Chemical composition effect on VVER-1000 RPV weld metal thermal aging

2015 ◽  
Vol 465 ◽  
pp. 540-549 ◽  
Author(s):  
B.A. Gurovich ◽  
A.A. Chernobaeva ◽  
D.Yu Erak ◽  
E.A. Kuleshova ◽  
D.A. Zhurko ◽  
...  
2008 ◽  
Vol 580-582 ◽  
pp. 57-60
Author(s):  
Hee Joon Sung ◽  
Yeon Baeg Goo ◽  
Kyeong Ju Kim ◽  
Kee Young Choi

Chemical composition effect on the weld properties for low temperature steel was evaluated. The alloy elements of interest at the weld metal were Cr and Mo, which come from the steel plate and welding wire, respectively. Both side one run SAW process was carried out in a Ygroove butt joint. Microstructure of the weld metal is strongly dependent on the chemical composition of the steel plate and the welding wire, due to high dilution. The microstructure of the weld metal became fine acicular ferrite by increasing Cr and Mo content because of high hardenability effect. The weld metal having Cr and Mo possessed the highest impact toughness at low temperatures among the weld metals studied. Cr seems to have more effect than Mo on the toughness of the weld metal.


CORROSION ◽  
10.5006/2902 ◽  
2019 ◽  
Vol 75 (4) ◽  
pp. 377-388 ◽  
Author(s):  
Xiaodong Lin ◽  
Qunjia Peng ◽  
En-Hou Han ◽  
Wei Ke

Double loop electrochemical potentiokinetic reactivation (DL-EPR) was applied to evaluate thermal aging of 308L stainless steel weld metal. It was found that the activation and reactivation peaks of DL-EPR curve were induced by dissolution of austenite and δ-ferrite, respectively. Before saturation of hardness, the linear relationship between reactivation ratio and hardness could be used for assessing the thermal aging-induced hardening. In the following thermal aging process, the reactivation ratio is applicable to assess the occurrence of the saturation of thermal aging-induced hardening. The results demonstrated that the DL-EPR test is applicable to assess the evolution of thermal aging.


2014 ◽  
Vol 627 ◽  
pp. 241-244 ◽  
Author(s):  
Pawel Kucharczyk ◽  
Sebastian Münstermann

The microstructure of welded joints differs significantly from that of the base material, what changes their mechanical properties and influences fatigue life. The aim of this work was the investigation of the local deformation field within a butt joint made of 10 mm thick structural steel S355. However, a direct sampling even of the weld metal was impossible due to small dimensions of butt joints. Therefore, the following procedure was utilized in order to manufacture big samples of the microstructure identical to that of the local weldment areas.A geometrical model of the welded structure describing the relevant areas e.g. weld metal, heat-affected zone was established. It was based on the results of the metallographic investigations, hardness mapping and electron-probe-micro-analysis of the local chemical composition. The welding process was numerically simulated using SYSWELD program to estimate the time-temperature-transition (TTT) curves for each identified area. The parameters of the heat input source were calibrated. Afterwards, the material of the defined chemical composition was heat-treated according to the TTT curves. For the validation purpose the heat-treated work pieces were evaluated in terms of microstructure and hardness distribution. Finally, the up-scaled samples of the respective bulk microstructure were manufactured and investigated in monotonic tests.


2015 ◽  
Vol 756 ◽  
pp. 92-96 ◽  
Author(s):  
Dmitry A. Chinakhov

The influence of the welding current and method of gas shielding in MAG welding on the content of silicon and manganese is considered. Results of study of the welded specimens of steels 45 and 30HGSA when applying welding wire of different formulas and different types of gas shielding (traditional shielding and two-jet shielding) are given. It is established that in MAG welding the value of the welding current and the speed of the gas flow from the welding nozzle have a considerable impact on the chemical composition of the weld metal. The consumable electrode welding under double-jet gas shielding provides the directed gas-dynamics in the welding area and enables controlling the electrode metal transfer and the chemical composition of a weld.


Author(s):  
Timothy J. Griesbach ◽  
Vikram Marthandam ◽  
Haiyang Qian ◽  
Patrick O’Regan

Prolonged exposure of cast austenitic stainless steels (CASS) to reactor coolant operating temperatures has been shown to lead to some degree of thermal aging embrittlement (reduction in fracture toughness of the material as a function of time). The fracture toughness data for the most severely aged CASS materials were found to be similar to those reported for some austenitic stainless steel weld metal, in particular weld metal from submerged arc welds (SAW). Such similarity offers the possibility for applying periodic inservice inspection flaw acceptance criteria, currently referenced in the ASME Code Section XI, Subsection IWB, for SAW and shielded metal arc weld (SMAW), to CASS component inservice inspection results. This paper presents the data to support both the proposed screening criteria (based on J-R crack growth resistance) for evaluation of the potential significance of the effects of thermal aging embrittlement for Class 1 reactor coolant system and primary pressure boundary CASS components, for those situations where the effects of thermal aging embrittlement are found to be potentially significant. The fitness for continued service is based on the comparison of the limiting fracture toughness data for Type 316 SAW welds and the lower-bound fracture toughness data reported for high-molybdenum, high delta-ferrite, statically and centrifugally-cast CASS materials. These comparisons and the associated flaw acceptance criteria can be used to justify exemptions from current ASME Code Section XI inservice inspection requirements through flaw tolerance evaluation (e.g., see ASME Nuclear Code Case N-481).


Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3571 ◽  
Author(s):  
Zhenyu Fei ◽  
Zengxi Pan ◽  
Dominic Cuiuri ◽  
Huijun Li ◽  
Azdiar A. Gazder

The ballistic performance of armour steel welds using austenitic filler materials is poor on account of the disparity in the mechanical properties of the weld and base metals. Consequently, a novel Keyhole Gas Tungsten Arc Welding process with a trapezoidal AISI309 austenitic stainless steel interlayer was developed to tailor chemical composition and microstructure by controlling the solidification sequence. Results show that the dilution rate in the weld metal region can reach up to 43.5% by placing a specially designed interlayer in between the base metal, providing a major scope for microstructure modification. Detailed weld analysis was undertaken by X-ray diffraction, optical and secondary and transmission electron microscopy, energy dispersive spectroscopy and electron back-scattering diffraction. The results from Vickers hardness indents and Charpy impact toughness testing at −40 °C show that the properties of the weld metal region are comparable to that of the base metal. This is ascribed to the weld metal comprising a two phase microstructure of martensite and retained austenite, which contribute to improvements in strength and toughness, respectively. Furthermore, the tailored chemical composition, microstructure and low temperature phase transformation in the weld metal may reduce the tendency toward both solidification cracking and hydrogen assisted cold cracking.


Author(s):  
Seung Chang Yoo ◽  
Kyoung Joon Choi ◽  
Ji Hyun Kim

In order to investigate the long-term thermal aging effects on the type-II boundary region in Alloy 152 weld metal, a representative dissimilar weld mock-up made of Alloy 690–Alloy 152–A533 Gr. B has been fabricated and heat treated under accelerated temperature conditions. To simulate the thermal aging effects, the heat treatment was performed at 450°C for 15, 30 and 60-yr equivalent times (1,375, 2,750 and 5,500 h). The aging time was determined by the diffusion equation based on the activation energy for chromium diffusion. The microstructure characterization was primarily conducted in the type-II boundary region of the weld root, which is a boundary parallel to fusion boundary existing within 100um from the fusion boundary and is known to be less resistant to stress corrosion cracking than other regions in the weld. The investigations were performed by scanning electron microscope, electron backscatter diffraction, and nanoindentation test. In this study, the dilution zone of the chromium content was observed at the weld metal region within a 1.5-mm range from the fusion boundary. Ferrites and high angle grain boundaries are found at the type-II boundary region of weld metal. In the narrow zone between the type-II boundary and fusion boundary, the hardness is relatively higher than that of other regions. These results show that the chromium content in the dilution zone increases with heat treatment, but the stiff chemical gradient still exists in the weld region at the narrow zone between the type-II boundary and fusion boundary.


2012 ◽  
Vol 134 (2) ◽  
Author(s):  
Michael L. Santella

Computational thermodynamics approach was used to predict the ranges of the lower ferrite-austenite transformation temperatures, A1’s, in three 9% Cr steels. The predicted A1 ranges were: 766–856 °C for SA387 Grade 91, 775–863 °C for SA213 Grade T92, and 676–862 °C for the weld metal SFA-5.23 B9 (2004). For Grade 91 and Grade T92 using the highest tempering temperature permitted by ASME Code, 800 °C, would permit certain alloys conforming to the chemical composition specification to be tempered above their A1, thereby risking the formation of untempered martensite. Similar circumstances exist for weld metal conforming to the SFA-5.23 B9 specification. Linear regression analyses were performed to develop simplified expressions capable of representing the thermodynamically predicted relationships between chemical compositions and A1’s. These are, Grade 91/SFA-5.23 B9 (2004): 805 °C + 2.5(%Cr) + 18.1(%Mo) + 19.1(%Si)+ 37.1(%V) + 19.2(%Nb) − 63.7(%C) − 130.6(%N) − 60.5(%Mn) − 72.3(%Ni) Grade T92:778°C + 4.9(%Cr) + 22.6(%Mo) + 10.8(%W) + 22.9(%Si) + 43.6(%V) + 20.2(%Nb) − 80.6(%C) − 150.7(%N) − 55.1(%Mn) − 68.0(%Ni).


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