Impact history of the Chelyabinsk meteorite: Electron microprobe and LA-ICP-MS study of sulfides and metals

2015 ◽  
Vol 118 ◽  
pp. 54-78 ◽  
Author(s):  
A.V. Andronikov ◽  
I.E. Andronikova ◽  
D.H. Hill
Keyword(s):  
Electron Microprobe ◽  
Chelyabinsk Meteorite ◽  
Icp Ms ◽  
History Of

scholarly journals Mineralogy and Geochemistry of Ultramafic Rocks from Rachoni Magnesite Mine, Gerakini (Chalkidiki, Northern Greece)

Minerals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 934
Author(s):  
Evangelos Tzamos ◽  
Micol Bussolesi ◽  
Giovanni Grieco ◽  
Pietro Marescotti ◽  
Laura Crispini ◽  
...  
Keyword(s):  
Raw Materials ◽  
Mining Area ◽  
Ultramafic Rocks ◽  
Northern Greece ◽  
Icp Ms ◽  
Time In Literature ◽  
History Of ◽  
First Time ◽  
The Eu

The importance of magnesite for the EU economy and industry is very high, making the understanding of their genesis for the exploration for new deposits a priority for the raw materials scientific community. In this direction, the study of the magnesite-hosting ultramafic rocks can be proved very useful. For the present study, ultramafic rock samples were collected from the magnesite ore-hosting ophiolite of the Gerakini mining area (Chalkidiki, Greece) to investigate the consecutive alteration events of the rocks which led to the metallogenesis of the significant magnesite ores of the area. All samples were subjected to a series of analytical methods for the determination of their mineralogical and geochemical characteristics: optical microscopy, XRD, SEM, EMPA, ICP–MS/OES and CIPW normalization. The results of these analyses revealed that the ultramafic rocks of the area have not only all been subjected to serpentinization, but these rocks have also undergone carbonation, silification and clay alteration. The latter events are attributed to the circulation of CO2-rich fluids responsible for the formation of the magnesite ores and locally, the further alteration of the serpentinites into listvenites. The current mineralogy of these rocks was found to be linked to one or more alteration event that took place, thus a significant contribution to the metallo- and petrogenetic history of the Gerakini ophiolite has been made. Furthermore, for the first time in literature, Fe inclusions in olivines from Greece were reported.

scholarly journals The emplacement age of the Muntele Mare Variscan granite (Apuseni Mountains, Romania)

2009 ◽  
Vol 60 (6) ◽  
pp. 495-504 ◽  
Author(s):  
Ioan Balintoni ◽  
Constantin Balica ◽  
Monica Cliveţi ◽  
Li-Qiu Li ◽  
Horst Hann ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Variscan Orogeny ◽  
Weighted Mean ◽  
Apuseni Mountains ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
History Of ◽  
The Alps ◽  
Last Stage

The emplacement age of the Muntele Mare Variscan granite (Apuseni Mountains, Romania)Like the Alps and Western Carpathians, the Apuseni Mountains represent a fragment of the Variscan orogen involved in the Alpine crustal shortenings. Thus the more extensive Alpine tectonic unit in the Apuseni Mountains, the Bihor Autochthonous Unit is overlain by several nappe systems. During the Variscan orogeny, the Bihor Unit was a part of the Someş terrane involved as the upper plate in subduction, continental collision and finally in the orogen collapse and exhumation. The Variscan thermotectonic events were marked in the future Bihor Unit by the large Muntele Mare granitoid intrusion, an S-type anatectic body. Zircon U-Pb laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) dating yielded a weighted mean age of 290.9 ± 3.0 Ma and a concordia age of 291.1 ± 1.1 Ma. U-Pb isotope dilution zircon analyses yielded a lower intercept crystallization age of 296.6 + 5.7/-6.2 Ma. These two ages coincide in the error limits. Thus, the Muntele Mare granitoid pluton is a sign of the last stage in the Variscan history of the Apuseni Mountains. Many zircon grains show inheritance and/or Pb loss, typical for anatectic granitoid, overprinted by later thermotectonic events.

