Interfacial reaction mechanism of SiC joints joined by pure nickel foil

2020 ◽  
Vol 40 (15) ◽  
pp. 5162-5171
Author(s):  
Haojiang Shi ◽  
Yidi Chai ◽  
Ning Li ◽  
Jiazhen Yan ◽  
Xin Zhu ◽  
...  
Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7797
Author(s):  
Zhu Ruican ◽  
Guo Shixiong ◽  
Huang Chao ◽  
Lei Zhenglong ◽  
Zhang Xinrui ◽  
...  

The influence of tin foil and Ni coatings on microstructures, mechanical properties, and the interfacial reaction mechanism was investigated during laser welding/brazing of Al/Cu lap joints. In the presence of a Zn-based filler, tin foil as well as Ni coating strengthened the Al/Cu joints. The tin foil only slightly influenced the joint strength. It considerably improved the spreading/wetting ability of the weld filler; however, it weakened the bonding between the seam and the Al base metal. The Ni coating considerably strengthened the Al/Cu lap joints; the highest tensile strength was 171 MPa, which was higher by 15.5% than that of a joint without any interlayer. Microstructure analysis revealed that composite layers of Ni3Zn14–(τ2 Zn–Ni–Al ternary phase)–(α-Zn solid solution)–Al3Ni formed at the fusion zone (FZ)/Cu interface. Based on the inferences about the microstructures at the interfaces, thermodynamic results were calculated to analyze the interfacial reaction mechanism. The diffusion of Cu was limited by the Ni coating and the mutual attraction between the Al and Ni atoms. The microstructure comprised Zn, Ni, and Al, and they replaced the brittle Cu–Zn intermetallic compounds, successfully strengthening the bonding of the FZ/Cu interface.


2013 ◽  
Vol 52 (38) ◽  
pp. 13785-13794 ◽  
Author(s):  
Lenuţa Kloetzer ◽  
Mădălina Poştaru ◽  
Anca-Irina Galaction ◽  
Alexandra Cristina Blaga ◽  
Dan Caşcaval

2016 ◽  
Vol 28 (3) ◽  
pp. 133-140 ◽  
Author(s):  
Bingsheng Xu ◽  
Yan Wu ◽  
Lina Zhang ◽  
Junwei Chen ◽  
Zhangfu Yuan

Purpose This research aims to provide a theoretical method and data supports for a future study on interfacial reaction mechanism and spreading mechanism between molten solder and V-shaped substrate, which also gives guidance for those complicated welding operation objects in brazing technique. Design/methodology/approach Wetting experiments were performed to measure the contact angles at different temperatures of molten Sn-3.0Ag-0.5Cu wetting on the quartz substrate with an included angle of 90°. According to the experimental results, the theoretical spreading morphology of molten solder on V-shaped substrate at corresponding temperature was simulated by Surface Evolver. Findings The theoretical morphology profiles of the molten solder sitting on the V-shaped substrate are simulated using Surface Evolver when the molten solder reaches spreading equilibrium. The spreading mechanisms as well as the impact of surface tension and gravity on interfacial energy of the molten solder wetting on the V-shaped groove substrate are also discussed where theoretical results agree well with experiment results. The contact area between the gas and liquid phases shows a tendency of first increasing and later decreasing. Otherwise, the spreading distance and the height of the molten solder increases as the droplet volume increases as the included angle and the contact angle are given as constants, and both the interfacial energy and the gravitational energy increase as well. This research has a wide influence on predicting the outcomes in commercial impact and also gives guidance for those complicated welding operation objects in brazing technique. Research limitations/implications It is of very important significance in both science and practice to investigate the differences between the flat surface and V-shaped surface. Some necessary parameters including intrinsic contact angle and surface tension need to be directly measured when the droplet spreads on the flat surface. The relevant simulation conclusions on the inherent characteristics can be given based on these intrinsic parameters. Compared with the flat surface, the V-shaped substrate is chosen for further discuss on the effects of gravity on the droplet spreading behavior and the changes of apparent contact angle which can only occurs as the substrate is inclined. Therefore, this research provides theoretical method and data supports for a future study on interfacial reaction mechanism and spreading mechanism between molten solder and substrate. Practical implications The research is developed for verifying the accuracy of the model built in Surface Evolver. Based on this verified model, other researches on the spreading distance along y-axis and the contact area that are especially difficult to be experimentally measured can be directly simulated by Surface Evolver, which can provides a convenient method to discuss the changes of horizontal spreading distance, droplet height and contact area with increasing the included angle of V-shaped substrate or with increasing the droplet volume. Actually, the modeling results are calculated for supplying the theoretical parameters and technical guidance in the welding process. Social implications This research provides theoretical method and data supports for a future study on interfacial reaction mechanism and spreading mechanism between molten solder and substrate, which has a wide influence on prediction the outcomes in commercial impact and also gives guidance for those complicated welding operation objects in brazing technique. Originality/value Surface Evolver, can also be used to discuss the structure and spreading mechanism of droplets on V-shaped substrates, which have not been discussed before.


1878 ◽  
Vol 9 ◽  
pp. 120-123
Author(s):  
C. Michie Smith ◽  
J. Gordon MacGregor

Pure nickel foil, obtained in Paris by Dr Andrews, was cut into spiral about 20 inches long, and it was on this spiral that all the following experiments were made. During the month of November 1875 a large number of experiments were made as to its thermoelectric properties, and these were found to be almost identical with that of the specimen from observations on which the line was laid down on the “thermo-electric diagram.” (Trans. R.S.E., 1872–3.) This line, it will be remembered, is a peculiar one, and is very similar to that of iron, with this difference, that the peculiar changes take place at much lower temperatures in nickel than in iron.


MRS Advances ◽  
2019 ◽  
Vol 4 (57-58) ◽  
pp. 3153-3161
Author(s):  
J. López-Cuevas ◽  
J.C. Rendón-Angeles ◽  
J.L. Rodríguez-Galicia ◽  
C.A. Gutiérrez-Chavarría

ABSTRACTBased on wettability and reaction interfaces previously reported, as well as on thermodynamic considerations, a likely mechanism has been proposed for the chemical interaction taking place at the metal/ceramic interface during wettability experiments carried out by the so-called “sessile drop” method. The experiments involved three Ag-Cu-based brazing alloys [Cusil (Ag-28wt.%Cu), Cusil-ABA (Ag-34.6wt.%Cu-1.58wt.%Ti) and Incusil-ABA (Ag-26.6wt.%Cu-12.4wt.%In-0.89wt.%Ti)] and as polished and pre-oxidized pressure-less sintered silicon carbide (PLS-SiC), with a total holding time of 90 minutes at 850 °C, under a Zr sponge-gettered vacuum of 10-4/10-5 Torr.


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