Start-up and long-term operation of the Anammox process in a fixed bed reactor (FBR) filled with novel non-woven ring carriers

Chemosphere ◽  
2013 ◽  
Vol 91 (5) ◽  
pp. 669-675 ◽  
Author(s):  
Tao Wang ◽  
Hanmin Zhang ◽  
Fenglin Yang ◽  
Yifei Li ◽  
Guangyi Zhang
Keyword(s):  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Term Operation ◽  
Start Up ◽  
Anammox Process

scholarly journals Co-digestion of Oil Palm Trunk Hydrolysate and Slaughterhouse Wastewater for Biohydrogen Production in a Fixed Bed Reactor by Immobilized Thermoanaerobacterium thermosaccharolyticum KKU19 on Expanded Clay

2021 ◽  
Vol 9 ◽  
Author(s):  
Sontaya Khamtib ◽  
Sureewan Sittijunda ◽  
Tsuyoshi Imai ◽  
Alissara Reungsang
Keyword(s):  
Oil Palm ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Hydrogen Yield ◽  
Support Material ◽  
Slaughterhouse Wastewater ◽  
Term Operation ◽  
Oil Palm Trunk ◽  
Thermoanaerobacterium Thermosaccharolyticum

The goal of this study was to evaluate the use of expanded clay as a support material for Thermoanaerobacterium thermosaccharolyticum KKU19 to produce hydrogen from oil palm trunk hydrolysate (OPT) and slaughterhouse wastewater (SHW) in a fixed-bed reactor (FBR) under non-sterile conditions. The effects of hydraulic retention time (HRT) on the performance of the FBR were also investigated. The FBR was operated at an OPT hydrolysate to SHW ratio of 2.55:1 (v:v), 60°C, initial pH 6.5, and 1.2 mg (as total volatile solids/g expanded clay) of T. thermosaccharolyticum KKU19 immobilized on expanded clay. A maximum hydrogen production rate (HPR) and hydrogen yield (HY) of 7.15 ± 0.22 L/L day and 234.45 ± 5.14 mL H2/g-COD, respectively, were obtained at an HRT of 6 h. Long-term operation of FBR at 6 h HRT indicated that expanded clay efficiently immobilizes T. thermosaccharolyticum KKU19, for which an HPR of 6.82 ± 0.56 L H2/L day, and an HY of 231.99 ± 19.59 mL H2/g-COD were obtained. Furthermore, the COD removal efficiency of 30% obtained under long-term operation was comparable to that under short-term operation at an HRT of 6 days. Butyric and acetic acids were the main soluble metabolite products, thereby indicating a butyrate–acetate type fermentation. Our findings indicate that expanded clay is an effective support material that contributes to the protection of microbial cells and can be used for long-term operation.

scholarly journals Short-Term and Long-Term Inhibitory Effects of Copper on Anammox Process

Proceedings ◽  
2018 ◽  
Vol 2 (11) ◽  
pp. 657 ◽  
Author(s):  
Cigdem Kalkan Aktan ◽  
Ayse Ekin Uzunhasanoglu ◽  
Kozet Yapsakli ◽  
Bulent Mertoglu
Keyword(s):  
Competitive Inhibition ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Anammox Bacteria ◽  
Inhibitory Effects ◽  
Short Term ◽  
Inhibition Model ◽  
Short Term Exposure ◽  
Anammox Process

The main goal of this study is to evaluate the short-term and long-term inhibitory effects of Cu (II) on Anammox process. To investigate the short-term inhibition level, four different concentrations (1, 2.5, 5 and 10 mg L−1 as Cu2+) were tested in batch reactors. IC50 levels for short-term exposure deduced as 4.57mg L−1 (R2: 0.97) from the modified non-competitive inhibition model. Lab-scale continuous flow up-flow fixed bed reactor with Kaldness biofilm carriers was operated 240 days with gradually increased Cu concentrations (from 0.2 to 8 mg L−1). To identify the IC50 levels in case of prolonged exposure of Cu(II), experimental data were fitted with a modified non-competitive inhibition model, and calculated as 6.77 mg L−1 (R2: 0.95). The results show that the IC50 level for copper in long-term exposure was higher than in short-term exposure and the possible reason for that is the self-adaptation of Anammox bacteria.

