scholarly journals Effects of Insulating Material Ageing on Ignition Time and Heat Release Rate of the Flame Retardant Cables

2018 ◽  
Vol 211 ◽  
pp. 972-978 ◽  
Author(s):  
Bo-si Zhang ◽  
Jia-qing Zhang ◽  
Qiang Li ◽  
Liu-fang Wang ◽  
Hui Xie ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Ignition Time ◽  
Insulating Material ◽  
Material Ageing

scholarly journals TESTING OF NATURAL INSULATION MATERIALS USING A CONICAL CALORIMETER

2020 ◽  
Vol 1 ◽  
pp. 14-20
Author(s):  
Michael Horváthová ◽  
Linda Makovická Osvaldová
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Fire Safety ◽  
Ignition Time ◽  
Point Of View ◽  
Maximum Heat ◽  
Insulating Material ◽  
Insulation Materials ◽  
Wide Range

This paper examines three types of natural insulation materials, such as fiberboard, hemp and straw, from the point of view of fire safety. Cellulose-based materials allow a wide range of applications when used for insulation and weatherproofing of buildings, in particular floors, roofs, ceilings, attics, sound barriers, etc. The use of these materials is increasing in ecological constructions as well as for weatherproofing wood-based structures. In terms of fire safety requirements, the question is: Which insulating material is the safest in terms of fire propagation? The article focuses on natural products used as external insulation systems which are covered by a facade plaster. Each type of insulation is briefly described in terms of its composition, use, and production process. We describe the process of preparation of samples as well as the testing and measurement procedures. Three tests were carried out for each type of material. For a more objective evaluation, results were averaged. The results of the cone calorimeter were used to obtain data for comparison. The aim is to clarify the behavior of the natural insulating material with regard to the heat release rate, ignition time, burning duration, and maximum heat release rate. These are the essential parameters for comparison. The values were compared to determine the safest material from the point of view of fire safety.

Synthesis of a phosphorus–nitrogen-containing flame retardant and its application in epoxy resin

2018 ◽  
Vol 31 (2) ◽  
pp. 186-196 ◽  
Author(s):  
Shuang Yang ◽  
Yefa Hu ◽  
Qiaoxin Zhang
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Heat Release Rate ◽  
Flame Retardancy ◽  
Release Rate ◽  
Epoxy Resins ◽  
Proton Nuclear Magnetic Resonance ◽  
Scanning Calorimetry ◽  
Cone Calorimeter Test

In this article, a phosphorus–nitrogen-containing flame retardant (DOPO-T) was successfully synthesized by nucleophilic substitution reaction between 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and cyanuric chloride. The chemical structure of DOPO-T was characterized by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance (NMR) and phosphorous-31 NMR, and elemental analysis. DOPO-T was then blended with diglycidyl ether of bisphenol-A to prepare flame-retardant epoxy resins. Thermal properties, flame retardancy, and combustion behavior of the cured epoxy resins were evaluated by differential scanning calorimetry, thermogravimetric analysis, limited oxygen index (LOI) measurement, UL94 vertical burning test, and cone calorimeter test. The results indicated that the glass transition temperature ( Tg) and temperature at 5% weight loss of epoxy resin (EP)/DOPO-T thermosets were gradually decreased with the increasing content of DOPO-T. DOPO-T catalyzed the decomposition of EP matrix in advance. The flame-retardant performance of EP thermosets was significantly enhanced with the addition of DOPO-T. EP/DOPO-T-0.9 sample had an LOI value of 36.2% and achieved UL94 V-1 rating. In addition, the average of heat release rate, peak of heat release rate, average of effective heat of combustion, and total heat release (THR) of EP/DOPO-T-0.9 sample were decreased by 32%, 48%, 23%, and 31%, respectively, compared with the neat EP sample. Impressively, EP/DOPO-T thermosets acquired excellent flame retardancy under low loading of flame retardant.

scholarly journals Flame-Retardant and Thermal Degradation Mechanism of Caged Phosphate Charring Agent with Melamine Pyrophosphate for Polypropylene

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Xuejun Lai ◽  
Jiedong Qiu ◽  
Hongqiang Li ◽  
Xingrong Zeng ◽  
Shuang Tang ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Degradation Mechanism ◽  
Limiting Oxygen Index ◽  
Thermal Degradation Mechanism ◽  
Charring Agent ◽  
Ul 94

