scholarly journals Efficiency analysis of eggshell and tea waste as Low cost adsorbents for Cr removal from wastewater sample

Author(s):  
Purbita Saha Katha ◽  
Zia Ahmed ◽  
Rafiul Alam ◽  
Badhan Saha ◽  
Arup Acharjee ◽  
...  
Author(s):  
Abimbola O. Aleshinloye ◽  
Kemayou Ngangsso ◽  
Feyisara B. Adaramola ◽  
Adebayo Onigbinde

This study investigated the potential of some agricultural wastes viz; African Star apple seed shell (ASS, plant source), crab shell (CS, animal source) and chicken egg shell (ES, animal source) as eco-friendly and low-cost biological materials for the removal of heavy metals from poultry wastewater. TS, TSS and TDS of the wastewater sample were assayed by filtration methods, chloride content by previously reported method and heavy metal contents (Zn, V, Cd, Fe, Ni, Cu, Co, Pb, Cr and Mn); were analyzed using Microwave Plasma Atomic Emission Spectrometer. The results of the solids and chloride contents of the poultry wastewater were TDS (3100 mg/L), TS (3700 mg/L), TSS (6000 mg/L) and chloride (4.7 g/L); all above the EPA permissible limits. Results of the FTIR analysis showed that ASS is an amide polymer while the CS and ES shells are mixtures of amide and carbonate polymers. Also, results of heavy metal analysis before and after adsorption showed that ASS caused removal of Zn, V, Fe, Cu, Co/ Pb and Mn by 48.27, 32.22, 49.64, 91.44, 100 and 82.39% respectively while Cd, Ni and Cr contents increased by 31, 61 and 48.3% respectively. CS showed removal of Fe, Ni/ Co/ Cr, Pb and Mn by 89.64, 100, 3.51 and 95.96% respectively while Zn, V, Cd and Cu contents increased by 1.7, 61.2, 76.1 and 68.1% respectively. Meanwhile, with ES, the contents of Zn, Fe, Ni, Cu, Cr and Mn increased by 31.56, 86.36, 100, 55.5, 45.80 and 90.33% respectively while the contents of V, Cd, Co and Pb decreased by 78.9, 86.7, 42.5 and 46.2% respectively. This study demonstrated the use of ASS, CS and ES as low- cost and eco-friendly agricultural wastes with significant potential for removal of heavy metals from wastewaters.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Hakan Çelebi ◽  
Gülden Gök ◽  
Oğuzhan Gök

Abstract Recently, the search for low-cost eco-friendly adsorbents has become one of the main objectives of researchers. The aim of this study was to test the removal of four heavy metals, namely lead (Pb), zinc (Zn), nickel (Ni) and cadmium (Cd), from a simulated watery solution using brewed tea waste as a potentially suitable adsorbent. The effects of pH levels (2.0–6.0), adsorbent amount (0.1–5.0 g), contact times (1–150 min.) were examined throughout the adsorption process. The results of the experiments showed that the heavy metals elimination yields had an inverse relationship with pH and a linear relationship between the other parameters. The optimum pH for the removal of the heavy metals was between 4.0 and 5.0 in the case of the brewed tea waste. Equilibrium times of 2, 10, 30 and 5 min were required for the adsorption of Pb, Zn, Ni, Cd onto Camellia sinensis, respectively. Based on the results of this study it can be said that brewed tea waste has a high potential to remove heavy metals from aqueous solutions. The maximum adsorption capacities were calculated as 1.197, 1.457, 1.163 and 2.468 mg/g, for Pb, Zn, Ni and Cd, respectively, by fitting the equilibrium data to the Langmuir isotherm model.


