Optical band gap, glass transition temperature and structural studies of (100−2x)TeO2–xAg2O–xWO3 glass system

2010 ◽  
Vol 504 (2) ◽  
pp. 468-474 ◽  
Author(s):  
G. Upender ◽  
S. Ramesh ◽  
M. Prasad ◽  
V.G. Sathe ◽  
V.C. Mouli
2020 ◽  
Vol 12 (4) ◽  
pp. 545-554
Author(s):  
R. Khajuria ◽  
A. Sharma ◽  
P. Sharma

The rationale of this study is to investigate band gap tailoring of Sb-Se-Sn chalcogenide glasses. This study has been accompanied by the assessment of various theoretical parameters such as average co-ordination number, Lone-pair of electrons, number of constraints, average heat of atomization, mean bond energy and glass transition temperature. It has been observed that almost all these physical parameters have been enhanced with the increase in tin (Sn) content except Lone-pair of electrons. The number of lone-pair electrons has been decreased with the increase in Sn content. The glass transition temperature has been observed to increase due to the addition of Sn atom in the Se-Sb glassy system. The band gap is decreasing with increase in Sn content due to overall decrease in the average single bond energy of the Sb-Se-Sn glassy system.  


2017 ◽  
Vol 888 ◽  
pp. 146-150 ◽  
Author(s):  
Siti Hafizah Mohamad ◽  
Mohd Al Amin Muhamad Nor

The effect addition of Na2O on the solubility properties of phosphate glass of the composition, 45P2O5-18CaO-xNa2O-(34-x)K2O-6Al2O3, where x = 0,5,10,15 and 20 wt. %. has been studied. Glass transition temperature (Tg) of glass samples, weight loss and pH of the immersion solution were measured. The Tg value of the phosphate glass also decreased with the incorporation of Na2O up to 10 wt. % and increased with the incorporation of 15 and 20 wt. %. These results indicates that the solubility and Tg value of phosphate glass were highly influence by the glass composition. The substitution of Na2O to the phosphate glass system with the present of K2O has decrease the solubility of phosphate glass. The released of phosphate and calcium ion seem to decrease with the increasing of Na2O content in the glass composition.


2009 ◽  
Vol 118 (2-3) ◽  
pp. 298-302 ◽  
Author(s):  
G. Upender ◽  
Suresh Bharadwaj ◽  
A.M. Awasthi ◽  
V. Chandra Mouli

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