scholarly journals The Depressing Effect of Kaolinite on Molybdenite Flotation in Seawater

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 578 ◽  
Author(s):  
Andres Ramirez ◽  
Leopoldo Gutierrez ◽  
Dennis Vega-Garcia ◽  
Lorenzo Reyes-Bozo

Copper-molybdenum grades of important mining deposits have progressively decayed, which is associated with high levels of clay minerals which affect froth flotation. The depressing effect of clay minerals on copper sulfides was previously reported but there are no systematic studies on the effect on molybdenite flotation in seawater. The objective of this work was to study the effect of kaolinite on molybdenite flotation in seawater and to evaluate the use of sodium hexametaphosphate (SHMP) as dispersant. The results of this work show that kaolinite depresses molybdenite flotation which is more significant in seawater at pH > 9. All the experimental data validate the hypothesis that kaolinite covers molybdenite, reducing its flotation recovery. The depressing effect of kaolinite on molybdenite flotation in seawater is enhanced by the magnesium and calcium hydroxo complexes at pH > 9, which induce heterocoagulation between kaolinite and molybdenite, thus reducing recovery. The attachment of the positively charged hydroxo complexes of magnesium and calcium to the molybdenite and kaolinite surfaces is diminished by SHMP. This reagent increases the repulsive forces between molybdenite and precipitates and as a result, molybdenite becomes more hydrophobic and recovery increases.

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 499
Author(s):  
Duong Huu Hoang ◽  
Doreen Ebert ◽  
Robert Möckel ◽  
Martin Rudolph

The depletion of ore deposits, the increasing demand for raw materials, the need to process low-grade, complex and finely disseminated ores, and the reprocessing of tailings are challenges especially for froth flotation separation technologies. Even though they are capable of handling relatively fine grain sizes, the flotation separation of very fine and ultrafine particles faces many problems still. Further, the flotation of low-contrast semi-soluble salt-type minerals with very similar surface properties, many complex interactions between minerals, reagents and dissolved species often result in poor selectivity. This study investigates the flotation beneficiation of ultrafine magnesite rich in dolomite from desliming, currently reported to the tailings. The paper especially focuses on the impact of the depressant sodium hexametaphosphate (SHMP) on the following: (i) the froth properties using dynamic froth analysis (DFA), (ii) the separation between magnesite and dolomite/calcite, and (iii) its effect on the entrainment. As a depressant/dispersant, SHMP has a beneficial impact on the flotation separation between magnesite and dolomite. However, there is a trade-off between grade and recovery, and as well as the dewatering process which needs to be considered. When the SHMP increases from 200 g/t to 700 g/t, the magnesite grade increases from 67% to 77%, while recovery decreases massively, from 80% to 40%. The open circuit with four cleaning stages obtained a concentrate assaying 77.5% magnesite at a recovery of 45.5%. The dolomite content in the concentrate is about 20%, where 80% of dolomite was removed and importantly 98% of the quartz was removed, with only 0.3% of the quartz in the final concentrate. Furthermore, the application of 1-hydroxyethylene-1,1-diphosphonic acid (HEDP) as a more environmentally friendly and low-cost alternative to SHMP is presented and discussed. Using only 350 g/t of HEDP can achieve a similar grade (76.3%), like 700 g/t of SHMP (76.9%), while obtaining a 17% higher magnesite recovery as compared to 700 g/t of SHMP. Interestingly, the proportion of hydrophilic quartz minerals ending up in the concentrate is lower for HEDP, with only 1.9% quartz at a recovery of 21.5% compared to the 2.7% of quartz at a recovery of 24.9% when using SHMP. The paper contributes in general to understanding the complexity of the depressant responses in froth flotation.


2005 ◽  
Vol 77 (3) ◽  
pp. 631-641 ◽  
Author(s):  
W. Hummel

If a true thermodynamic equilibrium with a well-known solid is expected to establish, chemical equilibrium thermodynamics allows estimation of the maximum concentration of a given radionuclide in a specified pore fluid of an underground repository. However, in the course of the review process for the Nagra/PSI Chemical Thermodynamic Data Base 01/01, important cases of insufficient chemical knowledge were identified, leading to gaps in the database. First, experimental data for the ThO2–H2O and UO2–H2O systems cannot be interpreted by a unique set of thermodynamic constants. There, a pragmatic approach was chosen by including parameters in the database that are not thermodynamic constants in a strict sense, but that reproduced relevant experimental observations. Second, potentially important thermodynamic constants are missing because of insufficient experimental data. Estimations of these missing constants led to problem-specific database extensions. Especially constants for ternary mixed carbonato-hydroxo complexes of tetravalent actinides have been estimated by the “backdoor approach”, i.e., by adjusting thermodynamic constants to maximum feasible values that are still consistent with all available experimental solubility data.


