Optimization of lignin extraction from alkaline treated mango seed husk by high shear homogenization-assisted organosolv process using response surface methodology

Author(s):  
Fatimatu Bello ◽  
Annie Chimphango
2021 ◽  
Vol 11 (4) ◽  
pp. 1739
Author(s):  
Muhammad Ajaz Ahmed ◽  
Jae Hoon Lee ◽  
Joon Weon Choi

A synergistic combination of dioxane, acetic acid, and HCl was investigated for lignin extraction from pine wood biomass. After initial screening of reagent combination, response surface methodology (RSM) was used to optimize the lignin yield with respect to the variables of time 24–72 h, solids loading 5–15%, and catalyst dose 5–15 mL. A quadratic model predicted 8.33% of the lignin yield, and it was further confirmed experimentally and through the analysis of variance (ANOVA). Lignin at optimum combination exhibited features in terms of derivatization followed by reductive cleavage (DFRC) with a value of (305 µmol/gm), average molecular weights of 4358 and polydispersity of 1.65, and 2D heteronuclear single quantum coherence nuclear magnetic resonance spectrum (2D-HSQC NMR) analysis showing relative β-O-4 linkages (37.80%). From here it can be suggested that this fractionation can be one option for high quality lignin extraction from lignocellulosic biomass.


Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 591 ◽  
Author(s):  
Xuyang Cui ◽  
Junhong Yang ◽  
Xinyu Shi ◽  
Wanning Lei ◽  
Tao Huang ◽  
...  

Pelletization is a significant approach for the efficient utilization of biomass energy. Sunflower seed husk is a common solid waste in the process of oil production. The novelty of this study was to determine the parameters during production of a novel pellet made from sunflower seed husk. The energy consumption (W) and physical properties (bulk density (BD) and mechanical durability (DU)) of the novel pellet were evaluated and optimized at the laboratory by using a pelletizer and response surface methodology (RSM) under a controlled moisture content (4%–14%), compression pressure (100–200 MPa), and die temperature (70–170 °C). The results show that the variables of temperature, pressure, and moisture content of raw material are positively correlated with BD and DU. Increasing the temperature and moisture content of raw materials can effectively reduce W, while increasing the pressure has an adverse effect on W. The optimum conditions of temperature (150 °C), pressure (180 MPa), and moisture content (12%) led to a BD of 1117.44 kg/m3, DU of 98.8%, and W of 25.3 kJ/kg in the lab. Overall, although the nitrogen content was slightly high, the novel manufactured pellets had excellent performance based on ISO 17225 (International Organization for Standardization of 17225, Geneva, Switzerland, 2016). Thus, sunflower seed husk could be considered as a potential feedstock for biomass pelletization.


2013 ◽  
Vol 238 ◽  
pp. 142-150 ◽  
Author(s):  
Chirangano Mangwandi ◽  
Ahmad B. Albadarin ◽  
Ala'a H. Al-Muhtaseb ◽  
Stephen J. Allen ◽  
Gavin M. Walker

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