrations, microelectrophoresis and “proton–ion” titration curves. It was inferred that the adsorbed V(V) oxo-species are retained inside the compact layer of the interface through hydrogen/coordinative bonds forming very probably innersphere complexes with the titania surface groups.


2019 ◽  
Vol 42 (1) ◽  
pp. 67-72
Author(s):  
Maxim A. Lutoshkin ◽  
Boris N. Kuznetsov ◽  
Vladimir A. Levdanskiy

Abstract This article focuses on the aqueous complexation between two flavonoids (morin and morinsulfonate) and Pb2+ at constant ionic strength I=0.5 M (NaClO4). The determination of stability constants of ML complexes were performed at wide pH range. Two obtained constants are 14.8 ± 0.1 and 15.2 ± 0.1 logarithmic units for morin and morin-5’-sulfonic acid, respectively. For estimating the thermodynamic stability of the complexes studied, the Def2-SV(P)/DFT/PBE0/SMD method has been used. Different computational models were tested to describe the data obtained. The theoretical values of logK reproduce the experimental parameters within reasonable errors.


2017 ◽  
Vol 23 (32) ◽  
pp. 7785-7790 ◽  
Author(s):  
Youngsam Kim ◽  
Yoon Jeong Jang ◽  
Sandip V. Mulay ◽  
Thuy-Tien T. Nguyen ◽  
David G. Churchill

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