Anaerobic digestion of high-sulphate-content wastewater from the industrial production of citric acid

1994 ◽  
Vol 30 (12) ◽  
pp. 263-273 ◽  
Author(s):  
E. Colleran ◽  
S. Finnegan ◽  
R. B. O'Keeffe
Keyword(s):  
Steady State ◽  
Citric Acid ◽  
Fixed Bed ◽  
Full Scale ◽  
Sulphate Content ◽  
Methanogenic Activity ◽  
Term Operation ◽  
Steady State Operation ◽  
Start Up

The start-up and steady-state operation of a full-scale fixed bed digester treating citric acid production wastewater with an estimated COD/sulphate ratio of approximately 4 are described. Parallel studies at laboratory-scale with two reactors, one of which received the same high influent sulphate concentration as the full-scale plant, confirmed the finding that methanogenesis was not inhibited by the level of sulphate reduction shown to occur. After long-term operation on a high sulphate influent, the retained biomass in the laboratory and full-scale reactors displayed a very low specific methanogenic activity against propionate and butyrate. Since propionate and butyrate were barely detectable in the effluents at steady-state, their oxidation under high influent sulphate conditions may be completely or incompletely mediated by fatty-acid-utilising SRB.

Application of Biofilm Kinetics to Anaerobic Fixed Bed Reactors

1991 ◽  
Vol 23 (7-9) ◽  
pp. 1319-1326 ◽  
Author(s):  
I. E. Gönenç ◽  
D. Orhon ◽  
B. Beler Baykal
Keyword(s):  
Removal Rate ◽  
Fixed Bed ◽  
Experimental Studies ◽  
Pilot Scale ◽  
Cod Removal ◽  
Experimental Results ◽  
Fixed Bed Reactor ◽  
Removal Mechanism ◽  
Term Operation ◽  
Fixed Bed Reactors

Two basic phenomena, reactor hydraulics and mass transport through biofilm coupled with kinetic expressions for substrate transformations were accounted for in order to describe the soluble COD removal mechanism in anaerobic fixed bed reactors. To provide necessary verification, experimental results from the long term operation of the pilot scale anaerobic reactor treating molasses wastewater were used. Theoretical evaluations verified by these experimental studies showed that a bulk zero-order removal rate expression modified by diffusional resistance leading to bulk half-order and first-order rates together with the particular hydraulic conditions could adequately define the overall soluble COD removal mechanism in an anaerobic fixed bed reactor. The experimental results were also used to determine the kinetic constants for practical application. In view of the complexity of the phenomena involved it is found remarkable that a simple simulation model based on biofilm kinetics is a powerful tool for design and operation of anaerobic fixed bed reactors.

scholarly journals Analysis and Model-Based Description of the Total Process of Periodic Deactivation and Regeneration of a VOx Catalyst for Selective Dehydrogenation of Propane

Catalysts ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1374
Author(s):  
Andreas Brune ◽  
Andreas Seidel-Morgenstern ◽  
Christof Hamel
Keyword(s):  
Catalyst Deactivation ◽  
Process Development ◽  
Coke Formation ◽  
Fixed Bed ◽  
Reaction Network ◽  
Fixed Bed Reactor ◽  
Side Reactions ◽  
Model Based ◽  
Total Process

This study intends to provide insights into various aspects related to the reaction kinetics of the VOx catalyzed propane dehydrogenation including main and side reactions and, in particular, catalyst deactivation and regeneration, which can be hardly found in combination in current literature. To kinetically describe the complex reaction network, a reduced model was fitted to lab scale experiments performed in a fixed bed reactor. Additionally, thermogravimetric analysis (TGA) was applied to investigate the coking behavior of the catalyst under defined conditions considering propane and propene as precursors for coke formation. Propene was identified to be the main coke precursor, which agrees with results of experiments using a segmented fixed bed reactor (FBR). A mechanistic multilayer-monolayer coke growth model was developed to mathematically describe the catalyst coking. Samples from long-term deactivation experiments in an FBR were used for regeneration experiments with oxygen to gasify the coke deposits in a TGA. A power law approach was able to describe the regeneration behavior well. Finally, the results of periodic experiments consisting of several deactivation and regeneration cycles verified the long-term stability of the catalyst and confirmed the validity of the derived and parametrized kinetic models for deactivation and regeneration, which will allow model-based process development and optimization.

