Partitioning and transformation behavior of arsenic during Fe(III)-As(III)-As(V)-SO42− coprecipitation and subsequent aging process in acidic solutions: Implication for arsenic mobility and fixation

Author(s):  
Xu Ma ◽  
Jiaxi Zhang ◽  
Mario A. Gomez ◽  
Yu Ding ◽  
Shuhua Yao ◽  
...  
2000 ◽  
Vol 15 (7) ◽  
pp. 1496-1504 ◽  
Author(s):  
V. A. Chernenko ◽  
E. Cesari ◽  
J. Pons ◽  
C. Seguí

Structural and ferromagnetic transitions in shape memory Ni–Mn–Ga alloys and their martensitic structure and microstructure were found to be strongly influenced by rapid quenching from the liquid state and by subsequent aging. Detailed calorimetric and magnetic measurements, dynamic mechanical analysis, and transmission electron microscopy observations were performed to characterize the transformation behavior of thin ribbons compared to the bulk materials. The rapid quenching caused the decrease of the ferromagnetic, martensitic, and premartensitic transformation temperatures, as well as of the saturation magnetization, while the subsequent annealing brought about an increase of the depressed values. This influence was attributed to quenched-in short-range chemical disorder within sublattices, the ordering being improved by a vacancy migration mechanism upon subsequent annealing.


2014 ◽  
Vol 794-796 ◽  
pp. 704-709
Author(s):  
Li Rong ◽  
Liu Qiu Lin ◽  
Xiao Lan Wu ◽  
B.L. Li ◽  
S.P. Wen ◽  
...  

Our former experimental study showed that the addition of Er to Al-Zn-Mg alloys speeded up the aging precipitation, accelerated the precipitation of and enhanced the effect of aging strengthening distinctively. In this paper, the Monte Carlo method was applied to simulate the microstructural evolution of Al-2.6Zn-(2.3Mg)-(0.07Er), Al-2.6Zn-2.3Mg-(0.12Er), and Al-2.6Zn-2.3Mg-0.1(Er,Zr) alloys during aging. The effects of Er addition to Al-Zn-Mg alloys on the clustering of Zn and Mg atoms are studied through analysis of the simulation results and the effects on the subsequent aging process are discussed as well. The results show that the Zn/Mg/Er clusters appear beside the Zn clusters, Mg clusters and Zn/Mg clusters in the Er addition Al-Zn-Mg alloys. The Zn clusters and Zn/Mg clusters are finer in the Al-2.6Zn-2.3Mg-xEr alloys than that in the Al-2.6Zn-2.3Mg alloys without Er addition. The size of the Zn clusters and Zn/Mg clusters in the Al-2.6Zn-2.3Mg-0.07Er is eight percent and nineteen percent smaller than that in the Al-2.6Zn-2.3Mg alloys without Er addition respectively. This precipitation refinement effect of Er addition to the Al-2.6Zn-2.3Mg alloys is enhanced with the increment of Er content. These above results are consistent with the experimental results that the precipitation in the Al-Zn-Mg alloys with Er is finer and denser than that in the Al-Zn-Mg alloys without Er. The Er addition changes the clusters distribution in the Al-Zn-Mg alloys by its interaction with the main solute atoms and the vacancy, and thus influences the precipitations during subsequent aging processing.


Metals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1274
Author(s):  
Ricardo Carabes ◽  
Héctor Carreón ◽  
Maria L. Carreon ◽  
Melchor Salazar ◽  
Pedro Hernández

The article reports a study carried out on metallic samples extracted from a metallurgically bonded clad pipe (API 5L X65 steel-Inconel 825 alloy) subjected to a solution heat treatment at 1200 °C and a subsequent aging treatment at 650 °C for different times in order to promote microstructural changes in thermo-metallurgical bonded materials. The non-destructive thermoelectric potential (TEP) technique was used to monitor microstructure changes due to the artificial aging process. In addition, micro-hardness tests were carried out on the metallic materials and micrographs were obtained by means of an optical and scanning electron microscope (SEM). The TEP value changed with solution treatment temperature and reached a maximum value for solution treatment at 1200 °C. The changes in TEP during solution treatment were caused by changes in the solubility of the alloying elements. In the artificial aging process, the TEP value decreased with increasing aging time due to the precipitation process, but exhibited distinct characteristics for the different zones at the clad pipe samples.


2020 ◽  
Vol 321 ◽  
pp. 12006
Author(s):  
Elango Chandiran ◽  
Goro Miyamoto ◽  
Tadashi Furuhara

The microstructure evolution during solution treatment at (alpha+beta) two phase region and subsequent aging process at 620 ˚C, after compressing the specimen in beta structure to different strain (0-70%) followed by cooling to room temperature has been investigated. Deformation strain hardly affects the total volume fraction of alpha phase after the solution treatment and aging process. On the other hand, with an increase in deformation strain, the volume fraction of the primary alpha phase increased although secondary alpha phase decreased, during the aging process, scuhdecrease in secondary alpha phase volume fraction results in a decrease in the strength. The loss of coherency of alpha/beta interphase boundaries at higher deformation strain promoted by dynamic recovery increases the interfacial mobility; which results in faster growth of primary alpha, thereby decreases secondary alpha precipitation.


Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2283 ◽  
Author(s):  
Haoyu Zhang ◽  
Chuan Wang ◽  
Siqian Zhang ◽  
Ge Zhou ◽  
Lijia Chen

Evolution of secondary α phase during aging treatment of a novel near β titanium alloy Ti-6Mo-5V-3Al-2Fe(wt.%) was studied by OM, SEM, and TEM. Results indicated that size and distribution of secondary α phase were strongly affected by aging temperature and time. Athermal ω phase formed after super-transus solution treatment followed by water quenching, and promoted nucleation of needle-like intragranular α in subsequent aging process. When aged at 480 °C, fine scaled intragranular α with small inter-particle spacing precipitated within β grains and high ultimate tensile strength above 1500 MPa was achieved. When the aging temperature increased, the size and inter-particle spacing of intragranular α increased and made the strength reduce, but the ductility got improved. When aging temperature reached as high as 600 °C, ω phase disappeared and intragranular α coarsened obviously, resulting in serious decrease of strength. While mutually parallel Widmanstätten α laths formed at the vicinity of β grain boundaries and grew into the internal area of β grains, and significant improvement of ductility was achieved. As the aging time increased from 4 h to 16 h at 600 °C, the intragranular α grew slightly and brought about minor change of mechanical properties.


Author(s):  
Ettore Anelli ◽  
Marco Tivelli ◽  
Alfonzo Izquierdo ◽  
Hector Quintanilla

In this work, major efforts were devoted to a full understanding of the effect of the plastic deformation pattern which is typical of reeling on the in-service mechanical performance of quenched and tempered (Q&T) seamless pipes. This was performed by both laboratory multiple plastic straining cycle (MPSC) tests and full-scale reeling (FSR) trials. Different steel grades were investigated with and without aging after single deformation and MPSC/FSR. All materials showed similar deformation behavior. In MPSC tests and FSR trials, the direction of the last deformation step influenced the mechanical behaviour. Finishing with compression gave a slight reduction in YS, whereas subsequent aging gave a YS value similar to that in the as-received condition. Leaving the last step in tension, an increase in YS was observed and subsequent aging gave a further increase to a level similar to that of conventional tensile straining plus artificial aging. In terms of toughness properties (CVN energy, 50%FATT, CTOD) there was no significant effect of reeling plus aging process. Also girth welds were tested: no significant effect of reeling plus aging process was pointed out with respect to the as-received situation for both HAZ and weld metal. The behavior of deformed and aged material was explained in terms of work-hardening, Bauschinger and bake-hardening effects.


GeroPsych ◽  
2015 ◽  
Vol 28 (2) ◽  
pp. 47-55 ◽  
Author(s):  
Eva-Marie Kessler ◽  
Catherine E. Bowen

Both psychotherapists and their clients have mental representations of old age and the aging process. In this conceptual review, we draw on available research from gerontology, social and developmental psychology, and communication science to consider how these “images of aging” may affect the psychotherapeutic process with older clients. On the basis of selected empirical findings we hypothesize that such images may affect the pathways to psychotherapy in later life, therapist-client communication, client performance on diagnostic tests as well as how therapists select and apply a therapeutic method. We posit that interventions to help both older clients and therapists to reflect on their own images of aging may increase the likelihood of successful treatment. We conclude by making suggestions for future research.


2004 ◽  
Vol 20 (4) ◽  
pp. 262-274 ◽  
Author(s):  
Manuel de Gracia Blanco ◽  
Josep Garre Olmo ◽  
María Marcó Arbonès ◽  
Pilar Monreal Bosch

Summary: Self-concept is a construct consisting of a group of specific self-perceptions that are hierarchically organized. Age-associated changes of self-concept are related to the individual's perception of the changes occurring throughout the aging process. The authors examined external validity and internal consistency of an instrument that has been developed to assess self-concept in older adults and examined self-concept's characteristics in two different contexts. Results confirm the multidimensionality of the scale and show a satisfactory external validity, indicating good discriminatory capacity. Findings support the hypothesis that older people who live in a nursing home have a poor self-esteem, self-concept, and psychological well-being and have a greater presence of depressive symptoms than people who live in their own home.


2013 ◽  
Author(s):  
Li Qu ◽  
Joel Jia Wei Low ◽  
Chengcheng Jiang ◽  
Qiao Dai ◽  
Ting Zhang ◽  
...  

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