Effects of lacustrine depositional sequences on organic matter enrichment in the Chang 7 Shale, Ordos Basin, China

2021 ◽  
Vol 124 ◽  
pp. 104778
Author(s):  
Tianshu Zhang ◽  
Suyun Hu ◽  
Qingyun Bu ◽  
Bin Bai ◽  
Shizhen Tao ◽  
...  
2017 ◽  
Vol 5 (2) ◽  
pp. SF109-SF126 ◽  
Author(s):  
Yuxi Yu ◽  
Xiaorong Luo ◽  
Ming Cheng ◽  
Yuhong Lei ◽  
Xiangzeng Wang ◽  
...  

Shale oil and gas have been discovered in the lacustrine Zhangjiatan Shale in the southern Ordos Basin, China. To study the distribution of extractable organic matter (EOM) in the Zhangjiatan Shale ([Formula: see text] ranges from 1.25% to 1.28%), geochemical characterization of core samples of different lithologies, scanning electron microscope observations, low-pressure [Formula: see text] and [Formula: see text] adsorption, and helium pycnometry were conducted. The content and saturation of the EOM in the pores were quantitatively characterized. The results show that the distribution of the EOM in the shale interval is heterogeneous. In general, the shale layers have a higher EOM content and saturation than siltstone layers. The total organic content and the original storage capacity control the EOM content in the shale layers. For the siltstone layers, the EOM content is mainly determined by the original storage capacity. On average, 75% of the EOM occurs in the mesopores, followed by 14% in the macropores, and 11% in the micropores. The EOM saturation in the pores decreases with the increase in pore diameter. The distribution of EOM in the shale pores is closely related to the pore type. Micropores and mesopores developed in the kerogens and pyrobitumens and the clay-mineral pores coated with organic matter are most favorable for EOM retention and charging.


2017 ◽  
Vol 5 (2) ◽  
pp. SF225-SF242 ◽  
Author(s):  
Xun Sun ◽  
Quansheng Liang ◽  
Chengfu Jiang ◽  
Daniel Enriquez ◽  
Tongwei Zhang ◽  
...  

Source-rock samples from the Upper Triassic Yanchang Formation in the Ordos Basin of China were geochemically characterized to determine variations in depositional environments, organic-matter (OM) source, and thermal maturity. Total organic carbon (TOC) content varies from 4 wt% to 10 wt% in the Chang 7, Chang 8, and Chang 9 members — the three OM-rich shale intervals. The Chang 7 has the highest TOC and hydrogen index values, and it is considered the best source rock in the formation. Geochemical evidence indicates that the main sources of OM in the Yanchang Formation are freshwater lacustrine phytoplanktons, aquatic macrophytes, aquatic organisms, and land plants deposited under a weakly reducing to suboxic depositional environment. The elevated [Formula: see text] sterane concentration and depleted [Formula: see text] values of OM in the middle of the Chang 7 may indicate the presence of freshwater cyanobacteria blooms that corresponds to a period of maximum lake expansion. The OM deposited in deeper parts of the lake is dominated by oil-prone type I or type II kerogen or a mixture of both. The OM deposited in shallower settings is characterized by increased terrestrial input with a mixture of types II and III kerogen. These source rocks are in the oil window, with maturity increasing with burial depth. The measured solid-bitumen reflectance and calculated vitrinite reflectance from the temperature at maximum release of hydrocarbons occurs during Rock-Eval pyrolysis ([Formula: see text]) and the methylphenanthrene index (MPI-1) chemical maturity parameters range from 0.8 to [Formula: see text]. Because the thermal labilities of OM are associated with the kerogen type, the required thermal stress for oil generation from types I and II mixed kerogen has a higher and narrower range of temperature for hydrocarbon generation than that of OM dominated by type II kerogen or types II and III mixed kerogen deposited in the prodelta and delta front.


2017 ◽  
Vol 5 (2) ◽  
pp. SF63-SF79 ◽  
Author(s):  
Robert G. Loucks ◽  
Stephen C. Ruppel ◽  
Xiangzeng Wang ◽  
Lucy Ko ◽  
Sheng Peng ◽  
...  

Continental Upper Triassic Yanchang “black shales” in the southeastern Ordos Basin have been proven to be unconventional gas reservoirs. Organic-matter-lean and organic-matter-rich argillaceous mudstones form reservoirs that were deposited in a deeper water lacustrine setting during lake highstands. In the stratified lake, the bottom waters were dysaerobic to anoxic. This low-energy and low-oxygen lake-bottom setting allowed types II and III organic matter to accumulate. Interbedded with the argillaceous mudstones are argillaceous arkosic siltstones deposited by gravity-flow processes. Rock samples from the Yanchang Chang 7–9 members are very immature mineralogically. Mineral grains are predominantly composed of relatively equal portions of quartz and feldspar. The high clay-mineral content, generally greater than 40%, has promoted extensive compaction of the sediments, permitting the ductile material to deform and occlude interparticle pores. Furthermore, this high clay-mineral content does not favor hydraulic fracturing of the mudstone reservoir. The pore network within the mudstones is dominated by intraparticle pores and a lesser abundance of organic-matter pores. Interparticle pores are rare. The mean Gas Research Institute (GRI) crushed-rock porosity is 4.2%. Because the pore network is dominated by poorly connected intraparticle pores, permeability is very low (the GRI-calculated geometric mean permeability = 9.9 nd). The dominance of intraparticle pores creates a very poor correlation between GRI porosity and GRI permeability. Several methods of porosity analysis (GRI crushed rock, nitrogen adsorption, and point count) were conducted on each samples, and the results were compared. There is no significant correlation between the three methods, implying that each method measures different pore sizes or types. There is also no relationship between the porosity and permeability and total organic carbon. Much of the mature (peak oil window) organic matter is nonporous, suggesting that it is of type III. Most of the organic-matter pores are in migrated solid bitumen. Overall, the samples analyzed have low porosity and permeability for mudrocks.


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