Sodium hexametaphosphate interaction with 2:1 clay minerals illite and montmorillonite

In present paper, studied were the dispersion-flocculation behaviour of the primary natural raw „clay samples” from Omarska mine (Republic of Srpska, Bosnia and Herzegovina). Namely, our previous results showed that during the processing of iron ore in the Omarska mine, large quantities of fine sized (15μm) waste sludge, with relatively high Fe concentrations, were generated. Sludge samples are composed of major goethite and quartz, less clay minerals, and minor magnetite and todorokite. Selective flocculation is one of the methods that can be applied for the separation of fine class iron minerals from impurities and depends on the individual components of the sludge and their behaviour. This paper presents part of the research of the individual components of the sludge. The „clay samples” are composed of major quartz and clay minerals, which dominate over minor contents of feldspars, amphiboles, goethite and hematite. The clay minerals were identified as mostly illite-sericite which prevails over kaolinite, and with chlorites which appears only sporadically. The dispersion-flocculation behaviour was studied by settling and flocculation experiments and Zeta potential measurements. A three different dispersants (sodium hexametaphosphate, sodium-pyrophosphate and sodiumsilicate), and anionic and non-ionic polyacrylamide (PAM) flocculants were used. It was established that the best results were achieved with sodium-hexametaphosphate (1000 g/t) and anionic A100 PAM.

Download Full-text

Revolution of Malaysia’s Kaolin to Metakaolin towards various application: A Mini Review

Journal of Modern Manufacturing Systems and Technology ◽

10.15282/jmmst.v2i2.3027 ◽

2019 ◽

Vol 3 ◽

pp. 114-119

Author(s):

Norsuhailizah Sazali ◽

Zawati Harun ◽

Tijani Abdullahi ◽

Faiz Hafeez Azhar ◽

Norazlianie Sazali

Keyword(s):

Clay Minerals ◽

The Other ◽

Sodium Hexametaphosphate ◽

Significant Characteristic ◽

Primary Deposit ◽

Secondary Kaolin ◽

Sabah And Sarawak ◽

High Silicate

The transformation of kaolin to metakaolin was studied in various state in Malaysia which is Segamat, Nitar, Lenggor, Ipoh, Bidor, Mersing, Sabah, and Sarawak. In Segamat, the kaolin has a light colour due to the high silicate composition and also contain high mineral such as kaolinite and quartz existed as impurities. Aluminum rich kaolin is bright in color with elevated plasticity and is commonly used in the ceramic, plastic, dye, fabric, pesticide, pharmaceutical and beauty industry. For Nitar and Lenggor, production of metakaolin occurs at 510°C and formation of mullite occur at 900°C. Both clays show good crystallization of pseudohexagonal to hexagonal kaolinite particles. Moreover, the classification of clay and the sizing are the significant characteristic to be determined using the method of the beneficiations. The method of beneficiations is crucially important to increase the quality of clay to meet the requirement for industry application. In Ipoh and Sarawak, the primary deposit is dominated by kaolin and the mixture of granites and diorites produced from weathering. On the other hand, in Bidor, the primary deposit is a mixture of kaolinite, muscovite and smectite also formed by weathering. The increasing amount of illite in secondary kaolin deposits in the Mersing area due to the marine deposition of those deposits where illite formed by the absorption of clay minerals from the seawater by pottasium. Kaolin in Kg Gading, Bongawan Sabah were treated with sodium hexametaphosphate to remove impurities in natural kaolin. The transformation of kaolin to metakaolin was conducted at 800°C for 5 hours.

Download Full-text

The Depressing Effect of Kaolinite on Molybdenite Flotation in Seawater

Minerals ◽

10.3390/min10060578 ◽

2020 ◽

Vol 10 (6) ◽

pp. 578 ◽

Cited By ~ 1

Author(s):

Andres Ramirez ◽

Leopoldo Gutierrez ◽

Dennis Vega-Garcia ◽

Lorenzo Reyes-Bozo

Keyword(s):

