A single-column extraction chemistry for isotope dilution U-Pb dating of carbonate

2020 ◽  
Vol 531 ◽  
pp. 119311 ◽  
Author(s):  
John Engel ◽  
Roland Maas ◽  
Jon Woodhead ◽  
Jan Tympel ◽  
Alan Greig
Author(s):  
Abdelmouhcine GANNOUN ◽  
Krzysztof SUCHORSK ◽  
Christian Pin

A novel separation method is described for the separation of Nd from Fe-rich, silicate samples in view of isotopic analyses. The procedure is based on the synergistic enhancement of the...


2019 ◽  
Vol 107 (6) ◽  
pp. 479-487 ◽  
Author(s):  
Debasish Saha ◽  
Jayagopal Vithya ◽  
Ramalingam Kumar ◽  
Mathew Joseph

Abstract89Sr is being produced using yttria target via the nuclear reaction89Y(n,p)89Sr in Fast Breeder Test Reactor (FBTR), Kalpakkam. The isotope89Sr is a pure beta emitter with a half-life of 50.53 days which is useful mainly for bone pain palliation in patients with bone metastases. The existing method for processing the irradiated yttria target to obtain the pure89Sr source involves separation of the bulk yttrium target by solvent extraction using TBP-HNO3followed by purification of89Sr source by cation exchange chromatography technique using Dowex resin. The study described here involves the selective extraction and purification of89Sr by multi-column extraction chromatography technique using the Sr-specific crown ether, DtBuCH18C6 (CE) coated onto an XAD-7 resin matrix for superior separation and increased yield compared to single column technique. The89Sr source thus purified from the irradiated yttria target is free from other radionuclidic impurities produced during the target irradiation i.e.88Y,65Zn,139,141Ce,154Eu and160Tb.


2018 ◽  
Vol 142 ◽  
pp. 28-31 ◽  
Author(s):  
Eduardo Aluicio-Sarduy ◽  
Reinier Hernandez ◽  
Hector F. Valdovinos ◽  
Christopher J. Kutyreff ◽  
Paul A. Ellison ◽  
...  

2002 ◽  
Vol 90 (2) ◽  
Author(s):  
A. Morgenstern ◽  
C. Apostolidis ◽  
R. Carlos-Marquez ◽  
K. Mayer ◽  
R. Molinet

SummaryA rapid, single-column extraction chromatographic method using commercially available UTEVA resin has been developed for the separation of uranium, plutonium, neptunium and americium. The method yields recoveries superior to 90% and allows direct loading of separated fractions on filaments for subsequent analysis by thermal ionization mass spectrometry. The use of reagents compatible with robotized equipment allows automation of the separation process for routine analysis of nuclear materials. The redox reactions between plutonium, neptunium and hydrogen peroxide involved in the separation process were studied by UV/Vis/NIR absorption spectroscopy.


Author(s):  
Yun Liu ◽  
Xiao-lin Ding ◽  
Dan-hua Zhu

Solubilities are measured for natural tocopherols and fatty acid methyl esters(FAMEs) under partly isothermal, isobaric and isochoric conditions in the range of temperature of 40-60deg.C and pressure of 9.7-16.2MPa based on soybean de-odorizer(DOD) pretreatment, the separation factors between FAMEs and tocopherols are 3.1-5.4 in this study. Furthermore, three different technology projects are analyzed qualitatively and quantitatively of single column extraction (SCE), extraction and fractionation (EF), two-column extraction (TCE).


1968 ◽  
Vol 07 (01) ◽  
pp. 1-7
Author(s):  
Muhammad Razzak ◽  
Robert Botti ◽  
William MacIntyre

SummaryA pair of printing scalers was used to record the information obtained by external monitoring of the isotope dilution curve following the intravenous injection of radioiodinated human serum albumin. The first scaler gives the differential count rate of the curve at increments of one second, whereas the second integrates continuously the isotope dilution curve. This recording device enabled cardiac output determinations to be calculated rapidly at the bedside without any loss in accuracy.Using this method in 15 normal individuals, the cardiac output was found to be 6.13 ± 0.73 liters/minute (Mean ± 1 S.D.), with a cardiac index of 3.36 ± 0.35 liters/minute/m2. In the same group of normals, the stroke index (stroke volume/surface area) amounted to 50 ± 7.3 ml/beat/m2.Comparison of the results of this method with those obtained by integration of the entire isotope dilution curve by an IBM 1620 computer showed excellent agreement, proving the validity of the suggested technique.


2020 ◽  
Vol 14 (3) ◽  
pp. 7082-7093
Author(s):  
Jahirwan Ut Jasron ◽  
Sudjito Soeparmani ◽  
Lilis Yuliati ◽  
Djarot B. Darmadi

The hydrodynamic performance of oscillating water column (OWC) depends on the depth of the water, the size of the water column and its arrangement, which affects the oscillation of the water surface in the column. An experimental method was conducted by testing 4 water depths with wave periods of 1-3 s. All data recorded by the sensor is then processed and presented in graphical form. The research focused on analyzing the difference in wave power absorption capabilities of the three geometric types of OWC based on arrangements of water columns. The OWC devices designed as single water column, the double water column in a series arrangement which was perpendicular to the direction of wave propagation, and double water column in which the arrangement of columns was parallel to the direction of wave propagation. This paper discussed several factors affecting the amount of power absorbed by the device. The factors are the ratio of water depth in its relation to wavelength (kh) and the inlet openings ratio (c/h) of the devices. The test results show that if the water depth increases in the range of kh 0.7 to 0.9, then the performance of the double chamber oscillating water column (DCOWC) device is better than the single chamber oscillating water column (SCOWC) device with maximum efficiency for the parallel arrangement 22,4%, series arrangement 20.8% and single column 20.7%. However, when referring to c/h, the maximum energy absorption efficiency for a single column is 27.7%, double column series arrangement is 23.2%, and double column parallel arrangement is 29.5%. Based on the results of the analysis, DCOWC devices in parallel arrangement showed the ability to absorb better wave power in a broader range of wave frequencies. The best wave of power absorption in the three testing models occurred in the wave period T = 1.3 seconds.


1963 ◽  
Vol 44 (4) ◽  
pp. 499-504 ◽  
Author(s):  
M. Van Der Straeten ◽  
A. Vermeulen ◽  
N. Orie ◽  
P. Regniers

ABSTRACT The authors studied the correlation between cortisol production, as measured by an isotope dilution method, and the urinary excretion of total and free Porter-Silber chromogens, as well as of 17-ketogenic steroids. Although a significant correlation exists between total Porter-Silber chromogens, 17-ketogenic steroid excretion and cortisol production, discrepancies are occasionally observed. Hence, different colorimetric methods should be used to assess the glucocorticoid activity of the adrenal cortex.


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