Nonressonant nonlinear optical switching behavior of Ag monometallic and Ag@Au bimetallic investigated by femtosecond Z-Scan measurements

2021 ◽  
Vol 142 ◽  
pp. 107247
Author(s):  
Sara D.G. Mariano ◽  
Naythalla A.M. Saraiva ◽  
Jean C.S. Costa ◽  
Claudevan A. Sousa ◽  
Nefe J.B. Silva ◽  
...  
Keyword(s):  
Optical Switching ◽  
Nonlinear Optical ◽  
Switching Behavior

scholarly journals Above Room Temperature Reversible Phase Transition Induces Distinct Dielectric and Nonlinear Optical Switching Response Behavior in Crown-Ether-Based Supramolecular Clathrate

Crystals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 184 ◽  
Author(s):  
Jing Jing ◽  
Fan Jiang ◽  
Yan-Li Wei ◽  
Chao Shi ◽  
Heng-Yun Ye ◽  
...  
Keyword(s):  
Phase Transition ◽  
Crown Ether ◽  
Optical Switching ◽  
Nonlinear Optical ◽  
Thermal Hysteresis ◽  
Switching Behavior ◽  
Stimuli Responsive ◽  
Scanning Calorimetry ◽  
Reversible Phase Transition ◽  
Reversible Phase

Stimuli-responsive materials with coexisting nonlinear optical (NLO) and dielectric properties are technologically important, which enable simultaneous conversion of optoelectronic properties between different states under external stimuli. By rationally screening guest cations (C6H5NF2)+ in the crown-ether inclusion system, we synthesized a crown-ether supramolecular compound [(C6H5NF2)(18-crown-6)][PF6] (1). Differential scanning calorimetry (DSC) showed that 1 undergoes a reversible phase transition above room temperatures (305 K/292 K), with a thermal hysteresis of 13 K. Temperature-dependent dielectric and NLO measurements show that the compound exhibits two distinct switching response behaviors. Structural analysis indicates that the order–disorder change of the host molecule 18-crown-6 and the guest organic cation during the phase transition induces the dielectric and NLO switching behavior of the compound.

scholarly journals Second-order nonlinear optical switching with a record-high contrast for a photochromic and thermochromic bistable crystal

2017 ◽  
Vol 8 (11) ◽  
pp. 7751-7757 ◽  
Author(s):  
Xiu-Shuang Xing ◽  
Rong-Jian Sa ◽  
Pei-Xin Li ◽  
Ning-Ning Zhang ◽  
Zhong-Yuan Zhou ◽  
...  
Keyword(s):  
Optical Switching ◽  
Nonlinear Optical ◽  
Second Order ◽  
Switching Behavior ◽  
High Contrast ◽  
Crystalline Compound

The first bistable NLO crystalline compound with both photo- and heat-induced SHG-switching behavior shows a record-high photoinduced SHG-switching contrast.

Nonlinear optical switching behavior of nitrogen-doped carbon dots

2019 ◽  
Vol 95 ◽  
pp. 109216 ◽  
Author(s):  
Xiao Wang ◽  
Liang Bai ◽  
Lei Shen ◽  
Bowen Yao ◽  
Hui Huang ◽  
...  
Keyword(s):  
Carbon Dots ◽  
Optical Switching ◽  
Nonlinear Optical ◽  
Switching Behavior ◽  
Nitrogen Doped ◽  
Doped Carbon Dots ◽  
Nitrogen Doped Carbon

Nonlinear optical switching behavior of Au nanocubes and nano-octahedra investigated by femtosecond Z-scan measurements

2009 ◽  
Vol 95 (2) ◽  
pp. 023105 ◽  
Author(s):  
Yih Hong Lee ◽  
Yongli Yan ◽  
Lakshminarayana Polavarapu ◽  
Qing-Hua Xu
Keyword(s):  
Optical Switching ◽  
Nonlinear Optical ◽  
Switching Behavior

Nonlinear Optical Switching Behavior in the Solid State: A Theoretical Investigation on Anils