Influence of Creep on Low-Cycle Fatigue Life Assessment of Ultra-Supercritical Steam Turbine Rotor

2014 ◽  
Author(s):  
W. Z. Wang ◽  
J. H. Zhang ◽  
H. F. Liu ◽  
Y. Z. Liu
Keyword(s):  
High Temperature ◽  
Steam Turbine ◽  
Fatigue Damage ◽  
Low Cycle Fatigue ◽  
Turbine Rotor ◽  
High Temperature Creep ◽  
Cycle Fatigue ◽  
Term Operation ◽  
Start Up

Linear damage method is widely used to calculate low-cycle fatigue damage of turbine rotor in the long-term operation without fully considering the interaction between creep and low cycle fatigue. However, with the increase of steam turbine pressure and temperature, the influence of high-temperature creep on the strain distribution of turbine rotor becomes significant. Accordingly, the strain for each start-up or shut-down process is different. In the present study, the stress and strain during 21 iterations of continuous start-up, running and shut-down processes was numerically investigated by using the finite element analysis. The influence of high-temperature creep on low cycle fatigue was analyzed in terms of equivalent strain, Mises stress and low cycle fatigue damage. The results demonstrated that the life consumption of turbine rotor due to low cycle fatigue in the long-term operation of startup, running and shutdown should be determined from the full-time coverage of the load of turbine rotor.

scholarly journals Long-term performance and microbial dynamics of an up-flow fixed bed reactor established for the biodegradation of fluorobenzene

2006 ◽  
Vol 71 (4) ◽  
pp. 555-562 ◽  
Author(s):  
M. F. Carvalho ◽  
R. Ferreira Jorge ◽  
C. C. Pacheco ◽  
P. De Marco ◽  
I. S. Henriques ◽  
...  
Keyword(s):  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Microbial Dynamics ◽  
Long Term Performance ◽  
Term Performance

scholarly journals Start-up of anaerobic reactors for slaughterhouse wastewater treatment

2015 ◽  
Vol 35 (2) ◽  
pp. 331-339 ◽  
Author(s):  
RONALDO FIA ◽  
ERLON L. PEREIRA ◽  
FÁTIMA R. L. FIA ◽  
DÉBORA G. EMBOABA ◽  
EMANUEL M. GOMES
Keyword(s):  
Wastewater Treatment ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Upflow Anaerobic Sludge Blanket ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Stable Operation ◽  
Slaughterhouse Wastewater ◽  
Start Up ◽  
Bicarbonate Alkalinity

This study aimed to evaluate the start-up of a horizontal anaerobic fixed bed reactor (HAFBR) followed by an upflow anaerobic sludge blanket (UASB) for the slaughterhouse wastewater treatment. HAFBR was filled with bamboo rings and had 1.2 m in length, 0.10 m in diameter and volume of 7.5 L. The UASB had the volume of 15 L. The HAFBR and UASB operated at organic loading rate and hydraulic retention time average of 8.46 and 3.77 kg m-3 d-1 of COD and 0.53 and 0.98 days, respectively. During 150 days of monitoring system it was found pH 6.8, relatively high values of bicarbonate alkalinity (> 1000 mg L-1) and reduced values of volatile acids (70 to 150 mg L-1), which afforded average removal efficiencies of COD total and total suspended solids of the order of 31 and 23% in HAFBR and 79% and 63% in UASB. It can be concluded that the generation and consumption of bicarbonate alkalinity and total volatile acids, thereby maintaining the pH during the study indicated stable operation of the reactors. The COD removal in the reactors was satisfactory especially when it considers that the assessment was conducted in a period of adaptation of organisms to the effluent and also the high organic load applied during this period.

Nitritation of real sewage: start-up and maintenance by the side-stream heat-shock treatment

2019 ◽  
Vol 79 (4) ◽  
pp. 753-758 ◽  
Author(s):  
Jianfei Chen ◽  
Shujun Zhang ◽  
Xiaoyu Han ◽  
Liang Zhang ◽  
Yongzhen Peng
Keyword(s):  
Heat Shock ◽  
Accumulation Rate ◽  
Batch Reactor ◽  
Shock Treatment ◽  
Nitrite Accumulation ◽  
Heat Shock Treatment ◽  
Term Operation ◽  
Side Stream ◽  
Start Up

Abstract In this study, the side-stream heat-shock treatment was used to start up and maintain the nitritation of real sewage. Complete nitrification was obtained when the real sewage was treated in a sequencing batch reactor (SBR). Then, about 50% of the mixed sludge was collected from the SBR and treated with the heat-shock treatment at 60 °C for 40 min in another reactor every 2 weeks. After providing the heat-shock treatment for four times, the effluent nitrate in the SBR gradually decreased from 22.5 to 3.2 mg/L, while the nitrite accumulation rate increased from 4.4% to 81.8%, indicating a successful start-up of nitritation. Further, the sewage nitritation was stable with the regular side-steam heat-shock treatment for 91 days, and the ammonium removal efficiency of 80.6% and nitrite accumulation rate of 91.2% were achieved. This study suggests that the side-stream heat-shock treatment could be used to start up sewage nitritation and maintain stability for a long-term operation.

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