scholarly journals The partitioning behavior of PAHs between settled dust and its extracted water phase: Coefficients and effects of the fluorescent organic matter

2021 ◽  
Vol 223 ◽  
pp. 112573
Author(s):  
Yanru Sheng ◽  
Caixia Yan ◽  
Minghua Nie ◽  
Min Ju ◽  
Mingjun Ding ◽  
...  
2005 ◽  
Vol 52 (3) ◽  
pp. 171-180 ◽  
Author(s):  
J. Vollertsen ◽  
A.H. Nielsen ◽  
W. Yang ◽  
T. Hvitved-Jacobsen

Transformations of organic matter, nitrogen and sulfur in sewers can be simulated taking into account the relevant transformation and transport processes. One objective of such simulation is the assessment and management of hydrogen sulfide formation and corrosion. Sulfide is formed in the biofilms and sediments of the water phase, but corrosion occurs on the moist surfaces of the sewer gas phase. Consequently, both phases and the transport of volatile substances between these phases must be included. Furthermore, wastewater composition and transformations in sewers are complex and subject to high, natural variability. This paper presents the latest developments of the WATS model concept, allowing integrated aerobic, anoxic and anaerobic simulation of the water phase and of gas phase processes. The resulting model is complex and with high parameter variability. An example applying stochastic modeling shows how this complexity and variability can be taken into account.


2014 ◽  
Vol 69 (9) ◽  
pp. 1828-1833 ◽  
Author(s):  
D. Lefebvre ◽  
V. Dossat-Létisse ◽  
X. Lefebvre ◽  
E. Girbal-Neuhauser

Temperature-phased anaerobic digestion with a 50–70 °C pre-treatment is widely proposed for sludge. Here, such a sludge pre-treatment (65 °C) was studied against the physical, enzymatic and biodegradation processes. The soluble and particulate fractions were analysed in terms of biochemical composition and hydrolytic enzymatic activities. Two kinetics of organic matter solubilisation were observed: a rapid transfer of the weak-linked biopolymers to the water phase, including sugars, proteins or humic acid-like substances, to the water phase, followed by a slow and long-term solubilisation of proteins and humic acid-like substances. In addition, during the heat treatment a significant pool of thermostable hydrolytic enzymes including proteases, lipases and glucosidases remains active. Consequently, a global impact on organic matter was the transfer of the biodegradable chemical oxygen demand (COD) from the particulate to the soluble fraction as evaluated by the biological methane potential test. However, the total biodegradable COD content of the treated sludge remained constant. The heat process improves the bio-accessibility of the biodegradable molecules but doesn't increase the inherent sludge biodegradability, suggesting that the chemistry of the refractory proteins and humic acids seems to be the real limit to sludge digestion.


1989 ◽  
Vol 32 (1) ◽  
pp. 12-23 ◽  
Author(s):  
James T. Teller

AbstractThe timing of deglaciation in the Lake Agassiz basin is critical in establishing the routing of meltwater and precipitation runoff from a 2,000,000-km2 region of central North America and in evaluating the influence this water had on rivers and oceans into which it drained. Dates of 12,400 ± 420 and 12,100 ± 160 yr B.P. for moss at the Rossendale site in Manitoba have long been a key for those advocating an “early” deglacial chronology in this region. However, new dates for wood from this site and paleoecological interpretations of ostracods, molluscs, and the dated moss all support a “young” deglacial scenario. Of particular significance is the fact that the dated moss, Scorpidium scorpioides, is a subaquatic type subject to contamination by old carbon dissolved from bedrock. In fact, most subaquatic moss may be unreliable for radiocarbon dating. For these reasons, the 12,400 and 12,100 yr B.P. dates are rejected. New dates of 9600 ± 70 and 9510 ± 90 yr B.P. for wood from the same organic-rich unit containing the dated moss, ostracods, and molluscs fit well with the “young” deglacial chronology of the southwestern Laurentide ice margin advocated by many. In short, the ice margin appears to have retreated into the southern Lake Agassiz basin after 12,000 yr B.P. and north of the Rossendale site by 11,000 yr B.P. About 10,000 yr B.P., following the Moorhead low-water phase, Lake Agassiz rose to the Campbell level. The dated organic matter at Rossendale was deposited in a lagoon behind the Campbell beach.


Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4580
Author(s):  
Yongchao Wang ◽  
Yanqing Xia ◽  
Zihui Feng ◽  
Hongmei Shao ◽  
Junli Qiu ◽  
...  

Pore network modeling based on digital rock is employed to evaluate the mobility of shale oil in Qingshankou Formation, Songliao Basin, China. Computerized tomography technology is adopted in this work to reconstruct the digital rock of shale core. The pore network model is generated based on the computerized tomography data. We simulate the dynamics of fluid flow in a pore network model to evaluate the mobility of fluid in shale formation. The results show that the relative permeability of oil phase increases slowly in the initial stage of the displacement process, which is mainly caused by the poor continuity of the oil phase. In the later stages, with the increase in the oil phase continuity, the range of relative permeability increases. With the increase of organic matter content, the permeability of the water phase remains unchanged at low water saturation, but gradually increases at high water saturation. At the same time, it can be seen that, with the increase in organic matter content, the isosmotic point of the oil–water phase permeability shifts to the left, indicating that the wettability to water phase gradually weakens.


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