Comparison of cracking activity of the core-shell composite MCM-41/HY & MCM-48/HY catalysts in the synthesis of organic liquid fuel from Mahua oil

2021 ◽  
pp. 112474
Author(s):  
Minglong Zhang ◽  
Ganesan Ramya ◽  
Kathirvel Brindhadevi ◽  
Ashraf Elfasakhany ◽  
Amany Salah Khalifa ◽  
...  
2020 ◽  
Vol 65 (10) ◽  
pp. 904
Author(s):  
V. O. Zamorskyi ◽  
Ya. M. Lytvynenko ◽  
A. M. Pogorily ◽  
A. I. Tovstolytkin ◽  
S. O. Solopan ◽  
...  

Magnetic properties of the sets of Fe3O4(core)/CoFe2O4(shell) composite nanoparticles with a core diameter of about 6.3 nm and various shell thicknesses (0, 1.0, and 2.5 nm), as well as the mixtures of Fe3O4 and CoFe2O4 nanoparticles taken in the ratios corresponding to the core/shell material contents in the former case, have been studied. The results of magnetic research showed that the coating of magnetic nanoparticles with a shell gives rise to the appearance of two simultaneous effects: the modification of the core/shell interface parameters and the parameter change in both the nanoparticle’s core and shell themselves. As a result, the core/shell particles acquire new characteristics that are inherent neither to Fe3O4 nor to CoFe2O4. The obtained results open the way to the optimization and adaptation of the parameters of the core/shell spinel-ferrite-based nanoparticles for their application in various technological and biomedical domains.


MRS Advances ◽  
2020 ◽  
Vol 5 (40-41) ◽  
pp. 2121-2127
Author(s):  
Ssu-Hao Huang ◽  
Pei-Hua Chen ◽  
Yan-Ping Chen ◽  
Muoi Tang

ABSTRACTThe polymerization of 3,4-ethylenedioxythiophene (EDOT) onto nanosilica (SiO2) was synthesized in this study by using supercritical carbon dioxide (SCCO2). With the addition of dopants of p-toluenesulfonic acid (p-TSA) or decylbenzene sulfonic acid (DBSA), the PEDOT/SiO2 composite became conductive. The product was characterized by FTIR spectroscopy and the core-shell structure was confirmed through the TEM images. The electrical properties were analyzed by UV-vis absorbance and four-point probe measurement. DBSA is shown as the better dopants with the molar ratio (DBSA/EDOT) of 0.2 at the reaction time of 48 hours. The maximum coating percentage is 63 wt% under the optimal operation conditions at 40oC and 280 bar. The conductivity is tuned up to 6.6×10-2 S/cm after the coating process.


2010 ◽  
Vol 168-170 ◽  
pp. 1833-1836
Author(s):  
Gang Qiang Geng ◽  
Jing Tao Guo ◽  
Jun Jun Zou ◽  
Gong Xun Bian

In order to obtain super aerogels heat insulating composite materials with silane coupling agent on the in-situ surface treatment. The core-shell structure composite materials have been prepared by dispersion polymerization process of polystyrene grafted on the SiO2 particles. By TEM on these samples the impact of the system components initiator polymerization parameters and dispersion process was discussed. The results showed that the system component of the greatest impact on conversion rate is the ratio of aerogels /St ,the optimum reaction temperature is 75 °C.With organic initiator KPS as initiator after a unique ultrasound technique to obtain the core-shell composite materials structure which coating is 70%.


2015 ◽  
Vol 3 (22) ◽  
pp. 4539-4545 ◽  
Author(s):  
Cuiling Du ◽  
Anhe Wang ◽  
Jinbo Fei ◽  
Jie Zhao ◽  
Junbai Li

The core–shell composite of Au–polypyrrole nanorods with high two-photon photothermal effect and stability could efficiently kill tumor cells under irradiation.


2014 ◽  
Vol 936 ◽  
pp. 359-363
Author(s):  
Yan Li Wu ◽  
Min Liao ◽  
Hai Xin Ding ◽  
Ru Chun Yang ◽  
Dan Dan Xiong ◽  
...  

The SiO2/NaGdF4:Eu3+ core/shell composite was prepared by a template-mediated method, making monodispersed SiO2 as core and NaGdF4:Eu colloids as shell, the morphology and the core-shell structure of the resulting particles were analyzed by SEM,X-ray diffraction, and the photo-luminescence and magnetic properties of the microspheres were investigated too. The results shows the composite have great potential to be used as homogeneous magnetic/optical bifunctional material.


2003 ◽  
Vol 796 ◽  
Author(s):  
Zhexiong Tang ◽  
Hui Wan ◽  
Robert Clark ◽  
Sze C. Yang

ABSTRACTWe report the synthesis of new inorganic/organic composite particles with a core/shell structure. The core component is an inorganic oxide (e.g. TiO2, CeO2 or MoO3), and the shell component is a double-strand polyaniline. Three methods for material synthesis were examined. The electrochemical properties of one type of the composite particles show electronic interaction between the organic conducting polymer shell and its inorganic core. The double-strand polyaniline in the composite shows better pH stability of the conductive form than that of the corresponding single-strand polyaniline in a similar core/shell composite.


ACS Nano ◽  
2009 ◽  
Vol 3 (8) ◽  
pp. 2235-2240 ◽  
Author(s):  
Keyou Yan ◽  
Qingzhong Xue ◽  
Dan Xia ◽  
Huijuan Chen ◽  
Jie Xie ◽  
...  

2015 ◽  
Vol 17 (14) ◽  
pp. 8802-8810 ◽  
Author(s):  
Biao Zhao ◽  
Gang Shao ◽  
Bingbing Fan ◽  
Wanyu Zhao ◽  
Yajun Xie ◽  
...  

The microwave absorption properties of the core–shell Ni@rutile TiO2 composite are superior to those of the Ni@anatase TiO2 composite.


2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Fengyun Guo ◽  
Ziyi Guo ◽  
Lei Gao ◽  
Dongming Qi ◽  
Guichu Yue ◽  
...  

The core-shell NaYF4/Yb/Tm/TiO2 hollow composite fibers were prepared by coaxial electrospinning and high-temperature calcination. The composite fibers exhibit excellent photocatalytic activity under the dual synergistic of regulating the core-shell hollow microstructure and the composition by doping nanoparticles. Compared with commercial P25 and hollow fiber without nanoparticles, the degradation efficiency of rhodamine B using the core-shell composite fiber was significantly improved up to 99%. Moreover, the nanoparticles in the composite fibers can exist stably and maintain good structure and photocatalytic activity after repeated use. Therefore, the composite fiber has a wide application prospect in photocatalytic degradation of organic pollutants.


2011 ◽  
Vol 347-353 ◽  
pp. 3302-3305
Author(s):  
Jing Na Zhu ◽  
Zhen Lu Shen ◽  
Wei Min Mo ◽  
Mei Chao Li

Abstract. The core-shell composite of platinum/polyaniline (Pt@PAN) had been prepared by chemical synthesis approach. Reduction of the platinum salt in aqueous solution leaded to the formation of platinum nanoparticles, and then polyaniline were synthesized by interfacial polymerization to get Pt@PAN composite. Transmission electron microscopy of Pt@PAN showed Pt particles are uniform with spherical and granular morphology. Pt@PAN was also characterized by EDAX, XPS and FTIR.


Sign in / Sign up

Export Citation Format

Share Document