scholarly journals Long-term cement hydration studies with isothermal calorimetry

2021 ◽  
Vol 141 ◽  
pp. 106344
Author(s):  
O. Linderoth ◽  
L. Wadsö ◽  
D. Jansen
2020 ◽  
Vol 9 (1) ◽  
pp. 998-1008
Author(s):  
Guo Li ◽  
Zheng Zhuang ◽  
Yajun Lv ◽  
Kejin Wang ◽  
David Hui

AbstractThree nano-CaCO3 (NC) replacement levels of 1, 2, and 3% (by weight of cement) were utilized in autoclaved concrete. The accelerated carbonation depth and Coulomb electric fluxes of the hardened concrete were tested periodically at the ages of 28, 90, 180, and 300 days. In addition, X-ray diffraction, thermogravimetry, and mercury intrusion porosimetry were also performed to study changes in the hydration products of cement and microscopic pore structure of concrete under autoclave curing. Results indicated that a suitable level of NC replacement exerts filling and accelerating effects, promotes the generation of cement hydration products, reduces porosity, and refines the micropores of autoclaved concrete. These effects substantially enhanced the carbonation and chloride resistance of the autoclaved concrete and endowed the material with resistances approaching or exceeding that of standard cured concrete. Among the three NC replacement ratios, the 3% NC replacement was the optimal dosage for improving the long-term carbonation and chloride resistance of concrete.


2021 ◽  
Vol 10 (1) ◽  
pp. 768-778
Author(s):  
Shaoqiang Meng ◽  
Xiaowei Ouyang ◽  
Jiyang Fu ◽  
Yanfei Niu ◽  
Yuwei Ma

Abstract Graphene (G) and graphene oxide (GO) have been shown to significantly improve the mechanical properties of cement-based materials. In this study, the effect of the G/GO on cement hydration was investigated. First, the zeta potential of G/GO in simulated solutions was tested, and the interaction between G/GO’s surface and Ca2+ was explored. Subsequently, scanning electron microscopy was used to observe the morphology of C–S–H nucleation and growth on the cement surface in the cement paste containing G/GO. Furthermore, XRD and TGA analyses were carried out on the hydration products of the sample. At last, isothermal calorimetry was applied to investigate the influence of G/GO on the early hydration of cement. The results showed that the addition of G/GO significantly accelerates C–S–H nucleation and growth on the cement surface. It is indicated that the high mobility ions derived by G/GO in the cement paste dominate the reason for the accelerated hydration of cement. The presence of G, especially GO, facilitates the mobility of ions, especially Ca2+, thus enhances the interaction between the cement surface and the ions. This strong interaction promotes the C–S–H nucleation and growth, and therefore, the hydration of the cement.


2021 ◽  
Author(s):  
Bohuslav Slánský ◽  
Vit Šmilauer ◽  
Jiří Hlavatý ◽  
Richard Dvořák

A jointed plain concrete pavement represents a reliable, historically proven technical solution for highly loaded roads, highways, airports and other industrial surfaces. Excellent resistance to permanent deformations (rutting) and also durability and maintenance costs play key roles in assessing the economic benefits, rehabilitation plans, traffic closures, consumption and recycling of materials. In the history of concrete pavement construction, slow-to-normal hardening Portland cement was used in Czechoslovakia during the 1970s-1980s. The pavements are being replaced after 40-50 years of service, mostly due to vertical slab displacements due to missing dowel bars. However, pavements built after 1996 used rapid hardening cements, resulting in long-term surface cracking and decreased durability. In order to build durable concrete pavements, slower hardening slag-blended binders were designed and tested in the restrained ring shrinkage test and in isothermal calorimetry. Corresponding concretes were tested mainly for the compressive/tensile strength evolution and deicing salt-frost scaling to meet current specifications. The pilot project was executed on a 14 km highway, where a unique temperature-strain monitoring system was installed to provide long-term data from the concrete pavement. A thermo-mechanical coupled model served for data validation, showing a beneficial role of slower hydration kinetics. Continuous monitoring interim results at 24 months have revealed small curling induced by drying and the overall small differential shrinkage of the slab.


