Quantitative 3D characterization of intermetallic phases in an Al–Mg industrial alloy by X-ray microtomography

2006 ◽  
Vol 55 (2) ◽  
pp. 123-126 ◽  
Author(s):  
E MAIRE ◽  
J GRENIER ◽  
D DANIEL ◽  
A BALDACCI ◽  
H KLOCKER ◽  
...  
Keyword(s):  
Intermetallic Phases ◽  
X Ray ◽  
Industrial Alloy

scholarly journals X-Ray Characterization of Intermetallic Phases in Al/Ni Multilayer System

2015 ◽  
Vol 8 ◽  
pp. 1150-1159 ◽  
Author(s):  
Andrea Urrutia ◽  
Silvana Tumminello ◽  
Diego Germán Lamas ◽  
Silvana Sommadossi
Keyword(s):  
Intermetallic Phases ◽  
Multilayer System ◽  
X Ray

Characterization of the Convoluted 3D Intermetallic Phases in a Recycled Al Alloy by Synchrotron X-ray Tomography and Machine Learning

2021 ◽  
Author(s):  
Zhenhao Li ◽  
Ling Qin ◽  
Baisong Guo ◽  
Junping Yuan ◽  
Zhiguo Zhang ◽  
...  
Keyword(s):  
Machine Learning ◽  
Intermetallic Phases ◽  
Al Alloy ◽  
X Ray

Intermetallic phases in the magnesium-palladium system: x-ray absorption spectroscopic characterization of the amorphous magnesium-palladium-carbon-hydrogen alloy MgPdCxHy

1992 ◽  
Vol 4 (3) ◽  
pp. 620-625 ◽  
Author(s):  
Deborah J. Jones ◽  
Jacques Roziere ◽  
Lorraine E. Aleandri ◽  
Borisav Bogdanovic ◽  
Sara C. Huckett
Keyword(s):  
Spectroscopic Characterization ◽  
Intermetallic Phases ◽  
X Ray ◽  
X Ray Absorption

Microstructural Characterization of Nanostructured Al-Zn-Mg-Cu Alloy during Mechanical Alloying and Subsequent Annealing

2013 ◽  
Vol 829 ◽  
pp. 57-61 ◽  
Author(s):  
Mohammad Amin Shafei ◽  
Seyed Jamal Hosseinipour ◽  
Mohammad Rajabi
Keyword(s):  
Mechanical Alloying ◽  
Crystallite Size ◽  
Milling Time ◽  
Lattice Strain ◽  
Microstructural Characterization ◽  
Intermetallic Phases ◽  
Argon Atmosphere ◽  
X Ray ◽  
Cu Alloy

In this study, Al-6Zn-2.5Mg-1.5Cu alloy powders were synthesized by mechanical alloying of the elemental powders of Al, Zn, Mg and Cu at different milling times. The 60 h milled powders were isothermally annealed at 380 °C for 30 min under argon atmosphere. The microstructure and mechanical properties of the as-milled and annealed powders were characterized using X-ray diffractometry (XRD), scanning electron microscopy (SEM) and microhardness test. The crystallite size and lattice strain of Al were estimated from the broadening of XRD peaks using WilliamsonHall method. The results showed that the crystallite size of Al decreases with increasing milling time and after milling up to 60 h, the crystallite size reduced to 76 nm. Due to formation of intermetallic phases such as MgZn2 during annealing, an increase in the hardness of the alloy powders was achieved.

The Use of Advanced Analytical Techniques for Characterization of the Chemical, Physical, and Crystallographic Nature of a Surface

1973 ◽  
Vol 31 ◽  
pp. 132-133 ◽  
Author(s):  
R. E. Herfert
Keyword(s):  
Surface Characterization ◽  
Analytical Techniques ◽  
X Ray Diffraction ◽  
Depth Of Penetration ◽  
X Ray ◽  
The Past ◽  
Transmission Electron ◽  
Scanning Electron

Studies of the nature of a surface, either metallic or nonmetallic, in the past, have been limited to the instrumentation available for these measurements. In the past, optical microscopy, replica transmission electron microscopy, electron or X-ray diffraction and optical or X-ray spectroscopy have provided the means of surface characterization. Actually, some of these techniques are not purely surface; the depth of penetration may be a few thousands of an inch. Within the last five years, instrumentation has been made available which now makes it practical for use to study the outer few 100A of layers and characterize it completely from a chemical, physical, and crystallographic standpoint. The scanning electron microscope (SEM) provides a means of viewing the surface of a material in situ to magnifications as high as 250,000X.

High Resolution Replication of Organoclay Surfaces

1982 ◽  
Vol 40 ◽  
pp. 576-577
Author(s):  
W. W. Barker ◽  
W. E. Rigsby ◽  
V. J. Hurst ◽  
W. J. Humphreys
Keyword(s):  
Clay Mineral ◽  
Organic Molecule ◽  
Organic Molecules ◽  
X Ray Diffraction ◽  
Xrd Pattern ◽  
X Ray ◽  
Naturally Occurring ◽  
Silicate Layers ◽  
Mineral Identification

Experimental clay mineral-organic molecule complexes long have been known and some of them have been extensively studied by X-ray diffraction methods. The organic molecules are adsorbed onto the surfaces of the clay minerals, or intercalated between the silicate layers. Natural organo-clays also are widely recognized but generally have not been well characterized. Widely used techniques for clay mineral identification involve treatment of the sample with H2 O2 or other oxidant to destroy any associated organics. This generally simplifies and intensifies the XRD pattern of the clay residue, but helps little with the characterization of the original organoclay. Adequate techniques for the direct observation of synthetic and naturally occurring organoclays are yet to be developed.