An efficient caged phosphate charring agent named PEPA was synthesized and combined with melamine pyrophosphate (MPP) to flame-retard polypropylene (PP). The effects of MPP/PEPA on the flame retardancy and thermal degradation of PP were investigated by limiting oxygen index (LOI), vertical burning test (UL-94), cone calorimetric test (CCT), and thermogravimetric analysis (TGA). It was found that PEPA showed an outstanding synergistic effect with MPP in flame retardant PP. When the content of PEPA was 13.3 wt% and MPP was 6.7 wt%, the LOI value of the flame retardant PP was 33.0% and the UL-94 test was classed as a V-0 rating. Meanwhile, the peak heat release rate (PHRR), average heat release rate (AV-HRR), and average mass loss rate (AV-MLR) of the mixture were significantly reduced. The flame-retardant and thermal degradation mechanism of MPP/PEPA was investigated by TGA, Fourier transform infrared spectroscopy (FTIR), TG-FTIR, and scanning electron microscopy-energy dispersive X-ray spectrometry (SEM-EDXS). It revealed that MPP/PEPA could generate the triazine oligomer and phosphorus-containing compound radicals which changed the thermal degradation behavior of PP. Meanwhile, a compact and thermostable intumescent char was formed and covered on the matrix surface to prevent PP from degrading and burning.

scholarly journals Enhanced Thermal Insulation and Flame-Retardant Properties of Polyvinyl Alcohol-Based Aerogels Composited with Ammonium Polyphosphate and Chitosan

2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
MinYi Luo ◽  
Jiayou Xu ◽  
Shu Lv ◽  
XueFeng Yuan ◽  
Xiaolan Liang
Keyword(s):  
Polyvinyl Alcohol ◽  
Heat Release ◽  
Flame Retardant ◽  
Thermal Insulation ◽  
Heat Release Rate ◽  
Flame Retardancy ◽  
Release Rate ◽  
Ammonium Polyphosphate ◽  
Composite Aerogel ◽  
Composite Aerogels

Polyvinyl alcohol- (PVA-) based aerogels have attracted widespread attention owing to their low cost, eco-friendliness, and low density. However, the applications of PVA-based aerogels are limited by their flammability. In this study, a flame retardant, ammonium polyphosphate (APP), and a biopolymer, chitosan (CS), were added to polyvinyl alcohol (PVA), and the polymer was further crosslinked using boric acid (H3BO3). In the PVA aerogels, the negatively charged APP and positively charged CS formed a polyelectrolyte complex (PEC) through ionic interaction. Cone calorimetry and vertical burning tests (UL-94) indicated that the PVA composite aerogels have excellent flame retardancy; they could decrease the heat release rate, total heat release rate, and carbon dioxide (CO2) generation. Both PVA/H3BO3 and APP-CS in the composite aerogel could be burned to carbon, and the foamed char layer could act together to impart the PVA composite aerogels with good flame retardancy. Further, the decrease in the temperature at the backside of the aerogels with increasing APP-CS content, as determined by the flame-spraying experiment, indicated that the PVA-based aerogels with APP-CS can also serve as thermal insulation materials. This work provides an effective and promising method for the preparation of PVA-based aerogels with good flame retardancy and thermal insulation property for construction materials.

scholarly journals The Fabrication and Properties Characterization of Wood-Based Flame Retardant Composites

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Xia He ◽  
Xianjun Li ◽  
Zhu Zhong ◽  
Yongli Yan ◽  
Qunying Mou ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Untreated Wood ◽  
Smoke Suppression ◽  
Zinc Borate ◽  
Fire Intensity ◽  
Flame Retardation ◽  
Nano Zinc

Wood-based flame retardant composites were fabricated based on vacuum-pressure impregnating method after high intensive microwave pretreatment. The effects of ammonium polyphosphate (APP) and modified nano-zinc borate (nZB) addition on flame-retardation and smoke-suppression properties of wood were investigated by cone calorimeter method (CONE) and thermogravimetric analysis (TGA). The results show that the heat release rate (HRR), peak heat release rate (pk-HRR), and total heat release (THR) of APP-treated woods decreased greatly with increasing concentration of APP. However, mean yield of CO (Mean COY) of APP-treated wood was much higher (3.5 times) than that of untreated wood. Compared with wood treated with APP at a concentration of 15%, the total smoke product (TSP), Mean COY, and pk-HRR decreased by 78.4%, 71.43%, and 31.23%, when wood was treated with APP and nZB (both concentrations were at 15%). APP and nZB have synergistic effects of flame-retardation and smoke-suppression. Nano-zinc borate combined with APP would be used in wood-based composites to efficiently retard flame, reduce fire intensity, and decrease noxious (CO)/smoke release.

Study on Flame-Retardant Properties of Flame Retardant Asphalt Mixture

2013 ◽  
Vol 438-439 ◽  
pp. 387-390 ◽  
Author(s):  
Da Liang Liu ◽  
Yi Zhong Yan ◽  
Yun Yong Huang ◽  
Jia Liang Yao ◽  
Jian Bo Yuan
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Flame Retardants ◽  
Asphalt Mixture ◽  
Modified Asphalt ◽  
Peak Heat Release Rate ◽  
Flame Retardant Properties ◽  
Sbs Modified Asphalt

Flame retardants modified asphalt with SBS flame retardant SMA hybrid material was prepared, flame retardant performances of SMA mixture was studied by the cone calorimeter. The results show that adding 12% flame retardant with SBS modified asphalt in preparation of flame retardant SMA mixture, the peak heat release rate values than the non-flame retardant asphalt mixture decreased by 4.02 kW/m2, and the heat release rate values were significantly reduced, the total heat and the amount of smoke of flame retardant asphalt mixture released less than the non-flame retardant asphalt mixture.

