Films of a-Si:C have been prepared by vacuum deposition while the substrate was simultaneously bombarded with 1000-V electrons. Some film properties (electrical, optical) are compared for films deposited both with and without electron beam irradiation. It is concluded that the effect of the electron beam irradiation is to produce a film with a structure closer to that of an ideal random network. Some of the films are photoconducting and have undoped electrical characteristics similar to those of a-Si:H.