A magnetic separable 3D hierarchical BiOI/rGO/Fe3O4 catalyst for degradation of Rhodamine B under visible light: Kinetic studies and mechanism of degradation

2022 ◽  
Vol 276 ◽  
pp. 115576
Author(s):  
N. Premalatha ◽  
Lima Rose Miranda
2020 ◽  
Vol 9 (3) ◽  
pp. 1-8
Author(s):  
Hung Nguyen Van ◽  
Nguyet Bui Thi Minh ◽  
Linh Bui Thi Thuy ◽  
Nghi Nguyen Huu ◽  
Tuoi Nguyen Thanh ◽  
...  

In the present study, the synthesis of ZnO/LSAC through pyrolysis of the carbonized material prepared from longan seed, zinc acetate in alkaline medium. The obtained materials was characterized by means of XRD, SEM, TEM, BET and UV-Vis-DRS. The XRD patterns of ZnO/LSAC nanocomposites were assigned to wurtzite structure of ZnO with crystallite size about 15 to 30 nm. SEM and TEM observations showed the spherical ZnO particles formed on the activated carbon. The band gap energy and specific surface area of ZnO/LSAC were found to be 2.79 eV and 294.4 m2/g, respectively. The photocatalytic activities of the prepared materials were evaluated for the degradation of Rhodamine B (RhB) dye. The removal of RhB was found to be pH dependent, and the optimized removal efficiency reached to 93.75% and the mineralization level was over 84,09% at initial RhB concentration of 40 mg.L-1 andpH 7 following 120 min under visible-light illumination. The kinetic studies showed the decolorizationof RhB followed pseudo first-order kinetics with the rate constant were determined kapp= 1.67Í10-2 min−1


Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2206
Author(s):  
Gaoqian Yuan ◽  
Gen Zhang ◽  
Kezhuo Li ◽  
Faliang Li ◽  
Yunbo Cao ◽  
...  

Loading a noble metal on Bi4Ti3O12 could enable the formation of the Schottky barrier at the interface between the former and the latter, which causes electrons to be trapped and inhibits the recombination of photoelectrons and photoholes. In this paper, AgPt/Bi4Ti3O12 composite photocatalysts were prepared using the photoreduction method, and the effects of the type and content of noble metal on the photocatalytic performance of the catalysts were investigated. The photocatalytic degradation of rhodamine B (RhB) showed that the loading of AgPt bimetallic nanoparticles significantly improved the catalytic performance of Bi4Ti3O12. When 0.10 wt% noble metal was loaded, the degradation rate for RhB of Ag0.7Pt0.3/Bi4Ti3O12 was 0.027 min−1, which was respectively about 2, 1.7 and 3.7 times as that of Ag/Bi4Ti3O12, Pt/Bi3Ti4O12 and Bi4Ti3O12. The reasons may be attributed as follows: (i) the utilization of visible light was enhanced due to the surface plasmon resonance effect of Ag and Pt in the visible region; (ii) Ag nanoparticles mainly acted as electron acceptors to restrain the recombination of photogenerated electron-hole pairs under visible light irradiation; and (iii) Pt nanoparticles acted as electron cocatalysts to further suppress the recombination of photogenerated electron-hole pairs. The photocatalytic performance of Ag0.7Pt0.3/Bi4Ti3O12 was superior to that of Ag/Bi4Ti3O12 and Pt/Bi3Ti4O12 owing to the synergistic effect between Ag and Pt nanoparticles.


2021 ◽  
Vol 4 (2) ◽  
pp. 1149-1161 ◽  
Author(s):  
Ana Rovisco ◽  
Rita Branquinho ◽  
Jonas Deuermeier ◽  
Tomás Freire ◽  
Elvira Fortunato ◽  
...  

Author(s):  
Asim Ali Yaqoob ◽  
Nur Habibah binti Mohd Noor ◽  
Khalid Umar ◽  
Rohana Adnan ◽  
Mohamad Nasir Mohamad Ibrahim ◽  
...  

2008 ◽  
Vol 83 (1-2) ◽  
pp. 8-14 ◽  
Author(s):  
J. Madhavan ◽  
P. Maruthamuthu ◽  
S. Murugesan ◽  
S. Anandan

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