Influence of chemical interesterification on thermal behavior, microstructure, polymorphism and crystallization properties of canola oil and fully hydrogenated cottonseed oil blends

2009 ◽  
Vol 42 (8) ◽  
pp. 1153-1162 ◽  
Author(s):  
Ana Paula Badan Ribeiro ◽  
Rodrigo Corrêa Basso ◽  
Renato Grimaldi ◽  
Luiz Antonio Gioielli ◽  
Adenilson Oliveira dos Santos ◽  
...  
2009 ◽  
Vol 16 (3) ◽  
pp. 362-381 ◽  
Author(s):  
ANA PAULA BADAN RIBEIRO ◽  
RODRIGO CORRÊA BASSO ◽  
RENATO GRIMALDI ◽  
LUIZ ANTONIO GIOIELLI ◽  
LIRENY APARECIDA GUARALDO GONÇALVES

2013 ◽  
Vol 27 (6) ◽  
pp. 3306-3315 ◽  
Author(s):  
Jinwen Chen ◽  
Hena Farooqi ◽  
Craig Fairbridge

2016 ◽  
Vol 7 (2) ◽  
pp. 81-96
Author(s):  
W. EL-Reffaei ◽  
A. EL-Sebeay ◽  
Hanan EL-Ghandour ◽  
Eman Ragheb ◽  
S. Badr

2010 ◽  
Vol 10 (4) ◽  
pp. 25-34 ◽  
Author(s):  
david s. shields

From the 1770s to the 1880s agriculturists and cooks sought to develop culinary oils from plants. Thomas Jefferson's attempts to introduce the olive into the agriculture of the United States, as a partial substitute for lard in cookery and as a cheap oleo for the consumption of slaves, met with limited success, even in the southeast, because periodic freezes and high humidity thwarted the development of groves. Southern slaves from West Africa supplied their own oil, derived from benne (Sesamum indicum). Benne oil was merely one feature of an elaborate African-American cuisine employing sesame that included benne soup, benne and greens, benne and hominy, benne candy, and benne wafers. Only the last item has survived as a feature of regional and ethnic cookery. In the first decades of the nineteenth century, planter experimentalists began the commercial scale production of benne oil, establishing it as the primary salad oil and the second favored frying medium in the southern United States. It enjoyed acceptance and moderate commercial success until the refinement of cottonseed oil in the 1870s and 1880s. Cotton seed, a waste product of the south's most vital industry, was turned into a revenue stream as David Wesson and other scientists created a salad oil and frying medium designedly tasteless and odorless, and a cooking fat, hydrogenated cottonseed oil (Cottonlene or Crisco) that could cheaply substitute for lard in baking. With the recent recovery of regional foodways, both the olive and sesame are being revived for use in the neo-southern cookery of the twenty-first century.


2016 ◽  
Vol 78 (6-5) ◽  
Author(s):  
Norizzah Abd Rashid ◽  
Tunku Saidatul Sa’adiah Tunku Safuan ◽  
Amalyna Teja Kelana ◽  
Mohd Akram Zuher ◽  
Zaliha Omar

Palm stearin (PS) and rice bran oil (RBO) were blended in the mass ratio of 100:0, 70:30, 50:50, 30:70 and 0:100. The oil blends were subjected to chemical interesterification (CIE) catalyzed by sodium methoxide (0.2% w/w). The following analysis were carried out before and after CIE: triacylglycerol (TAG) composition, slip melting point (SMP), solid fat content (SFC), microstructure, polymorphism and hardness index (HI).  After chemical interesterification, there were decrease and increase in the amount of several TAG. Changes in TAG composition caused changes in the physical properties of the blends. Both SMP and SFC of all blends decreased significantly (p<0.05) after interesterification except for RBO. Chemical interesterification also reduced the eutectic interaction at 5°C. However, for hardness index, only blends with 50% and 100% PS decreased significantly (p<0.05) from 33.197 to 26.097 and 5.397 to 3.720, respectively. The crystals of the blends became smaller and reduced in number after interesterification. Interesterification promoted the formation of more β' crystals than β in all blends. The 30:70 PSRBO blend was the most suitable for margarine production as it melted close to body temperature.


2010 ◽  
Vol 93 (1) ◽  
pp. 323-326 ◽  
Author(s):  
Ni Zhang ◽  
Zhiying Ding ◽  
Hao Li ◽  
Xin Wang ◽  
Xiaodong Shao

Abstract A practical and nontarnishing method for the determination of trace nickel (Ni) in hydrogenated cottonseed oil by inductively coupled plasma/mass spectrometry (ICP/MS) was developed. In order to avoid tarnishing in the pretreatment of samples, the technology of pressurized PTFE vessel acid digestion was applied. The temperature and acid content in the digestion were optimized. The results showed that hydrogenated cottonseed oil could be digested completely by the proposed method. Compared with the U.S. Pharmacopeia 28 and British Pharmacopoeia 2003 methods, the developed method avoided the risk of using platinum and the tarnish from silica crucibles. In addition, the analytical cycle of the test solution was shortened by the use of ICP/MS instead of graphite furnace atomic absorption spectrophotometry.


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