scholarly journals DESENVOLVIMENTO DO MÉTODO DE DATAÇÃO QUÍMICA U-Th-Pb DE MONAZITA POR MICROSSONDA ELETRÔNICA NA UFMG

2013 ◽  
Author(s):  
Alexandre de Oliveira Chaves ◽  
Elizabeth Kerpe de Oliveira ◽  
Luiz Rodrigues Armoa Garcia
Keyword(s):  
Electron Microprobe ◽  
Chemical Data ◽  
Common Lead ◽  
Icp Ms ◽  
Dating Method ◽  
Physics Department ◽  
Chemical Dating

O método de datação química U-Th-Pb (não-isotópica) de monazita por microssonda eletrônica vem sendo desenvolvido há pelomenos 20 anos e já tem o reconhecimento da comunidade geológica por apresentar resultados que se equivalem à geocronologia isotópicaU-Pb. Este mineral contém quantidades negligenciáveis de chumbo comum, guardando apenas Pb radiogênico proveniente do Th e U destemineral. O desenvolvimento deste método no Laboratório de Microanálises do Departamento de Física da Universidade Federal de MinasGerais mostra que os dados químicos de U, Th e Pb de cristais de monazita fornecidos por sua microssonda eletrônica produzem idadesnão-isotópicas para eles que se equiparam às idades isotópicas U-Pb produzidas pela técnica LA-ICP-MS. Grãos de monazita de placersmarinhos de Buena (RJ) isotopicamente datados pelo método U-Pb com idades entre 530 e 580 Ma foram quimicamente datadas na UFMGentre 505 e 580 Ma. Estes resultados são consideravelmente compatíveis e colocam o referido laboratório a disposição da comunidadegeocientífica para obtenção de idades de cristais de monazita.Palavras-Chave: MONAZITA, DATAÇÃO QUÍMICA, MICROSSONDA ELETRÔNICA, UFMG ABSTRACTDEVELOPMENT OF THE MONAZITE U-Th-Pb CHEMICAL DATING METHOD BY USING ELECTRON MICROPROBE AT UFMG. Themonazite U-Th-Pb chemical dating method (non-isotopic) by electron microprobe has been developed for about 20 years and has theacceptance of the geological community by presenting results that are equivalent to the isotope U-Pb geochronology. This mineral containsnegligible amounts of common lead, keeping only radiogenic Pb from the Th and U of this mineral. The development of this method in themicroanalysis laboratory of the Physics Department- UFMG shows that the monazite U, Th and Pb chemical data provided by itsmicroprobe produce non-isotopic ages for it that are similar to the U-Pb isotopic ages produced by LA-ICP-MS technique. Monazite grainsfrom marine placers of Buena (RJ) isotopically dated by method U-Pb between 530 and 580 Ma were chemically dated at UFMG between505 and 580 Ma. These results are consistent each other and put the laboratory available to the geoscience community as a tool inobtaining monazite ages.Keywords: MONAZITE, CHEMICAL DATING, ELECTRON MICROPROBE, UFMG

A geochronological framework for sedimentation and Mesoproterozoic tectono-magmatic activity in lower Belt–Purcell rocks exposed west of Kimberley, British Columbia

2015 ◽  
Vol 52 (7) ◽  
pp. 444-465 ◽  
Author(s):  
Christopher R.M. McFarlane
Keyword(s):  
British Columbia ◽  
Minor Component ◽  
Structural Level ◽  
Peraluminous Granite ◽  
Icp Ms ◽  
Ductile Shearing ◽  
History Of ◽  
Metamorphic Zone ◽  
A Minor ◽  
Plate Reconstruction

