Conversion of CO2 to formic acid by integrated all-solar-driven artificial photosynthetic system

2021 ◽  
Vol 512 ◽  
pp. 230532
Author(s):  
Jiwu Zhao ◽  
Lan Xue ◽  
Zhenjie Niu ◽  
Liang Huang ◽  
Yidong Hou ◽  
...  
2020 ◽  
Vol 8 (35) ◽  
pp. 18310-18317 ◽  
Author(s):  
Yanjun Xiao ◽  
Yao Qian ◽  
Anqi Chen ◽  
Tian Qin ◽  
Fan Zhang ◽  
...  

Artificial photosynthetic systems store solar energy in chemical fuels via CO2 reduction or renewable hydrogen evolution from water splitting.


RSC Advances ◽  
2016 ◽  
Vol 6 (62) ◽  
pp. 57293-57305 ◽  
Author(s):  
Jian-Yong Liu ◽  
Xue-Ni Hou ◽  
Ye Tian ◽  
Lizhi Jiang ◽  
Shuiquan Deng ◽  
...  

The bis(triphenylamine)–BODIPY–C60 artificial photosynthetic system has been prepared and studied for its photoinduced transfer processes in polar and nonpolar solvents using various steady-state and time-resolved spectroscopic techniques.


2015 ◽  
Vol 51 (65) ◽  
pp. 13008-13011 ◽  
Author(s):  
Xiaomin Liu ◽  
Hung-Cheng Chen ◽  
Xianggui Kong ◽  
Youlin Zhang ◽  
Langping Tu ◽  
...  

A NIR light driven nano-photosensitizer is reported as a novel concept in an artificial photosynthetic system that integrates upconversion nanoparticles with Pt(ii)-porphyrin.


2018 ◽  
Vol 9 (17) ◽  
pp. 4152-4159 ◽  
Author(s):  
Jean-François Lefebvre ◽  
Julian Schindler ◽  
Philipp Traber ◽  
Ying Zhang ◽  
Stephan Kupfer ◽  
...  

The π-extended ligand of a ruthenium complex stores two photo-generated electrons, mimicking a key step in photosynthesis.


2015 ◽  
Vol 44 (11) ◽  
pp. 3431-3473 ◽  
Author(s):  
Federico Bella ◽  
Claudio Gerbaldi ◽  
Claudia Barolo ◽  
Michael Grätzel

This review highlights the efforts towards the realization of an artificial photosynthetic system able to convert sunlight into electricity by using a unique solvent, water, the solvent of life.


2016 ◽  
Vol 9 (1) ◽  
pp. 193-199 ◽  
Author(s):  
Meenesh R. Singh ◽  
Alexis T. Bell

The design for a novel artificial photosynthetic system is proposed that can be ten-fold more efficient than natural photosynthesis and produce almost pure liquid fuel.


2015 ◽  
Vol 5 (3) ◽  
pp. 20150011 ◽  
Author(s):  
Alex Bruce ◽  
Thomas Faunce

This article discusses challenges that artificial photosynthetic (AP) systems will face when entering and competing in a global market characterized by established fossil fuel technology. It provides a perspective on the neoliberal principles underpinning much policy entrenching such environmentally destructive technology and outlines how competition law could aid overcoming these hurdles for AP development. In particular, it critiques the potential for competition law to promote a global AP initiative with greater emphasis on atmospheric carbon dioxide and nitrogen fixation (as well as solar-driven water splitting) to produce an equitable, globally distributed source of human food, fertilizer and biosphere sustainability, as well as hydrogen-based fuel. Some relevant strategies of competition law evaluated in this context include greater citizen–consumer involvement in shaping market values, legal requirements to factor services from the natural environment (i.e. provision of clean air, water, soil pollution degradation) into corporate costs, reform of corporate taxation and requirements to balance maximization of shareholder profit with contribution to a nominated public good, a global financial transactions tax, as well as prohibiting horizontal cartels, vertical agreements and unilateral misuse of market power.


2015 ◽  
Vol 87 (6) ◽  
pp. 583-599 ◽  
Author(s):  
Giuseppina La Ganga ◽  
Fausto Puntoriero

Abstract By the use of a molecular approach we performed photo-induced water oxidation by combining different photosensitizers and catalysts in order to obtain an efficient system that pave the way to the construction of an artificial photosynthetic system. Different types of molecular catalysts, such as ruthenium and vanadium polyoxometalates or cobalt core stabilized by different organic ligands were combined with ruthenium (II) polypyridine complexes of different nuclearity, mononuclear species like [Ru(bpy)3]2+ or a tetranuclear dendrimer.


Science ◽  
2020 ◽  
Vol 368 (6491) ◽  
pp. 649-654 ◽  
Author(s):  
Tarryn E. Miller ◽  
Thomas Beneyton ◽  
Thomas Schwander ◽  
Christoph Diehl ◽  
Mathias Girault ◽  
...  

Nature integrates complex biosynthetic and energy-converting tasks within compartments such as chloroplasts and mitochondria. Chloroplasts convert light into chemical energy, driving carbon dioxide fixation. We used microfluidics to develop a chloroplast mimic by encapsulating and operating photosynthetic membranes in cell-sized droplets. These droplets can be energized by light to power enzymes or enzyme cascades and analyzed for their catalytic properties in multiplex and real time. We demonstrate how these microdroplets can be programmed and controlled by adjusting internal compositions and by using light as an external trigger. We showcase the capability of our platform by integrating the crotonyl–coenzyme A (CoA)/ethylmalonyl-CoA/hydroxybutyryl-CoA (CETCH) cycle, a synthetic network for carbon dioxide conversion, to create an artificial photosynthetic system that interfaces the natural and the synthetic biological worlds.


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