Flame Retardation of Natural Bamboo Fiber/ Polypropylene Fiber Non-Woven Materials

2011 ◽  
Vol 105-107 ◽  
pp. 1723-1726
Author(s):  
Wei Ma ◽  
Wen Bin Yao
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cone Calorimeter ◽  
Polypropylene Fiber ◽  
Bamboo Fiber ◽  
Peak Heat Release Rate ◽  
Natural Bamboo Fiber ◽  
Flame Retardation

According to Natural Bamboo Fiber/ Polypropylene fiber(PP) non-woven materials encountered the problem that its flame retardation is insufficient, this paper tried to add flame retardant to improve its performance, then the cone calorimeter was used to evaluate its flammability. The results show that Peak-Heat Release Rate and Smoke Release Rate etc significantly improved. In accordance with the UL94 ,the flame retardation meet the level V-0 , consistent with the requirements of enterprise.

Thermal Aging Effects on Fire Performance of the Cross-Linked Polyethylene Insulated Cable

2017 ◽  
Vol 898 ◽  
pp. 2399-2404 ◽  
Author(s):  
Jin Mei Li ◽  
Jia Qing Zhang ◽  
Qiang Li ◽  
Zi Dong Guo
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Thermal Aging ◽  
Ignition Time ◽  
Fire Performance ◽  
Aging Effects ◽  
Insulation Materials ◽  
Insulation Failure ◽  
Failure Temperature

To evaluate the fire performance of the cable in service, the ignition time, heat release rate and insulation failure parameters of the accelerated thermal aging cable on stimulated fire condition were studied. The results show that, the extended ignition time and decreasing peak of heat release rate of the cable in the early stage of aging are the addictive including the lubricant, plasticizer and anti-oxygen. In the aggravating of thermal aging, labile materials with low heating value will be exhausted, while the thermal stability of insulation sheath material decreases, its corresponding ignition time will start to shorten and initial peak of heat release rate will start to rise. The insulation failure temperature of the cable is related with the decomposition temperature of insulation materials of the cable by heating. In each aging stage, the decomposition temperatures of insulation materials by heating are all lower than the insulation failure temperature of the cable for about 10°C. The reason for the insulation failure of the cable is that the ambient heat , gives rise to the decomposition by heating of internal insulation materials of the cable through sheath materials finally under the thermal transmission effect.

Study of Flame Retardancy of Carbon Nanopaper Sheets in Glass Fiber-Reinforced Polyester Composites

2007 ◽  
Author(s):  
Z. F. Zhao ◽  
J. Gou
Keyword(s):  
Heat Release ◽  
Glass Fiber ◽  
Heat Release Rate ◽  
Release Rate ◽  
Composite Laminates ◽  
Carbon Nanofiber ◽  
Ignition Time ◽  
Fire Retardant ◽  
Transport Barrier ◽  
Engineering Requirement

In recent years, more severe requirement of budget and safety from industrial fields, especially space exploration and defense field, demand a new class of materials whose characteristics can satisfy both various engineering requirement and strict safety standard. The latter demands materials to have good thermal properties and significantly improved fire retardant property. In this research, multifunctional materials with layered structures are made from polyester resin, glass fiber mats and carbon nanofibers (CNFs). CNFs are added to the resin component of the composite laminates as additives in pulverised form and carbon nanofiber paper sheets (CNFS), respectively. Their flammability behaviors are investigated with cone calorimeter under well-controlled combustion conditions. And their heat release rate and other test parameters are compared and discussed, such as ignition time, heat release rate (HRR), peak heat release rate (PHRR), and so on. Although its PHRR is sharply increased to higher level for CNFS enforced composite laminates, its HRR curve is lowered greatly in most flaming time. Therefore, the pre-incorporated CNFS may act as an excellent insulator and mass transport barrier, improving the flame retardant property.

Research on the Capability and Application of Flame Retardant Cable

2011 ◽  
Vol 217-218 ◽  
pp. 631-635
Author(s):  
Yong Wang
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Loss Rate ◽  
Mass Loss Rate ◽  
Fire Retardant ◽  
Flame Retardant Property ◽  
Time To Ignition ◽  
Carbon Monoxide Yield

This paper, analyzes some parameters with the help of Cone Calorimeter (CONE) for the time to ignition, smoke extinction area, heat release rate, carbon monoxide yield and mass loss rate. The results show that the fire retardant agents affect KVV’s flame retardant property. Such as TTI ( time to ignition ) is prolonged to nearly two times, and the average HRR ( heat release rate ) reduces about 18% compared with the ordinary one and the maximum HRR down about 33%of its counterpart.

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