2011 ◽  
Vol 23 (17) ◽  
pp. 3993-4001 ◽  
Author(s):  
Audrey Ségerie ◽  
Frédéric Castet ◽  
Mohamed Benali Kanoun ◽  
Aurélie Plaquet ◽  
Vincent Liégeois ◽  
...  
Keyword(s):  
Solid State ◽  
Theoretical Investigation ◽  
Optical Switching ◽  
Nonlinear Optical ◽  
Switching Behavior

Optical Switching of Coherent VO2 Precipitates Embedded in Sapphire

1995 ◽  
Vol 396 ◽  
Author(s):  
L. A. Gea ◽  
L. A. Boatner ◽  
J. D. Budai ◽  
R. A. Zuhr
Keyword(s):  
Phase Transition ◽  
Vanadium Dioxide ◽  
Thermal Processing ◽  
Optical Switching ◽  
Optical Transmission ◽  
Structural Phase ◽  
Switching Behavior ◽  
New Type ◽  
Single Crystal Sapphire ◽  
Smart Surface

AbstractIn this work, we report the formation of a new type of active or “smart” surface that is produced by ion implantation and thermal processing. By co-implanting vanadium and oxygen into a single-crystal sapphire substrate and annealing the system under appropriate conditions, it was possible to form buried precipitates of vanadium dioxide that were crystallographically oriented with respect to the host AI2O3 lattice. The implanted VO2 precipitate system undergoes a structural phase transition that is accompanied by large variations in the optical transmission which are comparable to those observed for thin films of VO2 deposited on sapphire. Co-implantation with oxygen was found to be necessary to ensure good optical switching behavior.

scholarly journals Nonlinear Optical Switching in Regioregular Porphyrin Covalent Organic Frameworks

2019 ◽  
Vol 131 (21) ◽  
pp. 6970-6974 ◽  
Author(s):  
Bishnu P. Biswal ◽  
Sreeramulu Valligatla ◽  
Mingchao Wang ◽  
Tanmay Banerjee ◽  
Nabil A. Saad ◽  
...  
Keyword(s):  
Optical Switching ◽  
Nonlinear Optical ◽  
Covalent Organic Frameworks

scholarly journals Fused ring effect on optical nonlinearity and structure property relationship of anthracenyl chalcone based push-pull chromophores

PLoS ONE ◽  
2021 ◽  
Vol 16 (9) ◽  
pp. e0257808
Author(s):  
Dian Alwani Zainuri ◽  
Mundzir Abdullah ◽  
Muhamad Fikri Zaini ◽  
Hazri Bakhtiar ◽  
Suhana Arshad ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Electrostatic Potential ◽  
Nonlinear Refractive Index ◽  
Optical Switching ◽  
Nonlinear Optical ◽  
Continuous Wave ◽  
Excited State Absorption ◽  
Nonlinear Optical Properties ◽  
Closed Aperture

The Ultraviolet-visible (UV-Vis) spectra indicate that anthracenyl chalcones (ACs) have high maximum wavelengths and good transparency windows for optical applications and are suitable for optoelectronic applications owing to their HOMO–LUMO energy gaps (2.93 and 2.76 eV). Different donor substituents on the AC affect their dipole moments and nonlinear optical (NLO) responses. The positive, negative, and neutral electrostatic potential regions of the molecules were identified using molecular electrostatic potential (MEP). The stability of the molecule on account of hyperconjugative interactions and accompanying charge delocalization was analyzed using natural bond orbital (NBO) analysis. Open and closed aperture Z-scans were performed using a continuous-wave frequency-doubled diode-pumped solid-state (DPSS) laser to measure the nonlinear absorption and nonlinear refractive index coefficients, respectively. The valley-to-peak profile of AC indicated a negative nonlinear refractive index coefficient. The obtained single crystals possess reverse saturation absorption due to excited-state absorption. The structural and nonlinear optical properties of the molecules have been discussed, along with the role of anthracene substitution for enhancing the nonlinear optical properties. The calculated third-order susceptibility value was 1.10 x10-4 esu at an intensity of 4.1 kW/cm2, higher than the reported values for related chalcone derivatives. The NLO response for both ACs offers excellent potential in optical switching and limiting applications.

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