Hydrometallurgical preparation of lithium aluminum carbonate hydroxide hydrate, Li2Al4(CO3)(OH)12·3H2O from aluminate solution

2020 ◽  
Vol 155 ◽  
pp. 106470 ◽  
Author(s):  
Andrey Kropachev ◽  
Igor Kalabskiy
Keyword(s):  
Lithium Aluminum ◽  
Aluminate Solution ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate

Analysis of Mixtures of Gamma Lithium Aluminate, Lithium Aluminum Carbonate Hydroxide Hydrate, and Lithium Carbonate

1997 ◽  
Vol 496 ◽  
Author(s):  
M. T. Nemeth ◽  
R. B. Ford ◽  
T. A. Taylor
Keyword(s):  
Ceramic Powder ◽  
Lithium Carbonate ◽  
Lithium Aluminum ◽  
Carbonate Content ◽  
Lithium Aluminate ◽  
Molten Carbonate ◽  
X Ray Diffraction ◽  
Carbonate Hydroxide ◽  
Molten Carbonate Fuel Cells ◽  
Hydroxide Hydrate

ABSTRACTLithium aluminate, LiA1O2is a ceramic powder which is used as the porous solid support for the electrolyte in molten carbonate fuel cells (MCFCs). It has previously been reported that gamma LiAlO2will convert to lithium aluminum carbonate hydroxide hydrate, Li2Al4(CO3)(OH)123H2O and Li2CO3when exposed to water vapor and carbon dioxide. We compare three techniques, weight gain, carbonate content and x-ray diffraction to measure the amount of conversion. The reaction may involve amorphous intermediates and no one technique by itself is satisfactory to study the conversion.

Conversion of gamma lithium aluminate to lithium aluminum carbonate hydroxide hydrate

1996 ◽  
Vol 11 (4) ◽  
pp. 312-317 ◽  
Author(s):  
Susan Jacob Beckerman ◽  
Robert B. Ford ◽  
Mark T. Nemeth
Keyword(s):  
Ceramic Powder ◽  
Lithium Aluminum ◽  
Lithium Aluminate ◽  
Molten Carbonate ◽  
X Ray Diffraction ◽  
Decomposition Products ◽  
High Temperature Xrd ◽  
Carbonate Hydroxide ◽  
Molten Carbonate Fuel Cells ◽  
Hydroxide Hydrate

Gamma-phase lithium aluminate (LiAlO2) is a ceramic powder used in molten carbonate fuel cells (MCFCs) and in other nuclear and ceramic applications. Upon exposure to water vapor and carbon dioxide at 25 °C, we have observed that gamma-LiAlO2 converts to lithium aluminum carbonate hydroxide hydrate, Li2Al4(CO3)(OH)12·3H2O(LACHH) and Li2CO3. The conversion was observed by X-ray diffraction (XRD) and carbonate analysis. An equation for the conversion is given, and the morphology is determined by scanning electron microscopy. A high-temperature XRD study and thermogravimetric/differential thermal analysis (TGA/DTA) showed that LACHH decomposes at 250 °C. The decomposition products of LACHH and Li2CO3 react to form first alpha-LiAlO2 and then gamma-LiAlO2 at temperatures of 650 and 1000 °C, respectively.

scholarly journals Facile Synthesis of Carbon Cloth Supported Cobalt Carbonate Hydroxide Hydrate Nanoarrays for Highly Efficient Oxygen Evolution Reaction

2021 ◽  
Vol 9 ◽  
Author(s):  
Yubing Yan
Keyword(s):  
Electron Microscopy ◽  
Oxygen Evolution ◽  
Current Density ◽  
Oxygen Evolution Reaction ◽  
Active Sites ◽  
Carbon Cloth ◽  
High Porosity ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate

Developing efficient and low-cost replacements for noble metals as electrocatalysts for the oxygen evolution reaction (OER) remain a great challenge. Herein, we report a needle-like cobalt carbonate hydroxide hydrate (Co(CO3)0.5OH·0.11H2O) nanoarrays, which in situ grown on the surface of carbon cloth through a facile one-step hydrothermal method. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations demonstrate that the Co(CO3)0.5OH nanoarrays with high porosity is composed of numerous one-dimensional (1D) nanoneedles. Owing to unique needle-like array structure and abundant exposed active sites, the Co(CO3)0.5OH@CC only requires 317 mV of overpotential to reach a current density of 10 mA cm−2, which is much lower than those of Co(OH)2@CC (378 mV), CoCO3@CC (465 mV) and RuO2@CC (380 mV). For the stability, there is no significant attenuation of current density after continuous operation 27 h. This work paves a facile way to the design and construction of electrocatalysts for the OER.