Digital x-ray mapping of nanometer-size supported bimetallic catalysts

1988 ◽  
Vol 46 ◽  
pp. 530-531
Author(s):  
L. T. Germinario
Keyword(s):  
Background Radiation ◽  
Metal Cluster ◽  
Single Element ◽  
Beam Diameter ◽  
X Rays ◽  
X Ray ◽  
Major Interest ◽  
Induced Changes

Understanding the role of metal cluster composition in determining catalytic selectivity and activity is of major interest in heterogeneous catalysis. The electron microscope is well established as a powerful tool for ultrastructural and compositional characterization of support and catalyst. Because the spatial resolution of x-ray microanalysis is defined by the smallest beam diameter into which the required number of electrons can be focused, the dedicated STEM with FEG is the instrument of choice. The main sources of errors in energy dispersive x-ray analysis (EDS) are: (1) beam-induced changes in specimen composition, (2) specimen drift, (3) instrumental factors which produce background radiation, and (4) basic statistical limitations which result in the detection of a finite number of x-ray photons. Digital beam techniques have been described for supported single-element metal clusters with spatial resolutions of about 10 nm. However, the detection of spurious characteristic x-rays away from catalyst particles produced images requiring several image processing steps.

Plant Pathology Diagnosed by X-Ray Microanalysis

1987 ◽  
Vol 45 ◽  
pp. 974-975
Author(s):  
J. H. Resau ◽  
N. Howell ◽  
S. H. Chang
Keyword(s):  
Electron Microscopy ◽  
Plant Pathology ◽  
Biochemical Characterization ◽  
Nutrient Deficiency ◽  
Green Leaf ◽  
Parasitic Infestation ◽  
X Ray

Spinach grown in Texas developed “yellow spotting” on the peripheral portions of the leaves. The exact cause of the discoloration could not be determined as there was no evidence of viral or parasitic infestation of the plants and biochemical characterization of the plants did not indicate any significant differences between the yellow and green leaf portions of the spinach. The present study was undertaken using electron microscopy (EM) to determine if a micro-nutrient deficiency was the cause for the discoloration.Green leaf spinach was collected from the field and sent by express mail to the EM laboratory. The yellow and equivalent green portions of the leaves were isolated and dried in a Denton evaporator at 10-5 Torr for 24 hrs. The leaf specimens were then examined using a JEOL 100 CX analytical microscope. TEM specimens were prepared according to the methods of Trump et al.

EXELFS Studies of Carbon Fibers

1990 ◽  
Vol 48 (2) ◽  
pp. 72-73
Author(s):  
V. Serin ◽  
K. Hssein ◽  
G. Zanchi ◽  
J. Sévely
Keyword(s):  
Carbon Fibers ◽  
Energy Analysis ◽  
Electron Excitation ◽  
Complex Structures ◽  
High Modulus ◽  
Promising Technique ◽  
X Ray ◽  
Fine Structures ◽  
X Ray Absorption

The present developments of electron energy analysis in the microscopes by E.E.L.S. allow an accurate recording of the spectra and of their different complex structures associated with the inner shell electron excitation by the incident electrons (1). Among these structures, the Extended Energy Loss Fine Structures (EXELFS) are of particular interest. They are equivalent to the well known EXAFS oscillations in X-ray absorption spectroscopy. Due to the EELS characteristic, the Fourier analysis of EXELFS oscillations appears as a promising technique for the characterization of composite materials, the major constituents of which are low Z elements. Using EXELFS, we have developed a microstructural study of carbon fibers. This analysis concerns the carbon K edge, which appears in the spectra at 285 eV. The purpose of the paper is to compare the local short range order, determined by this way in the case of Courtauld HTS and P100 ex-polyacrylonitrile carbon fibers, which are high tensile strength (HTS) and high modulus (HM) fibers respectively.

Characterization of defects in tabular silver halide grains

1990 ◽  
Vol 48 (4) ◽  
pp. 1046-1047
Author(s):  
C. Goessens ◽  
D. Schryvers ◽  
J. Van Landuyt ◽  
A. Verbeeck ◽  
R. De Keyzer
Keyword(s):  
Radiation Damage ◽  
Silver Halide ◽  
Chemical Characteristics ◽  
X Ray ◽  
Free Region ◽  
Central Defect ◽  
Crystallographic Defects ◽  
Physical And Chemical ◽  
Two Sides

Silver halide grains (AgX, X=Cl,Br,I) are commonly recognized as important entities in photographic applications. Depending on the preparation specifications one can grow cubic, octahedral, tabular a.o. morphologies, each with its own physical and chemical characteristics. In the present study crystallographic defects introduced by the mixing of 5-20% iodide in a growing AgBr tabular grain are investigated. X-ray diffractometry reveals the existence of a homogeneous Ag(Br1-xIx) region, expected to be formed around the AgBr kernel. In fig. 1 a two-beam BF image, taken at T≈100 K to diminish radiation damage, of a triangular tabular grain is presented, clearly showing defect contrast fringes along four of the six directions; the remaining two sides show similar contrast under relevant diffraction conditions. The width of the central defect free region corresponds with the pure AgBr kernel grown before the mixing with I. The thickness of a given grain lies between 0.15 and 0.3 μm: as indicated in fig. 2 triangular (resp. hexagonal) grains exhibit an uneven (resp. even) number of twin interfaces (i.e., between + and - twin variants) parallel with the (111) surfaces. The thickness of the grains and the existence of the twin variants was confirmed from CTEM images of perpendicular cuts.

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