A bipolar metal phthalocyanine complex for sodium dual-ion battery

2020 ◽  
Author(s):  
Heng-Guo Wang ◽  
Haidong Wang ◽  
Yan Li ◽  
Yunong Wang ◽  
Zhenjun Si
Keyword(s):  
Metal Phthalocyanine ◽  
Phthalocyanine Complex

Structure and optical properties of fullerene C60 complex with dipyridinated iron(II) phthalocyanine [Fe(II)Pc(C5H5N)2]·C60·4C6H4Cl2: First structure of bisaxially coordinated iron(II) phthalocyanine complex with acetonitrile Fe(II)Pc(CH3CN)2

2014 ◽  
Vol 18 (01n02) ◽  
pp. 87-93 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Alexey V. Kuzmin ◽  
Sergey V. Simonov ◽  
Salavat S. Khasanov ◽  
Rimma N. Lyubovskaya
Keyword(s):  
Optical Properties ◽  
Charge Transfer ◽  
Bond Length ◽  
Single Crystals ◽  
Fullerene C60 ◽  
Metal Phthalocyanine ◽  
Phthalocyanine Complex ◽  
Uv Visible ◽  
Center Distance ◽  
Molecular Solid

The complex of fullerene C 60 with dipyridinated iron(II) phthalocyanine [ Fe ( II ) Pc ( C 5 H 5 N )2]· C 60·4 C 6 H 4 Cl 2 (1) has been obtained as single crystals. According to the IR- and UV-visible-NIR spectra, 1 is molecular solid with no charge transfer from Fe ( II ) Pc ( C 5 H 5 N )2 to C 60· C 60 molecules form closely packed linear columns in 1 along the b axis with a uniform interfullerene center-to center distance of 9.99 Å and multiple short van der Waals (vdW) C … C contacts between fullerenes of 3.10–3.18 Å. Totally each Fe ( II ) Pc ( C 5 H 5 N )2 unit is surrounded by four C 60 molecules two of which form short vdW C … C contacts with the phthalocyanine plane locating near two adjacent phenylene substituents of Fe ( II ) Pc . The Fe ( II ) Pc ( C 5 H 5 N )2 geometry remains almost unchanged as compared with that of fullerene free Fe ( II ) Pc ( C 5 H 5 N )2. The iron(II) atoms are located exactly in the Pc plane, the Fe - N ( C 5 H 5 N ) bond length is 2.038(3) Å and the averaged of the Fe - N ( Pc ) bond length is 1.935(3) Å. Bisaxially coordinated iron(II) phthalocyanine complex with acetonitrile Fe ( II ) Pc ( CH 3 CN )2 does not cocrystallize with C 60. Nevertheless, good quality crystals of [ Fe ( II ) Pc ( CH 3 CN )2]·2 C 6 H 4 Cl 2 (2) were isolated in this synthesis. That is the first structure of bisaxially coordinated metal phthalocyanine complex with nitrile containing solvent. Acetonitrile unusually strongly coordinates to Fe ( II ) Pc with the Fe – N ( CH 3 CN ) bond length of 1.938(1) Å. The iron(II) atoms are located in the Pc plane and the averaged length of the Fe - N ( Pc ) bonds is 1.934(1) Å.

Transition metal phthalocyanine and porphyrin complexes as catalysts for the polymerization of alkenes

2001 ◽  
Vol 79 (5-6) ◽  
pp. 1026-1029 ◽  
Author(s):  
Gregory S Long ◽  
Benjamin Snedeker ◽  
Kyle Bartosh ◽  
Michelle L Werner ◽  
Ayusman Sen
Keyword(s):  
Transition Metal ◽  
Metal Phthalocyanine ◽  
Nickel Phthalocyanine ◽  
Phthalocyanine Complex

Vanadium phthalocyanine and porphyrin complexes, in conjunction with methylaluminoxane (MAO) or EtAlCl2 cocatalyst, have been found to catalyze the homopolymerization of ethene. In addition, the copolymerization of ethene with propene and 1-decene was achieved with the vanadium phthalocyanine complex and MAO. Nickel phthalocyanine complex was also found to catalyze the polymerization of ethene in the presence of MAO. However, only dimerization was observed when EtAlCl2 was used as the cocatalyst.Key words: phthalocyanine, porphyrin, polymerization, copolymerization, ethene, propene, 1-decene.

Influence of metal phthalocyanine molecular orientation on charge separation at organic donor/acceptor interface

2021 ◽  
Author(s):  
Heeseon Lim ◽  
Sena Yang ◽  
Sang-Hoon Lee ◽  
Jung-Yong Lee ◽  
Yeunhee Lee ◽  
...  
Keyword(s):  
Solar Cell ◽  
Charge Separation ◽  
Molecular Orientation ◽  
Organic Solar Cell ◽  
Metal Phthalocyanine ◽  
Dipole Orientation ◽  
Highly Efficient ◽  
Donor Acceptor

To achieve a highly efficient organic solar cell (OPVs), control of molecular orientation is one of prime important factors, for interfacial dipole orientation and energy offset at donor/acceptor (D/A) interface...

scholarly journals Enhancing room-temperature NO2 gas sensing performance based on a metal phthalocyanine/graphene quantum dot hybrid material

RSC Advances ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 5618-5628
Author(s):  
Wenkai Jiang ◽  
Xinwei Chen ◽  
Tao Wang ◽  
Bolong Li ◽  
Min Zeng ◽  
...  
Keyword(s):  
Quantum Dot ◽  
Gas Sensor ◽  
Hybrid Material ◽  
High Performance ◽  
Room Temperature ◽  
Gas Sensing ◽  
Metal Phthalocyanine ◽  
Graphene Quantum Dot ◽  
Sensing Performance

A high performance gas sensor based on a metal phthalocyanine/graphene quantum dot hybrid material was fabricated for NO2 detection at room-temperature.

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