2020 ◽  
Vol 375 ◽  
pp. 317-326
Author(s):  
Yuanyuan Pu ◽  
Alicja Szmigiel ◽  
Jie Chen ◽  
Derek B. Apel

2016 ◽  
Vol 37 (4) ◽  
pp. 227-235 ◽  
Author(s):  
Lina Uribe ◽  
Leopoldo Gutierrez ◽  
Oscar Jerez

Minerals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 705 ◽  
Author(s):  
Jianhua Kang ◽  
Yuehua Hu ◽  
Wei Sun ◽  
Zhiyong Gao ◽  
Runqing Liu

This study presents a highly selective reagent system that utilizes sodium hexametaphosphate (SHMP) to improve the separation of scheelite from calcite and fluorite using an anionic–nonionic collector. The recoveries of calcite and fluorite decreased to 20% as the SHMP dose exceeded 6 × 10−6 mol/L, whereas that of scheelite remained at 85%. The interaction mechanisms of minerals with SHMP were investigated through equilibrium speciation, Zeta potential, Fourier transform infrared spectrometry, and X-ray photoelectron spectroscopy analyses. SHMP exists as hydrogen phosphate anion in the aqueous solution with a pH of 7–12. Moreover, it may be adsorbed intensively on the positively charged surfaces of calcite and fluorite via electrostatic force or chelation with calcium ion to impede further adsorption of the assembled collector. By comparison, the adsorption of SHMP is feeble on the scheelite surface because of its negative charge. The roughing grade of low-grade scheelite ore is substantially improved from 0.74% to 1.65% compared with that in the contrast test in the absence of SHMP.


1985 ◽  
Vol 50 (8) ◽  
pp. 1834-1841 ◽  
Author(s):  
O. Olaofe ◽  
P. L. Yue

The product distribution from the dehydration of 1-butanol over zeolites (13X, 4A, ZNa) has been investigated to gain insight of the reaction mechanism. The formation of 2-alkenes (cis-2-butene and trans-2-butene) in the absence of isomerization reactions during the catalytic dehydration of 1-butanol over zeolites is unambiguous evidence in favour of a positively charged intermediate, indicating that reaction proceeds via a E1 type of mechanism. Experimental data also showed the preferential formation of cis-2-butene over that of trans-2-butene. The predominance of E1 type mechanism increases with increasing temperature.


1962 ◽  
Vol 2 (04) ◽  
pp. 360-366 ◽  
Author(s):  
Valery M. Dobrynin

Abstract Experimental data demonstrate that physical properties of porous rocks change under pressure. In this paper an assumption is made and proved that under pressure the changes of physical properties such as porosity, density, permeability, resistivity and velocity of elastic waves are controlled to a large extent by the pore compressibility of rocks. It is also shown that the pore compressibility of rocks can be determined, within the range of pressures from 0 to 20,000 psi, by knowing the maximum pore compressibility and the magnitude of the pressure. Mathematical equations were developed which permit one to define changes in physical properties of porous rocks under pressure. These equations were verified by experimental data obtained from the study of sandstones. Introduction In studying the behavior of porous rocks under pressure in the field of petroleum technology, the most interesting aspect is the observation of those properties which characterize the rocks as possible reservoirs for example, porosity, permeability, resistivity, density and be velocity of elastic waves. The literature dealing with this problem mainly contains data concerning the study of only one or at most two of these parameters, but not of the group as a whole. An attempt is made in this paper to find general equations involving each of these parameters, which will permit the study of the behavior of rocks under pressure. All experimental data used here were obtained from the investigation of consolidated sandstones. EXPERIMENTAL In addition to the use of published experimental data, an experiment was carried out which studied the main physical properties of sandstones under pressure. Two homogeneous quartz sandstones were chosen for this purpose:the Torpedo sandstone bona Kansas, andthe Medina sandstone from Ohio. The porosity of the Torpedo sandstone was 20.2 per cent, and that of the Medina 8.7 per cent. Permeabilities were 45 md and less than 1 md, respectively. Each sandstone contained about 5 per cent clay minerals, consisting mostly of kaolinite and chlorite, which were distributed quite evenly throughout the samples. One cylindrical sample 2 in. in diameter and 5 in. in length was cut from each sandstone and then saturated in a vacuum with a 3N solution of NaCl. This high concentration was used in order to obtain true formation factors and to decrease the swelling of the clay minerals. The methods of mounting the samples and measuring the changes in porosity and resistivity were practically the same as those described by Fatt and Mann. Changes of resistivity under pressure were studied for sandstones with 100 per cent water saturation, and for sandstones with the irreducible water saturation. The irreducible saturation was obtained by enclosing the saturated rock samples in relatively fine silicate powder so as to remove the water by capillary action. This procedure is described by Orkin and Kuchinski. Changes of permeability with pressure were determined at room temperature using nitrogen as the flowing medium. In studying the effects of pressure, one series of measurements was made using an internal pore pressure Pi equal to the atmospheric pressure, while the overburden pressure P. ranged from 0 to 20,000 psi. A second series of measurements was used over the same range of overburden pressure, but with an internal pore pressure of 1,800 psi When the results were compared on the basis of net overburden pressure (P, - 0.85 Pi ), there was practically no difference for these two sandstones. The origin of the factor 0.85 in the expression for net overburden pressure is given by Brandt, Fatt and Geertsma. SPEJ P. 360^


2013 ◽  
Vol 83-84 ◽  
pp. 162-170 ◽  
Author(s):  
Elena Castellini ◽  
Christoph Berthold ◽  
Daniele Malferrari ◽  
Fabrizio Bernini

1984 ◽  
Vol 36 ◽  
Author(s):  
H. F. Schaake

ABSTRACTAn interstitial model is developed to quantitatively account for the anomalous effects which accompany the diffusion of phosphorus in silicon from high surface concentrations. Phosphorus is assumed to diffuse as both a positively charged (intrinsic diffusion) and an uncharged interstitial (high concentration case). Silicon is assumed to diffuse as both an uncharged (instrinsic) and a negatively charged interstitial (high phosphorus concentrations). The effect of internal fields on charged species is included. An excellent fit is found with published experimental data if a surface enhancement factor, analogous to that for the case of oxidation enhancement, is used. Flat-top diffusion is modelled by assuming the formation of a dislocation array, which alters the point defect equilibria.


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