The Matthew Creek Metamorphic Zone (MCMZ) exposes what is inferred to be the lowest structural level of the lower Aldridge Formation in the Canadian portion of the Belt–Purcell Supergroup. Zircon, monazite, and titanite were dated using the U–Pb system by LA–ICP–MS. The detrital zircon populations of quartzite layers in these rocks define a provenance dominated by sources of Laurentian affinity with a minor component of non-North American ages between 1600 and 1490 Ma. Special attention was paid to monazite in sillimanite-grade metapelitic schists that was analyzed using in situ LA–ICP–MS techniques guided by BSE imaging and compositional mapping. Textural and geochronological evidence indicate that coupled dissolution–reprecipitation affected detrital monazite at 1413 ± 10 Ma. This was followed by prograde monazite growth at 1365 ± 10 Ma, synchronous with crystallization of the nearby Hellroaring Creek peraluminous granite at 1365 ± 5 Ma. Late-stage pegmatite emplacement and ductile shearing along the contact of the MCMZ and overlying rocks occurred at 1335 ± 5 Ma, interpreted as a period of post-collisional extension, core complex formation, exhumation, and decompression melting. The entire package was subsequently affected by a pervasive ∼1050 Ma hydrothermal overprint that partially reset U–Pb dates in monazite, zircon, and titanite contained in all lithologies examined. The lowermost Belt–Purcell stratigraphy in southeast British Columbia preserves a detailed record of sedimentary provenance and a long history of episodic collision and extension that must be reconciled with plate reconstruction models for the break-up of the Nuna supercontinent and assembly of Rodinia.

scholarly journals Magmatic history of the Oldest Toba Tuff inferred from zircon U–Pb geochronology

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Hisatoshi Ito
Keyword(s):  
Caldera Collapse ◽  
Zircon Dating ◽  
Icp Ms ◽  
Zircon Crystallization ◽  
History Of ◽  
Eruption Age ◽  
Magmatic History

Abstract The magmatic history of the Oldest Toba Tuff (OTT), the second largest in volume after the Youngest Toba Tuff (YTT), northern Sumatra, Indonesia, was investigated using U–Pb zircon dating by LA-ICP-MS. Zircon dates obtained from surface and interior sections yielded ages of 0.84 ± 0.03 Ma and 0.97 ± 0.03 Ma, respectively. The youngest OTT zircon ages were in accordance with the 40Ar/39Ar eruption age of ~ 0.8 Ma, whereas the oldest zircon dates were ~ 1.20 Ma. Therefore, the distribution of zircon U–Pb ages is interpreted to reflect protracted zircon crystallization, suggesting that the estimated 800–2,300 km3 of OTT magma accumulated and evolved for at least 400,000 years prior to eruption. This result is comparable to the volume and timescales of YTT magmatism. The similarities of both magmatic duration and geochemistry between OTT and YTT may indicate that they are similar in size and that the caldera collapse that generated OTT might be much larger previously interpreted.

scholarly journals Trace elements geochemistry in high-incidence areas of liver-related diseases, northwestern Ethiopia

2019 ◽  
Vol 42 (5) ◽  
pp. 1235-1254
Author(s):  
Jemal Ahmed
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Selenium Deficiency ◽  
Stream Sediments ◽  
Low Grade ◽  
Geochemical Background ◽  
Water Stream ◽  
Icp Ms ◽  
History Of ◽  
Trace Element Contents

Abstract This paper reports the results of trace elements geochemistry from Tigray national state, northwestern Ethiopia. The area is part of the Arabian-Nubian Shield, where the dominant exposure is low-grade metamorphic rocks and has a long history of liver-related diseases. The increase in the number of liver-related disease patients of the area has been an environmental health issue of national concern. The aim of the study is to determine the level of trace element concentrations and distributions in water and stream sediments of the area and identify the possible sources in relation to human health. Water, stream sediment and rocks samples (20 water, 20 stream sediments, and 6 rock samples) were collected in March 2011 and analyzed for major and trace element contents using ICP-MS, ICP-OES, ion Chromatography, and XRF methods. Bromine, aluminum, fluorine, arsenic, and nitrate values exceed the WHO maximum acceptable concentration (MAC) for drinking purpose. Bromine ranges from 0.11 to 1.48 mg/l show higher values in all samples, and fluorine ranges from 0.21 to 16.49 mg/l show higher values in 20% of the samples. Other trace elements are aluminum—30%, arsenic—10%, and nitrate (NO3)—10%, and they are examples of elements which have above MAC for drinking water. Selenium deficiency may be the other problematic element in the area for which its deficiency is associated with liver damage and heart muscle disorder. The concentration of cobalt and chromium exceeded world geochemical background value in average shale at most sample stations indicated that these stations were in potential risk.