Cobalt iron carbonate hydroxide hydrate on 3D porous carbon as active and stable bifunctional oxygen electrode for Zn–air battery

2018 ◽  
Vol 402 ◽  
pp. 388-393 ◽  
Author(s):  
Yan Qi Jin ◽  
Zhipeng Lin ◽  
Rui Zhong ◽  
Jilin Huang ◽  
Guofeng Liang ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Oxygen Electrode ◽  
Iron Carbonate ◽  
Carbonate Hydroxide ◽  
Cobalt Iron ◽  
Air Battery ◽  
Hydroxide Hydrate

scholarly journals Simple Synthesis of Cobalt Carbonate Hydroxide Hydrate and Reduced Graphene Oxide Hybrid Structure for High-Performance Room Temperature NH3 Sensor

Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 615 ◽  
Author(s):  
Chang Wang ◽  
Huan Wang ◽  
Dan Zhao ◽  
Xianqi Wei ◽  
Xin Li ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Gas Sensor ◽  
Room Temperature ◽  
Gas Sensing ◽  
Hybrid Structure ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Reduced Graphene ◽  
Hydroxide Hydrate

A novel hybrid structure sensor based on cobalt carbonate hydroxide hydrate (CCHH) and reduced graphene oxide (RGO) was designed for room temperature NH3 detection. This hybrid structure consisted of CCHH and RGO (synthesized by a one-step hydrothermal method), in which RGO uniformly dispersed in CCHH, being used as the gas sensing film. The resistivity of the hybrid structure was highly sensitive to the changes on NH3 concentration. CCHH in the hybrid structure was the sensing material and RGO was the conductive channel material. The hybrid structure could improve signal-to-noise ratio (SNR) and the sensitivity by obtaining the optimal mass proportion of RGO, since the proportion of RGO was directly related to sensitivity. The gas sensor with 0.4 wt% RGO showed the highest gas sensing response reach to 9% to 1 ppm NH3. Compared to a conventional gas sensor, the proposed sensor not only showed high gas sensing response at room temperature but also was easy to achieve large-scale production due to the good stability and simple synthesis process.

Boosted Oxygen Evolution Reactivity via Atomic Iron Doping in Cobalt Carbonate Hydroxide Hydrate

2020 ◽  
Vol 12 (36) ◽  
pp. 40220-40228
Author(s):  
Shan Zhang ◽  
Bolong Huang ◽  
Liguang Wang ◽  
Xiaoyan Zhang ◽  
Haishuang Zhu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Iron Doping ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate

Cubic Nanostructures of Nickel–Cobalt Carbonate Hydroxide Hydrate as a High-Performance Oxygen Evolution Reaction Electrocatalyst in Alkaline and Near-Neutral Media

2020 ◽  
Vol 59 (22) ◽  
pp. 16690-16702 ◽  
Author(s):  
Kannimuthu Karthick ◽  
Sugumar Subhashini ◽  
Rishabh Kumar ◽  
Sridhar Sethuram Markandaraj ◽  
Muthukumar Muthu Teepikha ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Cobalt Carbonate ◽  
Nickel Cobalt ◽  
Carbonate Hydroxide ◽  
Neutral Media ◽  
Hydroxide Hydrate

Controllable fabrication of urchin-like Co3O4 hollow spheres for high-performance supercapacitors and lithium-ion batteries

2016 ◽  
Vol 45 (38) ◽  
pp. 15155-15161 ◽  
Author(s):  
Fashen Chen ◽  
Xiaohe Liu ◽  
Zhian Zhang ◽  
Ning Zhang ◽  
Anqiang Pan ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Hydrothermal Synthesis ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Hollow Spheres ◽  
Lithium Ion ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Controllable Fabrication ◽  
Hydroxide Hydrate

Urchin-like cobalt oxide (Co3O4) hollow spheres can be successfully prepared by thermal decomposition of cobalt carbonate hydroxide hydrate (Co(CO3)0.5(OH)·0.11H2O) obtained by template-assisted hydrothermal synthesis.

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