High-Speed Continuous Production of Polymeric Nanoparticles with Improved Stability Using a Self-Aligned Coaxial Turbulent Jet Mixer

Author(s):  
Hyeonwoo Han ◽  
Jeong Hoon Yoon ◽  
Gi-Ra Yi ◽  
Won Il Choi ◽  
Jong-Min Lim
2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Jiyun Heo ◽  
Jae-Yun Han ◽  
Soohyun Kim ◽  
Seongmin Yuk ◽  
Chanyong Choi ◽  
...  

Abstract The vanadium redox flow battery is considered one of the most promising candidates for use in large-scale energy storage systems. However, its commercialization has been hindered due to the high manufacturing cost of the vanadium electrolyte, which is currently prepared using a costly electrolysis method with limited productivity. In this work, we present a simpler method for chemical production of impurity-free V3.5+ electrolyte by utilizing formic acid as a reducing agent and Pt/C as a catalyst. With the catalytic reduction of V4+ electrolyte, a high quality V3.5+ electrolyte was successfully produced and excellent cell performance was achieved. Based on the result, a prototype catalytic reactor employing Pt/C-decorated carbon felt was designed, and high-speed, continuous production of V3.5+ electrolyte in this manner was demonstrated with the reactor. This invention offers a simple but practical strategy to reduce the production cost of V3.5+ electrolyte while retaining quality that is adequate for high-performance operations.


2019 ◽  
Vol 176 (1) ◽  
pp. 16-26 ◽  
Author(s):  
Ireneusz PIELECHA ◽  
Wojciech BUESCHKE ◽  
Maciej SKOWRON ◽  
Łukasz FIEDKIEWICZ ◽  
Filip SZWAJCA ◽  
...  

Searching for further reduction of fuel consumption simultaneously with the reduction of toxic compounds emission new systems for lean-mixture combustion for SI engines are being discussed by many manufacturers. Within the European GasOn-Project (Gas Only Internal Combustion Engines) the two-stage combustion and Turbulent Jet Ignition concept for CNG-fuelled high speed engine has been proposed and thoroughly investigated where the reduction of gas consumption and increasing of engine efficiency together with the reduction of emission, especially CO2 was expected. In the investigated cases the lean-burn combustion process was conducted with selection of the most effective pre-combustion chamber. The experimental investigations have been performed on single-cylinder AVL5804 research engine, which has been modified to SI and CNG fuelling. For the analysis of the thermodynamic, operational and emission indexes very advanced equipment has been applied. Based on the measuring results achieved for different pre-chamber config-urations the extended methodology of polioptimization by pre-chamber selection and the shape of main chamber in the piston crown for proposed combustion system has been described and discussed. The results of the three versions of the optimization methods have been comparatively summarized in conclusions.


2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Neha Atulkumar Singh ◽  
Abul Kalam Azad Mandal ◽  
Zaved Ahmed Khan

The purpose of this study was to develop an oral delivery system for the controlled release of catechin and evaluate the antioxidant potential and stability of catechin loaded PLA/PEG nanoparticles (CATNP). Nanoparticles were synthesized using a double emulsion solvent evaporation method. The fabricated nanoparticles were relatively small with a hydrodynamic diameter of 300 nm and an encapsulation efficiency of 95%. SEM image analysis showed uniform sized and spherically shaped nanoparticles. In vitro release profiles indicated a slow and sustained release of catechin from the nanoparticle. Stability of the nanoparticle in simulated gastric and intestinal fluids is maintained due to the PEG coating on the nanoparticles, which effectively protected catechin against gastrointestinal enzyme activity. Enhanced inhibition action of free radicals and metal chelation potential was noted when catechin was encapsulated in these polymeric nanoparticles. The reports obtained from this study would provide an opportunity for designing an oral delivery system aimed at inhibiting oxidative stress in the human body.


AIChE Journal ◽  
2019 ◽  
Vol 65 (12) ◽  
Author(s):  
Giovanni Bovone ◽  
Elia A. Guzzi ◽  
Mark W. Tibbitt

1979 ◽  
Vol 33 (3) ◽  
pp. 230-240 ◽  
Author(s):  
R. I. Bystroff ◽  
L. R. Layman ◽  
G. M. Hieftje

Details of the processes occurring during sample atomization from a “microarc” discharge have been studied photometrically, by use of high-speed color cinematography and through current-voltage waveforms. The microarc studied here is an atmospheric-pressure inert-gas glow discharge supported between 0.25 mm diameter tungsten wires; quiescent argon-1% H2 provides reactive-sputtering conditions and improved behavior in the presence of oxygen impurities. Excitation temperatures of ca. 5000°K are measured for the argon glow. Samples of Na, Al, and Sr illustrate the influence of volatile, refractory, insulating, and electron-emitting sample properties on the temporal-spatial-electrical behavior of the discharge. The step-by-step events occurring in the discharge are described qualitatively and a variety of processes are invoked to explain sample volatilization, including sputtering, chemical reactions, and purely thermal effects. In the first stages of the discharge, instabilities are related to the placement and insulating character of deposits. With heating, electron emission becomes important in directing the discharge to or away from the sample; abnormal glow wandering and glow-to-arc transitions can ensue. Improved stability is achieved by uniformly depositing multi-element samples along the electrode, which localizes the initial discharge and promotes ablative cooling of the sample and electrode.


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