Coupling thermodynamic modeling and high-resolution in situ LA-ICP-MS monazite geochronology: evidence for Barrovian metamorphism late in the Grenvillian history of southeastern Ontario

2014 ◽  
Vol 108 (6) ◽  
pp. 741-758 ◽  
Author(s):  
Travis McCarron ◽  
Fred Gaidies ◽  
Christopher R. M. McFarlane ◽  
R. Michael Easton ◽  
Peter Jones
Keyword(s):  
High Resolution ◽  
Thermodynamic Modeling ◽  
Icp Ms ◽  
History Of

The mineralogy of the historical Mochalin Log REE deposit, South Urals, Russia. Part I. New gatelite-group minerals ferriperbøeite-(La), (CaLa3)(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 and perbøeite-(La), (CaLa3)(Al3Fe2+)[Si2O7][SiO4]3O(OH)2

2020 ◽  
Vol 84 (4) ◽  
pp. 593-607 ◽  
Author(s):  
Anatoly V. Kasatkin ◽  
Natalia V. Zubkova ◽  
Igor V. Pekov ◽  
Nikita V. Chukanov ◽  
Radek Škoda ◽  
...  
Keyword(s):  
Rare Earth ◽  
Single Crystal ◽  
Electron Microprobe ◽  
Earth Element ◽  
South Urals ◽  
Charge Balance ◽  
Unit Cell Parameters ◽  
Cell Parameters ◽  
History Of ◽  
Brownish Black

AbstractThe paper opens a series devoted to the mineral diversity of the Mochalin Log rare earth element (REE) deposit, South Urals, Russia. There is a brief outline of the history of studies and geology of the deposit as well as the description of two new isostructural gatelite-group minerals, ferriperbøeite-(La) (CaLa3)(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 and perbøeite-(La) (CaLa3)(Al3Fe2+)[Si2O7][SiO4]3O(OH)2. Both minerals occur in polymineralic nodules and are associated with one another and allanite-(Ce), allanite-(La), bastnäsite-(Ce), bastnäsite-(La), ferriallanite-(Ce), ferriallanite-(La), ferriperbøeite-(Ce), perbøeite-(Ce), törnebohmite-(Ce) and törnebohmite-(La). The new minerals form isolated anhedral grains up to 0.3 mm [ferriperbøeite-(La)] and 0.5 mm [perbøeite-(La)] across and granular aggregates up to 1.5 mm × 0.5 mm [ferriperbøeite-(La)] and 3 mm × 1 mm [perbøeite-(La)]. Both minerals are brownish-black with vitreous lustre. Dcalc = 4.510 [ferriperbøeite-(La)] and 4.483 [perbøeite-(La)] g cm–3. They are optically biaxial (+); ferriperbøeite-(La): α = 1.788(5), β = 1.790(5), γ = 1.810(5) and 2Vmeas = 40(10)°; perbøeite-(La): α = 1.778(8), β = 1.783(8), γ = 1.805(8) and 2Vmeas = 40(10)°. Chemical data [wt.%, electron-microprobe; Fe3+:Fe2+ ratio from charge-balance requirements, H2O by stoichiometry; ferriperbøeite-(La)/perbøeite-(La)] are: CaO 4.91/4.81, ThO2 0.00/0.32, La2O3 23.75/22.16, Ce2O3 19.69/20.05, Pr2O3 0.85/1.09, Nd2O3 1.48/2.18, MgO 1.47/1.38, Al2O3 10.68/11.25, MnO 1.07/0.92, FeO 3.04/3.35, Fe2O3 5.31/3.78, TiO2 0.19/0.19, SiO2 27.47/27.35, F 0.11/0.23, H2O 1.61/1.54, –O = F –0.05/–0.10, total 101.58/100.50. The empirical formulae based on O20(OH,F)2 are for ferriperbøeite-(La): (Ca0.95La1.58Ce1.30Nd0.10Pr0.06)Σ3.99(Al2.27Fe3+0.72Fe2+0.46Mg0.40Mn0.16Ti0.03)Σ4.04Si4.96O20[(OH)1.94F0.06]; and for perbøeite-(La): (Ca0.94Th0.01La1.49Ce1.34Nd0.14Pr0.07)Σ3.99(Al2.42Fe3+0.52Fe2+0.51Mg0.38Mn0.14 Ti0.03)Σ4.00Si4.99O20[(OH)1.87F0.13]. Both minerals are monoclinic, P21/m; the unit-cell parameters [ferriperbøeite-(La)/perbøeite-(La)] are: a = 8.9458(2)/8.9652(4), b = 5.72971(13)/5.7306(2), c = 17.6192(3)/17.6770(9) Å, β = 115.9497(19)/116.053(6)°, V = 812.06(3)/815.88(6) Å3 and Z = 2/2. The crystal structures are solved on a single crystal and converged to R = 0.0355 [ferriperbøeite-(La)] and 0.0750 [perbøeite-(La)]. Ferriperbøeite-(La) and perbøeite-(La) are named as the La-analogues of ferriperbøeite-(Ce) and perbøeite-(Ce), respectively.

