Investigation of the Inhibition Mechanism Of Polymer/Nano-silica Composite as Shale Inhibitor in Water-based Drilling Fluids

Author(s):  
Fei Liu ◽  
Chengxiang Zhang ◽  
Xiaqing Li ◽  
Zhaoxiang Zhang ◽  
Xuewu Wang ◽  
...  
Author(s):  
Fei Liu ◽  
Hailei Yao ◽  
Qingxue Liu ◽  
Xuewu Wang ◽  
Xiaodong Dai ◽  
...  

2021 ◽  
Author(s):  
Dan-Chao Huang ◽  
Gang Xie ◽  
Ni-Yuan Peng ◽  
Jian-Guo Zou ◽  
Yao Xu ◽  
...  

AbstractMud shale hydration and swelling are major challenges in the development of water-based drilling fluids (WBDFs). In this work, the inhibition performance and inhibition mechanism of polyethylene glycol (PEG) and potassium chloride (KCl) were investigated by hot rolling recovery tests, linear swell tests, Fourier transform infrared spectroscopy, X-ray diffraction, atomic absorption spectrophotometry and X-ray photoelectron spectroscopy. The experimental results show that the combination of PEG and KCl achieved higher recovery and lower linear swelling rate than those obtained by individual PEG or KCl. Compared to the d-spacing of Na-montmorillonite (Na-Mt) with PEG or KCl, the d-spacing of Na-Mt with PEG+KCl was lower, which indicates that KCl and PEG have synergistic inhibition effect. This synergistic effect can replace sodium ions and water molecules from the interlayer space of Na-Mt and decrease the d-spacing of Na-Mt. Based on the above experimental results and analysis, a method for optimizing PEG and KCl concentrations was proposed and further verified by rheological and hot rolling recovery tests of WBDFs. Hence, the results of this work can provide valuable theoretical guidance for developing other synergistic inhibitors.


2018 ◽  
Vol 8 (10) ◽  
pp. 1839 ◽  
Author(s):  
Zhengsong Qiu ◽  
Jiangen Xu ◽  
Peng Yang ◽  
Xin Zhao ◽  
Tingbo Mou ◽  
...  

Research on using nanotechnology to solve shale instability problems in drilling engineering has been increasing. The combination of amphiphilic polymer and silica nanoparticles may be a new way to improve shale stability. Herein, an amphiphilic polymer/nano-silica composite (poly(styrene-methyl methacrylate-acrylamide)/nano-SiO2) was introduced as a novel shale stabilizer SMA/SiO2 for water-based muds, which possessed the advantages of both physical plugging and chemical inhibition during the drilling operations. The SMA/SiO2 was prepared and characterized by Fourier transform infrared spectra (FT-IR), nuclear magnetic resonance (1H-NMR), transmission electron microscope (TEM), particle size distribution (PSD) and thermogravimetric analysis (TGA) experiments, which confirmed that SMA/SiO2 was regularly spherical with nano-scale and showed good high-temperature resistance. To evaluate the plugging capacity of SMA/SiO2, the pressure transmission test and BET analysis were applied. The results indicated SMA/SiO2 was capable of effectively plugging the pores and fractures in shale. To evaluate the hydration inhibition capacity of SMA/SiO2, the rolling dispersion experiment and contact angle test were adopted. The results demonstrated that SMA/SiO2 could reduce the tendency of shale hydration, which was better than potassium chloride (KCl) and polymeric alcohol (JHC). In addition, SMA/SiO2 only created slight variations on the rheological parameters of the water-based muds (WBMs) and showed a significant filtration control performance. Due to the outstanding performance of physical plugging and chemical inhibition, SMA/SiO2 was expected to be a novel shale stabilizer to solve shale instability problems.


Fuel ◽  
2019 ◽  
Vol 244 ◽  
pp. 403-411 ◽  
Author(s):  
Han Jia ◽  
Pan Huang ◽  
Qiuxia Wang ◽  
Yugui Han ◽  
Shaoyan Wang ◽  
...  

2021 ◽  
pp. X
Author(s):  
Weichao DU ◽  
Xiangyun WANG ◽  
Taifei BI ◽  
Man LIU ◽  
Jie ZHANG ◽  
...  

In order to solve wellbore instability problem, a novel clay hydration inhibitor PDWC for water-based drilling fluids was synthesized by copolymerization of tris hydroxyethyl diallyl ammonium bromide (THDAB), sodium allyl sulfonate (AS) and methyl methacrylate (MMA) initiated by redox initiation in an aqueous solution. PDWC was characterized by Fourier transform infrared spectroscopy (FT-IR), Gel Permeation Chromatography (GPC) and Thermo-gravimetry-Differential Scanning Calorimetry (TGA-DSC), respectively. Evaluation of experiments indicated that PDWC showed superior clay hydration inhibition ability compared to some polymer and inorganic inhibitors. Characterization methods included particle size analysis, FT-IR, X-ray diffraction (XRD) and Scanning Electron Microscope (SEM) were utilized to study the inhibition mechanism of PDWC, it was observed that PDWC can be adsorbed on the surface of sodium montmorillonite (Na-MMT) by its hydroxyl functional group, which changed the micro-structure of Na-MMT and made the clay particles increased obviously. However, results of XRD demonstrated that it was difficult for PDWC to enter the inner layer crystal of Na-MMT.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4171
Author(s):  
Rabia Ikram ◽  
Badrul Mohamed Jan ◽  
Akhmal Sidek ◽  
George Kenanakis

An important aspect of hydrocarbon drilling is the usage of drilling fluids, which remove drill cuttings and stabilize the wellbore to provide better filtration. To stabilize these properties, several additives are used in drilling fluids that provide satisfactory rheological and filtration properties. However, commonly used additives are environmentally hazardous; when drilling fluids are disposed after drilling operations, they are discarded with the drill cuttings and additives into water sources and causes unwanted pollution. Therefore, these additives should be substituted with additives that are environmental friendly and provide superior performance. In this regard, biodegradable additives are required for future research. This review investigates the role of various bio-wastes as potential additives to be used in water-based drilling fluids. Furthermore, utilization of these waste-derived nanomaterials is summarized for rheology and lubricity tests. Finally, sufficient rheological and filtration examinations were carried out on water-based drilling fluids to evaluate the effect of wastes as additives on the performance of drilling fluids.


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