Investigation of thermoelectric power with modification of two band model with linear T term for superconductors and thermal conductivity study of Se added YBCO samples

2014 ◽  
Vol 584 ◽  
pp. 553-557 ◽  
Author(s):  
S. Altin ◽  
M.A. Aksan ◽  
M.E. Yakinci
1975 ◽  
Vol 53 (5) ◽  
pp. 486-497 ◽  
Author(s):  
J. G. Cook ◽  
M. J. Laubitz ◽  
M. P. Van der Meer

Data are presented for the thermal and electrical resistivity and thermoelectric power of two samples of Ca (having residual resistance ratios of 10 and 70) between 30 and 300 K. Large deviations from both Matthiessen's rule and the Wiedemann–Franz relationship are observed. The former are tentatively attributed to the presence of two distinct groups of carriers in Ca, and analyzed using the two band model. The latter deviations are interpreted as the effects of band structure. The thermoelectric power of Ca is large. In many respects the transport properties of Ca appear to be similar to those of the transition metals.


1972 ◽  
Vol 50 (3) ◽  
pp. 196-205 ◽  
Author(s):  
M. J. Laubitz ◽  
T. Matsumura

The thermal conductivity, electrical resistivity, and absolute thermoelectric power of pure palladium have been determined from 90 to 1300 K in two experimental systems of proven reliability. These properties are compared with the sparse available literature data, and show large deviations from them, particularly for the thermal conductivity at high temperatures. The results are also analyzed in terms of a simple two-band model, where one band contains the carriers, and the other acts as a trap into which phonons scatter the carriers. When the recent density of states values of Mueller et al. are used, the model predicts correctly the temperature variation of the electrical resistivity, and reasonably well its observed magnitude and the observed Wiedemann–Franz ratio. However, the model fails badly in respect to the absolute thermoelectric power, predicting values twice as large as the observed ones. Modifications to the model are suggested which may improve the fit between the predicted and observed values.


1982 ◽  
Vol 37 (10) ◽  
pp. 1127-1131 ◽  
Author(s):  
D. H. Kurlat ◽  
M. Rosen

The Seebeck coefficient (S) of Sni1-x- Tex liquid alloys was measured as a function of concentration and temperature. For 0 ≦ x <0.45 the behaviour is metallic; S values are small and negative, rising linearly with temperature. The predicted values of Ziman's theory when using the hard sphere approximation disagree with the experimental ones. The change in sign occurs for 0.45. For x = 0.5 (stoichiometric composition) the thermoelectric power decreases linearly with temperature. This fact is explained assuming a two-band model. For x ≧ 0.6 the liquid alloy becomes more semiconducting and presents a maximum in the isotherms of S for x = 0.65. For the excess tellurium concentration range we have calculated the difference EF - EV and γ/kB, assuming a S(1/T) law. The experimental values are compared with those of Dancy and Glazov.


1994 ◽  
Vol 49 (9) ◽  
pp. 6385-6387 ◽  
Author(s):  
V. P. S. Awana ◽  
V. N. Moorthy ◽  
A. V. Narlikar

1974 ◽  
Vol 52 (10) ◽  
pp. 861-867 ◽  
Author(s):  
D. J. Huntley ◽  
R. F. Frindt

The Hall coefficient, magnetoresistance, and thermoelectric power of several specimens of NbSe2 have been measured as a function of temperature for various crystal orientations. A range of behaviour of the Hall coefficient has been observed varying from a reversal at 27 K for the purest specimen to no temperature dependence for the most impure. The magnetoresistance shows large deviations from Kohler's rule which are correlated with the Hall reversal. The results are discussed in terms of a possible phase change or a two-band model.


1972 ◽  
Vol 50 (22) ◽  
pp. 2836-2839 ◽  
Author(s):  
F. J. Blatt

The thermoelectric power of iron exhibits a broad maximum of about 17 µV/K near 200 K. The relatively high temperature of this maxim and its dependence on alloying and cold work argue against phonon drag as the mechanism responsible for this peak. Recently, MacInnes and Schröder proposed that this peak derives from anisotropic (scew) scattering due to spin–orbit coupling, which may be simulated by a large effective transverse magnetic field. Their calculations, which reproduce experimental observations quite well, are based on an expression derived by Sondheimer that is valid for an ideal two-band model. According to this model and the suggestion of MacInnes and Schröder, the thermoèlectric power of iron should be strongly influenced by domain alignment. Measurements of the dependence of the thermoelectric power of iron in transverse and longitudinal magnetic fields reported here yield results contrary to the predictions of that model.


1963 ◽  
Vol 41 (10) ◽  
pp. 1542-1546 ◽  
Author(s):  
M. P. Sarachik ◽  
G. E. Smith ◽  
J. H. Wernick

The thermoelectric powers of the intermetallic compounds V3Ge, V3Si, V3Ga, and V3Sn have been measured from their superconducting transition temperatures to room temperature. It is found that the thermoelectric coefficients are all positive and about 10 μv/° K at room temperature. The coefficients for V3Si, V3Ga, and V3Sn are monotonically increasing functions of the temperature, whereas for V3Ge there is a pronounced maximum at about 60° K. The results are discussed in terms of a two-band model consisting of a conduction band and a d-band.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Natsumi Komatsu ◽  
Yota Ichinose ◽  
Oliver S. Dewey ◽  
Lauren W. Taylor ◽  
Mitchell A. Trafford ◽  
...  

AbstractLow-dimensional materials have recently attracted much interest as thermoelectric materials because of their charge carrier confinement leading to thermoelectric performance enhancement. Carbon nanotubes are promising candidates because of their one-dimensionality in addition to their unique advantages such as flexibility and light weight. However, preserving the large power factor of individual carbon nanotubes in macroscopic assemblies has been challenging, primarily due to poor sample morphology and a lack of proper Fermi energy tuning. Here, we report an ultrahigh value of power factor (14 ± 5 mW m−1 K−2) for macroscopic weavable fibers of aligned carbon nanotubes with ultrahigh electrical and thermal conductivity. The observed giant power factor originates from the ultrahigh electrical conductivity achieved through excellent sample morphology, combined with an enhanced Seebeck coefficient through Fermi energy tuning. We fabricate a textile thermoelectric generator based on these carbon nanotube fibers, which demonstrates high thermoelectric performance, weavability, and scalability. The giant power factor we observe make these fibers strong candidates for the emerging field of thermoelectric active cooling, which requires a large thermoelectric power factor and a large thermal conductivity at the same time.


1967 ◽  
Vol 45 (1) ◽  
pp. 119-126 ◽  
Author(s):  
J. Basinski ◽  
R. Olivier

Hall effect and resistivity measurements have been made in the temperature range 4.2–360 °K on several samples of n-type GaAs grown under oxygen atmosphere and without any other intentional dopings. The principal shallow donor in this material is considered to be Si. All samples exhibited impurity-band conduction at low temperature. Electron concentrations in the conduction band were calculated, using a two-band model, and then fitted to the usual equation expressing charge neutrality. A value of 2.3 × 10−3 eV was obtained for the ionization energy of the donors, for donor concentration ranging from 5 × 1015 cm−3 to 2 × 1016 cm−3. The conduction in the impurity band was of the hopping type for these concentrations. A value of 3.5 × 1016 cm−3 was obtained for the critical transition concentration of the impurity-band conduction to the metallic type.


Sign in / Sign up

Export Citation Format

Share Document