History of individuals of the 18th/19th centuries stored in bones, teeth, and hair analyzed by LA–ICP–MS—a step in attempts to confirm the authenticity of Mozart’s skull

2007 ◽  
Vol 388 (3) ◽  
pp. 593-602 ◽  
Author(s):  
Christina Stadlbauer ◽  
Christian Reiter ◽  
Beatrix Patzak ◽  
Gerhard Stingeder ◽  
Thomas Prohaska
Keyword(s):  
Icp Ms ◽  
History Of

First in-situ Rb-Sr dating of metasedimentary rocks from the Pontiac subprovince, Superior Craton, Canada. Implications towards the regional metamorphic evolution of the sequence.

2020 ◽  
Author(s):  
Nicholas Leventis ◽  
Thomas Zack ◽  
Iain Pitcairn ◽  
Johan Högmalm
Keyword(s):  
Accretionary Prism ◽  
Metasedimentary Rocks ◽  
Metamorphic History ◽  
Accuracy And Precision ◽  
Icp Ms ◽  
Age Variations ◽  
History Of ◽  
Peak Metamorphism ◽  
Superior Craton

<p>The Pontiac subprovince consists of metaturbidites, plutons and thin ultramafic rock layers of Archean age and lies south of the Cadillac-Larder Lake (C-LL) fault zone which is the boundary between the Pontiac and the extensively mineralized Abitibi Greenstone Belt. The sediments show a Barrovian metamorphic gradient which increases southwards, away from the C-LL fault. The most likely tectonic provenance for the Pontiac sedimentary rocks is that they represent a relic accretionary prism with material derived from both the Abitibi and an older terrane. Zircon U-Pb dating shows that deposition occurred not later than 2685±3 Ma ago and recent, robust Lu-Hf dating of garnets bracketed Pontiac's peak metamorphic conditions at 2658±4 Ma. For this study we used a recently developed LA-ICP-MS/MS method for in-situ Rb-Sr dating of biotite and plagioclase in samples ranging in metamorphic grade (biotite to sillimanite zones) from the Pontiac subprovince. Calibration of the instrument was achieved by repeated ablations on several reference materials (see Hogmalm et al. 2017) which also provided the monitoring of accuracy and precision throughout the analyses. Results show a range in dates between 2550 Ma and 2200 Ma with an average of 2440±50 Ma (2σ). Samples from the staurolite and kyanite zones have a larger range with respect to the other zones, but no significant differences are observed in the data with any method of data handing. These dates are ≈300Ma younger than the peak metamorphism in the area and this is attributed to either overgrowth and re-setting of the Rb-Sr system by a second metamorphic/hydrothermal event, or diffusional resetting with core-rim age variations. Possible influence from the adjacent late syntectonic to post-tectonic monzodiorite-monzonite-granodiorite-syenite (MMGS) plutons dated 2671±4 Ma and the garnet-muscovite-granite series (GMG) dated ≈2650 Ma cannot be ruled out. This study provides insights about the metamorphic history of the sequence and supports previous findings regarding resetting of some isotopic systems with relatively low closure temperatures (≈350-400°C) by later thermal events.</p>

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