Synthesis, structures, DFT studies and luminescent properties of copper(I)-diimine complexes and application in yellow-green light-emitting diode

2021 ◽  
pp. 120501
Author(s):  
Tian-Cheng Wu ◽  
Qiao-Long Hu ◽  
Ting-Hong Huang ◽  
Yi-Shun Cui ◽  
Dan Zheng ◽  
...  
2021 ◽  
Vol 118 (2) ◽  
pp. 021102
Author(s):  
Dong-Pyo Han ◽  
Ryoto Fujiki ◽  
Ryo Takahashi ◽  
Yusuke Ueshima ◽  
Shintaro Ueda ◽  
...  

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Fumiya Osawa ◽  
Kazuhiro Marumoto

Abstract Spin-states and charge-trappings in blue organic light-emitting diodes (OLEDs) are important issues for developing high-device-performance application such as full-color displays and white illumination. However, they have not yet been completely clarified because of the lack of a study from a microscopic viewpoint. Here, we report operando electron spin resonance (ESR) spectroscopy to investigate the spin-states and charge-trappings in organic semiconductor materials used for blue OLEDs such as a blue light-emitting material 1-bis(2-naphthyl)anthracene (ADN) using metal–insulator–semiconductor (MIS) diodes, hole or electron only devices, and blue OLEDs from the microscopic viewpoint. We have clarified spin-states of electrically accumulated holes and electrons and their charge-trappings in the MIS diodes at the molecular level by directly observing their electrically-induced ESR signals; the spin-states are well reproduced by density functional theory. In contrast to a green light-emitting material, the ADN radical anions largely accumulate in the film, which will cause the large degradation of the molecule and devices. The result will give deeper understanding of blue OLEDs and be useful for developing high-performance and durable devices.


2005 ◽  
Vol 23 (2) ◽  
pp. 167-171 ◽  
Author(s):  
Elke M. Vinck ◽  
Barbara J. Cagnie ◽  
Maria J. Cornelissen ◽  
Heidi A. Declercq ◽  
Dirk C. Cambier

2015 ◽  
Vol 20 (2) ◽  
pp. 020502 ◽  
Author(s):  
Noa Alon ◽  
Hamootal Duadi ◽  
Ortal Cohen ◽  
Tamar Samet ◽  
Neta Zilony ◽  
...  

2015 ◽  
Vol 2015 ◽  
pp. 1-4 ◽  
Author(s):  
W. Wang ◽  
Y. Cai ◽  
Y. B. Zhang ◽  
H. J. Huang ◽  
W. Huang ◽  
...  

A parallel and series network structure was introduced into the design of the high-voltage single-chip (HV-SC) light-emitting diode to inhibit the effect of current crowding and to improve the yield. Using such a design, a6.6×5 mm2large area LED chip of 24 parallel stages was demonstrated with 3 W light output power (LOP) at the current of 500 mA. The forward voltage was measured to be 83 V with the same current injection, corresponding to 3.5 V for a single stage. The LED chip’s average thermal resistance was identified to be 0.28 K/W by using infrared thermography analysis.


2020 ◽  
Vol 41 (3) ◽  
pp. 233-240
Author(s):  
郭 洁 GUO Jie ◽  
陆 敏 LU Min ◽  
孙思琪 SUN Si-qi ◽  
胡 强 HU Qiang ◽  
张 佳 ZHANG Jia ◽  
...  

2012 ◽  
Vol 100 (6) ◽  
pp. 061106 ◽  
Author(s):  
S.-P. Chang ◽  
Y.-C. Chen ◽  
J.-K. Huang ◽  
Y.-J. Cheng ◽  
J.-R. Chang ◽  
...  

2002 ◽  
Vol 55 (8) ◽  
pp. 499 ◽  
Author(s):  
M.-A. Hsu ◽  
T. J. Chow

A PPV-type polymer (1) incorporating 5,5�-diquinolinyl moieties is prepared by a Yamamoto homo-coupling reaction from the dibromide (2). Since all the hydroxyl groups were alkylated, this polymer showed high solubility in most organic solvents. It can be spin-coated readily to form a thin layer in the fabrication of light emitting diode (LED) devices. The adjacent quinoline rings are twisted to form a dihedral angle due to steric hindrance, so that π-conjugation is confined within each monomer unit. The emission spectra of (1) and (2) are nearly identical. The reduction potential of (1) was estimated to be –1.10 V (onset), with a band gap of 2.53 eV (490 nm). A single hetero-junction LED device fabricated by combining the films of poly(vinylkarbazol) (PVK) and (1) yielded promising results. The device ITO/PVK/(1)/Ca/Al exhibited a turn-on voltage at 6 V and reached a maximal brightness of 250 cd/m2 at 15 V. An alternate potential usage of (1) as an electron-injecting material was also explored on a green-light device using coumarin-6 as an emitter.


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