scholarly journals A thermo-hydro-chemical model with porosity reduction and enthalpy production: Application to silica precipitation in geothermal reservoirs

2021 ◽  
Vol 7 ◽  
pp. 6260-6272
Author(s):  
Batoul M. Gisler ◽  
Stephen A. Miller
Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7415
Author(s):  
Ilyas Khurshid ◽  
Imran Afgan

The main challenge in extracting geothermal energy is to overcome issues relating to geothermal reservoirs such as the formation damage and formation fracturing. The objective of this study is to develop an integrated framework that considers the geochemical and geomechanics aspects of a reservoir and characterizes various formation damages such as impairment of formation porosity and permeability, hydraulic fracturing, lowering of formation breakdown pressure, and the associated heat recovery. In this research study, various shallow, deep and high temperature geothermal reservoirs with different formation water compositions were simulated to predict the severity/challenges during water injection in hot geothermal reservoirs. The developed model solves various geochemical reactions and processes that take place during water injection in geothermal reservoirs. The results obtained were then used to investigate the geomechanics aspect of cold-water injection. Our findings presented that the formation temperature, injected water temperature, the concentration of sulfate in the injected water, and its dilution have a noticeable impact on rock dissolution and precipitation. In addition, anhydrite precipitation has a controlling effect on permeability impairment in the investigated case study. It was observed that the dilution of water could decrease formation of scale while the injection of sulfate rich water could intensify scale precipitation. Thus, the reservoir permeability could decrease to a critical level, where the production of hot water reduces and the generation of geothermal energy no longer remains economical. It evident that injection of incompatible water would decrease the formation porosity. Thus, the geomechanics investigation was performed to determine the effect of porosity decrease. It was found that for the 50% porosity reduction case, the initial formation breakdown pressure reduced from 2588 psi to 2586 psi, and for the 75% porosity reduction case it decreased to 2584 psi. Thus, geochemical based formation damage is significant but geomechanics based formation fracturing is insignificant in the selected case study. We propose that water composition should be designed to minimize damage and that high water injection pressures in shallow reservoirs should be avoided.


2020 ◽  
Author(s):  
Batoul Gisler ◽  
Stephen A. Miller

<p>Quartz dissolution and precipitation is an important pore reducing process in geothermal reservoirs. We present a single-phase reactive flow model coupled with hydrodynamic flow and heat transfer components and implement it into COMSOL Multiphysics. The model includes diffusion and advection, and analytical equations are used to describe quartz kinetics and equilibrium concentrations with respect to the silicate phases. The numerical model can <em>a priori</em> be used to analyze the evolution of the porosity/permeability, and hence the productivity of the reservoir induced by heat extraction in geothermal reservoirs. A geothermal reservoir is modeled with realistic time steps, where its geometry is represented as a porous medium block in which chemical reactions occur between the pore fluid and the rock matrix. Future developments include adding a fracture and fracture networks to the system and analyzing the changes in effective stresses in the presence of reactive flow. Economic reservoir development requires a combined analysis of the thermo-hydro-mechanical and chemical processes, and precipitation processes may be important in post-seismic fluid flow processes.</p>


2021 ◽  
Vol 172 ◽  
pp. 145-157
Author(s):  
Haoran Xu ◽  
Jingru Cheng ◽  
Zhihong Zhao ◽  
Tianyi Lin ◽  
Guihong Liu ◽  
...  

2021 ◽  
pp. 126411
Author(s):  
Mingjie Chen ◽  
Ali Al-Maktoumi ◽  
Mohammad Mahdi Rajabi ◽  
Azizallah Izady ◽  
Hilal Al-Mamari ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Hidekazu Yoshida ◽  
Ryusei Kuma ◽  
Hitoshi Hasegawa ◽  
Nagayoshi Katsuta ◽  
Sin-iti Sirono ◽  
...  

AbstractIsolated silica concretions in calcareous sediments have unique shapes and distinct sharp boundaries and are considered to form by diagenesis of biogenic siliceous grains. However, the details and rates of syngenetic formation of these spherical concretions are still not fully clear. Here we present a model for concretion growth by diffusion, with chemical buffering involving decomposition of organic matter leading to a pH change in the pore-water and preservation of residual bitumen cores in the concretions. The model is compatible with some pervasive silica precipitation. Based on the observed elemental distributions, C, N, S, bulk carbon isotope and carbon preference index (CPI) measurements of the silica-enriched concretions, bitumen cores and surrounding calcareous rocks, the rate of diffusive concretion growth during early diagenesis is shown using a diffusion-growth diagram. This approach reveals that ellipsoidal SiO2 concretions with a diameter of a few cm formed rapidly and the precipitated silica preserved the bitumen cores. Our work provides a generalized chemical buffering model involving organic matter that can explain the rapid syngenetic growth of other types of silica accumulation in calcareous sediments.


2021 ◽  
Vol 11 (2) ◽  
pp. 700
Author(s):  
Irene A. Kanellopoulou ◽  
Ioannis A. Kartsonakis ◽  
Costas A. Charitidis

Cementitious structures have prevailed worldwide and are expected to exhibit further growth in the future. Nevertheless, cement cracking is an issue that needs to be addressed in order to enhance structure durability and sustainability especially when exposed to aggressive environments. The purpose of this work was to examine the impact of the Superabsorbent Polymers (SAPs) incorporation into cementitious composite materials (mortars) with respect to their structure (hybrid structure consisting of organic core—inorganic shell) and evaluate the microstructure and self-healing properties of the obtained mortars. The applied SAPs were tailored to maintain their functionality in the cementitious environment. Control and mortar/SAPs specimens with two different SAPs concentrations (1 and 2% bwoc) were molded and their mechanical properties were determined according to EN 196-1, while their microstructure and self-healing behavior were evaluated via microCT. Compressive strength, a key property for mortars, which often degrades with SAPs incorporation, in this work, practically remained intact for all specimens. This is coherent with the porosity reduction and the narrower range of pore size distribution for the mortar/SAPs specimens as determined via microCT. Moreover, the self-healing behavior of mortar-SAPs specimens was enhanced up to 60% compared to control specimens. Conclusively, the overall SAPs functionality in cementitious-based materials was optimized.


Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1027
Author(s):  
Joan Lario ◽  
Ángel Vicente ◽  
Vicente Amigó

The HIP post-processing step is required for developing next generation of advanced powder metallurgy titanium alloys for orthopedic and dental applications. The influence of the hot isostatic pressing (HIP) post-processing step on structural and phase changes, porosity healing, and mechanical strength in a powder metallurgy Ti35Nb2Sn alloy was studied. Powders were pressed at room temperature at 750 MPa, and then sintered at 1350 °C in a vacuum for 3 h. The standard HIP process at 1200 °C and 150 MPa for 3 h was performed to study its effect on a Ti35Nb2Sn powder metallurgy alloy. The influence of the HIP process and cold rate on the density, microstructure, quantity of interstitial elements, mechanical strength, and Young’s modulus was investigated. HIP post-processing for 2 h at 1200 °C and 150 MPa led to greater porosity reduction and a marked retention of the β phase at room temperature. The slow cooling rate during the HIP process affected phase stability, with a large amount of α”-phase precipitate, which decreased the titanium alloy’s yield strength.


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