Partially replacing Styrene-Butadiene-Styrene (SBS) with other asphalt binder modifier: Feasibility study

2020 ◽  
Vol 249 ◽  
pp. 118752 ◽  
Author(s):  
Jun Liu ◽  
Kezhen Yan ◽  
Wenyao Liu ◽  
Xiaowen Zhao
2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2888
Author(s):  
Sylwia Dziadosz ◽  
Mieczysław Słowik ◽  
Filip Niwczyk ◽  
Marcin Bilski

The paper presents the results of laboratory investigation on asphalt binders relaxation at low temperature, carried out in a ductilometer using the tensile test with continuous force measurement. Polymer modified asphalt binder samples consisting of a 50/70 penetration grade bitumen mixed with a concentrate of styrene-butadiene-styrene (SBS) modified bitumen—a 160/220 penetration grade bitumen modified with a SBS copolymer in the amount of 9%—were tested. Therefore, polymer modified binders containing 3%, 4.5%, 6% and 7.5% SBS, respectively, were obtained and investigated. Tensile tests were performed at −16 °C on samples before aging and subjected to short-term aging (RTFOT). Test results in the form of relaxation curves have been mathematically described using a modified generalized Maxwell model. Based on the acquired results, it was shown that the increase of the SBS copolymer content in asphalt binder precipitates the relaxation process, while aging slows down this phenomenon. It has also been proven that with increased content of SBS elastomer in asphalt binder, the effect of short-term aging on binder’s stress relaxation ability at low temperatures is reduced.


2019 ◽  
Vol 22 (2) ◽  
pp. 94-101
Author(s):  
Miran Bahyam Ahmed ◽  
Alaa Hussein Abed ◽  
Yasir Mawla Hammood Al-Badran

Open-graded-fraction-course (OGFC), is a hot asphalt mixture usually utilized as a private purpose wearing course, because of open graded asphalt mixture and aggregates skeleton (stone-on-stone) contact, it contain a relatively high air voids’ percentage, after compaction which are permeable to water. In this research one type of gradation was used (12.5 mm) NMAS, to preparing the OGFC asphalt mixtures, penetration grade 40/50, crushed aggregate, asphalt content prepared with 4 % and up to 6 % by weight of mixture with 0.5 % increments. Optimum asphalt content (OAC) was selected based on these criteria, air voids content, asphalt draindown, permeability, and abrasion resistance (aged and un-aged) condition. The mix performance had been investigated by indirect tensile strength and moisture susceptibility (sensitivity) measured according to the (AASHTO T283-14). Results illustrate that the increasing of asphalt binder content leads to a decrease of the air voids content, abrasion loss and permeability values, while draindown increase, conversely, the indirect tensile strength (ITS) had been significantly increased for both conditions and this is a gaod suggestion to resistance alongside moisture susceptibility. It can be decided that the increasing of asphalt  binder percent in OGFC asphalt mixture, leads to an increase in the thickness of binder coating around the aggregates. On the other hand, the influence of modifier that prepared with 4% styrene-butadiene-styrene (SBS) on OGFC asphalt mixture tends to improve the mix properties and exhibit higher (TSR) as compared with original asphalt by (31, 27.7 and 24.4) % at asphalt percent (4.8, 5.3 and 5.8) %, respectively. The SBS improved the adhesion between aggregate and asphalt which leads to reduce stripping of HMA, horizontal deformation, and increased the tensile stiffness modulus value.


Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5715
Author(s):  
Bangwei Wu ◽  
Chufan Luo ◽  
Zhaohui Pei ◽  
Chuangchuang Chen ◽  
Ji Xia ◽  
...  

A wide variety of polymer additives have been widely used in recent years. However, the effect of different polymer additives on the durability of asphalt binders has not been investigated thoroughly. To evaluate the aging property of styrene-butadiene-styrene (SBS) asphalt binder with different polymer additives, three polymer modifiers, namely high modulus modifier (HMM), anti-rutting agent (ARA), and high viscosity modifier (HVM), were added to it. First, the Thin Film Over Test (TFOT) and Pressure Aging Vessel (PAV) was performed on the asphalt binders. The rheological properties of the four asphalt binders before and after aging were then checked by the Dynamic Shear Rheometer Test (DSR). The chemical compositions of the asphalt binders were determined by the Fourier Transform Infrared Spectrometer (FTIR) test. Several aging indicators were adopted to reflect the aging degree of the asphalt binders. The results show that when polymer additives are added to the SBS asphalt binder, the complex modulus, storage modulus, loss modulus, and rutting factor substantially increase and the phase angle decreases. All the test parameters become higher after aging. The phase angle of the SBS asphalt binder is the highest at both unaged and aged states, while its other parameters values are the smallest. Moreover, the Carbonyl Aging Indicator (CAI) of SBS with polymer additives becomes lower under both TFOT and PAV conditions, indicating that polymer additives can improve the aging resistance of SBS asphalt, of which HVM modifies the aging resistance best. Complex Modulus Aging Indicator (CMAI) and Storage Modulus Aging Indicator (SMAI) have the best correlation coefficients with CAI, and the two aging indicators can be used to predict the aging degree of polymer modified asphalt binders.


Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1006 ◽  
Author(s):  
Wensheng Wang ◽  
Yongchun Cheng ◽  
Peilei Zhou ◽  
Guojin Tan ◽  
Haitao Wang ◽  
...  

Superpave gyratory compaction (SGC) and Marshall compaction methods are essentially designed according to volumetric properties. In spite of the similarity, the optimum asphalt contents (OAC) of the two methods are greatly affected by the laboratory compaction process, which would further influence their performance. This study aims to evaluate the performance of styrene-butadiene-styrene (SBS)-modified stone mastic asphalt (SMA) with basalt fiber by using SGC and Marshall compaction methods. Basalt fiber was proved to improve and strength the basic properties of SBS-asphalt according to test results of asphalt binder. The effects of SGC and Marshall compaction methods on OAC and volumetric properties, i.e., density, air voids (VA), voids in mineral aggregates (VMA), and voids filled with asphalt (VFA), were evaluated in detail. Finally, the pavement performance of asphalt mixture prepared by SGC and Marshall compaction methods were compared in order to analyze the high-temperature creep, low-temperature splitting, and moisture stability performance. Results showed that the OAC of SGC (~5.70%) was slightly lower than that of Marshall method (5.80%). Furthermore, the pavement performance of SGC specimens were improved to a certain extent compared with Marshall specimens, indicating that SGC has a better compaction effect and mechanical performance.


2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Zahir Noori M. Taki ◽  
Alaa H. Abed ◽  
Hasan Al-Mosawe

Two types of polymers (plastomer (functionalized polyethylene (PE)) and elastomer (styrene-butadiene-styrene (SBS))) were used for shifting up asphalt binder performance grade (PG) and tensile strength resistance (moisture damage) of the asphalt concrete mixture. It is found that adding 3.5% functionalized polyethylene (PE) polymer to the binder is more effective than adding 4% styrene-butadiene-styrene (SBS) to shift up asphalt PG by two grades to PG 76-16. Furthermore, the viscosity of the binder increased about 200% when using 4% SBS, while there is no significant effect on viscosity when 3.5% PE is used. Therefore, there is no need to increase the temperature of mixing and compaction which may affect polymers. The indirect tensile test was used for measuring tensile strength ratio of dry and wet samples (conditioned according to ASTM D4867) and found that this ratio increased by 10 to 18% when using 4% SBS and 3.5% PE, respectively. Fracture energy (area under the strength-strain curve) and elasticity were estimated for neat and modified mixture samples.


2021 ◽  
Vol 1044 (1) ◽  
pp. 012003
Author(s):  
Ali Alnaqbi ◽  
Waleed Zeiada ◽  
Ghazi Al-Khateeb ◽  
Helal Ezzat ◽  
Abdallah Shanableh

Author(s):  
Jiri Stastna ◽  
Ludo Zanzotto ◽  
Otaca Vacin

Shear vibrations in conventional and polymer-modified asphalt binders are examined. Using dynamic compliances instead of moduli, viscous deformation effects can be separated from total deformation and the modified dynamic loss compliance and modified loss tangent functions can be defined. These two material functions appear to be more sensitive than viscoelastic moduli to the rheological behavior of asphalt binders and to changes caused by polymer addition. The characteristic temperature of the transition from the viscoelastic to viscous behavior of asphalt binder ( Tv) can be identified by using the viscous asymptote J”. The damping of shear vibrations that likely relates to the internal structure of asphalt material can be described by the modified loss tangent. The rheological behavior of the base asphalt 200/300 penetration grade and its blends with different amounts of radial styrene-butadiene-styrene rubber is investigated. Using master curves of dynamic functions and the Williams-Landel-Ferry form of the shift factor, isochrones of the original and modified dynamic material functions are constructed. Characteristic temperatures of the viscous transition ( Tv) and the glass transition ( Tg) are determined. Damping behaviors of the base and modified asphalts are studied.


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