2020 ◽  
Vol 36 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Peng Zhang ◽  
Wenxian Wang ◽  
Zimin Kou ◽  
Bo Wang ◽  
Xiaobin Zhong

2015 ◽  
Vol 13 (1) ◽  
pp. 110-118 ◽  
Author(s):  
Abdelrahman B. Fadhil ◽  
Liqaa I. Saeed
Keyword(s):  
Low Cost ◽  

2019 ◽  
Vol 1349 ◽  
pp. 012061 ◽  
Author(s):  
S Badrealam ◽  
V C Darrell ◽  
Z Dollah ◽  
M F P Mohamed Latiff ◽  
R Handan

Author(s):  
Nornasuha Abdullah ◽  
Nurul Ainirazali ◽  
Muhammad Najmuddin Mukhtar
Keyword(s):  
Low Cost ◽  

2018 ◽  
Vol 9 (1) ◽  
pp. 57-66 ◽  
Author(s):  
Gökçen Akgül ◽  
Tuğba Bolat Maden ◽  
Elena Diaz ◽  
Eduardo Moreno Jiménez

Abstract There is a requirement to provide more efficient, sensitive, low-cost materials for remediation of contaminated water. Biochar as a sorbent is an effective and low-cost material to remove contaminants in water but its adsorption properties can be improved by impregnation of metals on the surface. In this study, a biochar derived from industrial tea waste was modified with Mg, Fe, Mn and Al salts to create different composites, which were tested for PO43− and Cd2+ sorption. The modifications created biochars with the (hydr)oxides of each metal and changed the characterization parameters and surface functionality. Cd2+ was efficiently removed by all the materials even at high Cd2+ loadings in the water (100 mg Cd2+ L−1), the biochar with Mg being the most efficient in Cd2+ removal. The biochar with Mg also achieved the best sorption of PO43−, sorbing up to 30% at 20 mg PO43− L−1. Tea waste biochar can be modified with metal salts to enhance inorganic pollutant removal from waters, especially with Mg salts.


2018 ◽  
Vol 879 ◽  
pp. 131-136 ◽  
Author(s):  
Woravith Chansuvarn ◽  
Yuttapoom Pandee ◽  
Ariya Saechim ◽  
Kritsana Habunmee

This work was focused on evaluating the potential of bamboo powder modified with manganese oxide (MnO-BP) as a low-cost byproduct adsorbent for the adsorption of cadmium(II) ion. A batch method was carried out at room temperature and the optimized conditions. The optimization of adsorption parameters including pH, equilibrium time, dosage and initial Cd(II) concentration was also systematically studied for the removal of cadmium(II) ion. The maximum monolayer adsorption capacity of MnO-BP was estimated as 8.57 mg/g that it more adsorption capacity than untreated-bamboo powder by about 5 times. The Langmuir and the Freundlich isotherms were used to describe the adsorptive mechanism and calculated the maximum monolayer adsorption capacity. It was found that the data from MnO-BP fitted well to the Freundlich isotherm with R2>0.99. It indicated that the adsorptive behavior of MnO-BP to cadmium(II) ion is preferable. In this work, MnO-BP was used for the removal of cadmium(II) ion in wastewater sample. The MnO-BP is a low-cost adsorbent that can be used to remove cadmium(II) effectively.


2020 ◽  
Vol 997 ◽  
pp. 113-120
Author(s):  
Hafizah Binti Naihi

The extensive use of heavy metals such as copper in various industries has discharged a large amount of the metals into the environment which is toxic at higher concentrations. The use of low-cost agricultural waste of biological origin such as tea waste may be an economic solution to this problem. Tea waste is among the potential material to be developed as an adsorbent for heavy metal ions. Tea waste contains cellulose and lignin which have been reported having an excellent metal binding capacity. This study aims to use tea waste for the removal of Cu2+ ions. The effect of variation in different parameters like initial concentration of Cu2+ ions in solution, adsorbent dosage and contact time were investigated using batch adsorption method. The adsorbent, tea waste was characterized using a compound microscope and FTIR spectroscopy. Experimental results showed that the maximum removal of the copper ion by tea waste at optimum condition (pH 7, 60 min. contact time, 0.8 g adsorbent dose and 0.7 M concentration) is 74%. The adsorbent prepared from tea waste is efficient and it can be conveniently employed as a low-cost alternative in the treatment of wastewater for heavy metal removal.


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