2014 ◽  
Vol 20 (6) ◽  
pp. 405-412
Author(s):  
U. Antons ◽  
M. Raupach ◽  
O. Weichold

Abstract The paper focuses on how alkaline media, UV radiation, and carbonation as well as on-going cement hydration affects hydrophobic treatments of concrete and influences the properties of these water-repellent layers. Single-sided nuclear magnetic resonance measurements show that layers formed by impregnating samples with alkyl trialkoxysilanes are stable even under long-term exposure to alkaline solution and UV radiation, with the damage of the latter being limited to the topmost surface layers. Microstructural changes during accelerated carbonation of blast furnace slag cement based concrete have a major impact on the hydrophobic layer properties, while the carbonation of Portland cement concrete has no influence. On-going hydration additionally influences the hydrophobic layer properties.


Materials ◽  
2019 ◽  
Vol 12 (18) ◽  
pp. 2930 ◽  
Author(s):  
Šiler ◽  
Kolářová ◽  
Novotný ◽  
Másilko ◽  
Bednárek ◽  
...  

This work deals with the influence of zinc on cement hydration. The amount of zinc in cement has increased over recent years. This is mainly due to the utilization of solid waste and tires, which are widely used as a fuel in a rotary kiln. Zinc can also be introduced to cement through such secondary raw materials as slag, due to increased recycling of galvanized materials. The aim of this work was to determine the effect of zinc on the hydration of Portland cement, blended with ground blast furnace slag (GBFS). This effect was studied by isothermal and isoperibolic calorimetry. Both calorimetry methods are suitable for measurements during the first days of hydration. Isoperibolic calorimetry monitors the hydration process in real-life conditions, while isothermal calorimetry does so at a defined chosen temperature. Zinc was added to the cement in the form of two soluble salts, namely Zn(NO3)2, ZnCl2, and a poorly soluble compound, ZnO. The concentration of added zinc was chosen to be 0.05, 0.1, 0.5, and 1mass percent. The amount of GBFS replacement was 15% of cement dosage. The newly formed hydration products were identified by X-ray diffraction method (XRD).


2014 ◽  
Vol 670-671 ◽  
pp. 339-343 ◽  
Author(s):  
Aleksey Adamtsevich ◽  
Andrey Pustovgar ◽  
Stanislav Pashkevich ◽  
Aleksey Eremin ◽  
Andrey Zhuravlev

Nowadays, there is a great demand for the accelerated hardening construction mixtures. That causes the necessity to the methods development for testing the effectiveness of accelerators, well as the analysis of kinetics of cement systems hydration in the early stages of hardening. This paper presents the results of an experimental research of interrelation between the growth kinetics of cement-based binder system strength and the heat release for pure cement hydration. How it was found, two compositions of construction mix, which are identical in mineral composition and differ in the presence of mono-functional accelerator, a comparison of strength growth dynamics can be carried out indirectly via the integral curve of heat release, obtained using the method of isothermal calorimetry.


Holzforschung ◽  
1999 ◽  
Vol 53 (1) ◽  
pp. 104-108 ◽  
Author(s):  
N. Sauvat ◽  
R. Sell ◽  
E. Mougel ◽  
A. Zoulalian

Summary As an essential preliminary to understand the hydration of wood-cement composites, the effects of some additives on the delayed setting due to wood of an Ordinary Portland Cement have been investigated by isothermal calorimetry. With the addition of calcium chloride and activated charcoal, an increase of 50% of the total enthalpy is observed in wood-cement composites hydration, because calcium chloride mostly influences aluminate phases and activated charcoal silicate phases.


2018 ◽  
Vol 554 ◽  
pp. 61-69 ◽  
Author(s):  
Benjamin R. Clarkson ◽  
Rajoshi Chaudhuri ◽  
Arne Schön ◽  
Jonathan W. Cooper ◽  
Lisa Kueltzo ◽  
...  

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