Experimental Data ◽

Clay Minerals ◽

Froth Flotation ◽

Sodium Hexametaphosphate ◽

Depressing Effect ◽

Copper Sulfides ◽

Flotation Recovery ◽

Hydroxo Complexes ◽

Repulsive Forces ◽

Positively Charged

Copper-molybdenum grades of important mining deposits have progressively decayed, which is associated with high levels of clay minerals which affect froth flotation. The depressing effect of clay minerals on copper sulfides was previously reported but there are no systematic studies on the effect on molybdenite flotation in seawater. The objective of this work was to study the effect of kaolinite on molybdenite flotation in seawater and to evaluate the use of sodium hexametaphosphate (SHMP) as dispersant. The results of this work show that kaolinite depresses molybdenite flotation which is more significant in seawater at pH > 9. All the experimental data validate the hypothesis that kaolinite covers molybdenite, reducing its flotation recovery. The depressing effect of kaolinite on molybdenite flotation in seawater is enhanced by the magnesium and calcium hydroxo complexes at pH > 9, which induce heterocoagulation between kaolinite and molybdenite, thus reducing recovery. The attachment of the positively charged hydroxo complexes of magnesium and calcium to the molybdenite and kaolinite surfaces is diminished by SHMP. This reagent increases the repulsive forces between molybdenite and precipitates and as a result, molybdenite becomes more hydrophobic and recovery increases.

Download Full-text

Hydrated form of some clay minerals observed using a film sealed environmental cell

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100107502 ◽

1978 ◽

Vol 36 (1) ◽

pp. 72-73

Author(s):

N. Kohyama ◽

K. Fukushima ◽

A. Fukami

Keyword(s):

Clay Minerals ◽

Morphological Changes ◽

Carbon Film ◽

Electron Microscopic Observation ◽

Adsorbed Water ◽

Electron Microscopic ◽

Hydrated Form ◽

Thin Carbon ◽

Environmental Cell ◽

Thin Carbon Film

Since the interlayer or adsorbed water of some clay minerals are quite easily dehydrated in dried air, in vacuum, or at moderate temperatures even in the atmosphere, the hydrated forms have not been observed by a conventional electron microscope(TEM). Recently, specific specimen chambers, “environmental cells(E.C.),” have been developed and confirmed to be effective for electron microscopic observation of wet specimen without dehydration. we observed hydrated forms of some clay minerals and their morphological changes by dehydration using a TEM equipped with an E.C..The E.C., equipped with a single hole copper-microgrid sealed by thin carbon-film, attaches to a TEM(JEM 7A) with an accelerating voltage 100KV and both gas pressure (from 760 Torr to vacuum) and relative humidity can be controlled. The samples collected from various localities in Japan were; tubular halloysite (l0Å) from Gumma Prefecture, sperical halloysite (l0Å) from Tochigi Pref., and intermediate halloysite containing both tubular and spherical types from Fukushima Pref..

Download Full-text

Colloidal systems in soils

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100168050 ◽

1994 ◽

Vol 52 ◽

pp. 64-65

Author(s):

J. Thieme ◽

J. Niemeyer ◽

P. Guttman

Keyword(s):

Clay Minerals ◽

Polymeric Materials ◽

Spatial Arrangement ◽

High Specific Surface Area ◽

Turnover Rates ◽

Colloidal Systems ◽

Chemical Conditions ◽

Aggregation Phenomena ◽

Iron And Manganese ◽

Soil Colloids

In soil science the fraction of colloids in soils is understood as particles with diameters smaller than 2μm. Clay minerals, aquoxides of iron and manganese, humic substances, and other polymeric materials are found in this fraction. The spatial arrangement (microstructure) is controlled by the substantial structure of the colloids, by the chemical composition of the soil solution, and by thesoil biota. This microstructure determines among other things the diffusive mass flow within the soils and as a result the availability of substances for chemical and microbiological reactions. The turnover of nutrients, the adsorption of toxicants and the weathering of soil clay minerals are examples of these surface mediated reactions. Due to their high specific surface area, the soil colloids are the most reactive species in this respect. Under the chemical conditions in soils, these minerals are associated in larger aggregates. The accessibility of reactive sites for these reactions on the surface of the colloids is reduced by this aggregation. To determine the turnover rates of chemicals within these aggregates it is highly desirable to visualize directly these aggregation phenomena.

Download Full-text