Electrochemical oxidative desulfurization for high sulfur content crude gas-oil

2020 ◽  
Vol 248 ◽  
pp. 117117
Author(s):  
Yadollah Tavan ◽  
Mohammad Shahrokhi ◽  
Fatola Farhadi
Keyword(s):  
Sulfur Content ◽  
Oxidative Desulfurization ◽  
Gas Oil ◽  
High Sulfur Content

scholarly journals Oxidative Desulfurization of Heavy Oils with High Sulfur Content: A Review

Catalysts ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 344 ◽  
Author(s):  
Sara Houda ◽  
Christine Lancelot ◽  
Pascal Blanchard ◽  
Line Poinel ◽  
Carole Lamonier
Keyword(s):  
Sulfur Content ◽  
Fossil Fuels ◽  
Oxidative Desulfurization ◽  
High Viscosity ◽  
Heavy Oils ◽  
Transportation Fuels ◽  
High Sulfur Content ◽  
Recent Developments ◽  
Ultrasound Technology ◽  
Hydrodesulfurization Process

The demand for clean fuels is increasing throughout the world, with more stringent environmental regulations for transportation fuels including marine fuels, particularly regarding their sulfur content. Moreover, the quality of crude oil and derived petroleum cuts is getting lower while fossil fuels are still in high demand. Heavy oils are characterized by high sulfur content where most sulfur is found in bulky thiophenic structures difficult to remove using conventional high pressure hydrodesulfurization process. However they appeared more reactive in oxidative desulfurization (ODS) process, carried out at mild conditions without hydrogen pressure. This review focuses for the first time on the heavy fuels initially containing more than 0.5 wt.%S and upgraded by the ODS process. Different attractive approaches of the literature towards ODS are reported using homogeneous and heterogeneous catalysis. Recent developments in ODS assisted with ultrasound technology and the use of ionic liquid to enhance ODS efficiency will be fully detailed and discussed to better understand their viability when applied to high sulfur content, high viscosity, and high boiling point feeds.

A novel graphene oxide-wrapped sulfur composites cathode with ultra-high sulfur content for lithium–sulfur battery

2019 ◽  
Vol 493 ◽  
pp. 533-540 ◽  
Author(s):  
Johnny Muya Chabu ◽  
Ke Zeng ◽  
Wansong Chen ◽  
Abdulhadi Mustapha ◽  
Yajuan Li ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Sulfur Content ◽  
Lithium Sulfur Battery ◽  
High Sulfur Content ◽  
Sulfur Battery ◽  
Lithium Sulfur

Ultrasound-Assisted Oxidative Desulfurization of Diesel Fuel in H2O2/Heteropoly Acid/Solvent System

2014 ◽  
Vol 1033-1034 ◽  
pp. 85-89 ◽  
Author(s):  
Guo Xian Yu ◽  
Qian Zhong ◽  
Mei Jin ◽  
Ping Lu
Keyword(s):  
Sulfur Content ◽  
Ultrasonic Irradiation ◽  
Diesel Fuel ◽  
Oxidation Reaction ◽  
Heteropoly Acid ◽  
Oxidative Desulfurization ◽  
Solvent System ◽  
Oxidative Reaction ◽  
Solvent Systems ◽  
Ultrasound Assisted

Ultrasound-assisted oxidative desulfurization (UAODS) of diesel fuel in H2O2/Heteropoly acid/Solvent systems, was investigated. Effects of solvent, catalyst, ultrasound and reaction temperature on the oxidation desulfurization of diesel fuel were investigated. When MPA/oil was 2%wt, methanol/diesel fuel was 20%wt, ultrasound power was 400 W and ultrasound time was 10 min, the sulfur content of diesel fuel was decreased from 211 ppm to 19 ppm. The use of ultrasonic irradiation in H2O2/Heteropoly acid/Solvent system significantly improved the efficiency of the oxidation reaction, and solvent was helpful to make the oxidative reaction happen in the same one phase.

Efficient Oxidative Desulfurization (ODS) of Commercial Diesel with TBHP under Mild Conditions Catalyzed by Polymolybdates Supported on Al2O3

2015 ◽  
Vol 1107 ◽  
pp. 341-346
Author(s):  
Wan Nazwanie Wan Abdullah ◽  
Rusmidah Ali ◽  
Wan Azelee Wan Abu Bakar
Keyword(s):  
Sulfur Content ◽  
Research Work ◽  
Sulfur Removal ◽  
Oxidative Desulfurization ◽  
Catalyst System ◽  
Impregnation Method ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Alternative Method ◽  
Tert Butyl Hydroperoxide

Due to the low specifications for sulfur content in diesel, a lot of research work are been conducted to develop alternative method for desulfurization. Catalytic oxidative desulfurization (Cat-ODS) has been found to be an alternative method to replace a conventional method which is hydrodesulfurization.New catalyst formulation using tert-butyl hydroperoxide polymolybdate based catalyst system was investigated in this research utilizing tert-butyl hydroperoxide (TBHP) as oxidant and dimethylformamide (DMF) as solvent for extraction. A series of polymolybdate supported alumina catalysts were prepared using wet impregnation method, ageing at ambient room temperature for 24 hours and followed by calcination process. A commercial diesel with 440 ppmw of total sulfur was employed to evaluate the elimination of sulfur compounds. Besides, the percentage of sulfur removal was measured by gas chromatography-flame photometric detector (GC-FPD). The sulfur content in commercial diesel was successfully reduced from 440 ppmw to 35 ppmw under mild condition followed by solvent extraction. From catalytic testing, Mo-Al2O3 calcined at 500°C was revealed as the most potential catalyst which gave 92% of sulfur removal.

scholarly journals Oxidative Desulfurization of Tire Pyrolysis Oil over Molybdenum Heteropolyacid Loaded Mesoporous Catalysts

Reactions ◽  
2021 ◽  
Vol 2 (4) ◽  
pp. 457-472
Author(s):  
Jasmine Kaur ◽  
Sundaramurthy Vedachalam ◽  
Philip Boahene ◽  
Ajay K. Dalai
Keyword(s):  
Sulfur Content ◽  
Photoelectron Spectroscopy ◽  
Supported Catalysts ◽  
Surface Acidity ◽  
Oxidative Desulfurization ◽  
Acid Catalyst ◽  
Acid Sites ◽  
Process Conditions ◽  
Pyrolysis Oil ◽  
X Ray

Pyrolysis oil derived from waste tires consists of sulfur content in the range of 7000 to 9000 ppm. For use in diesel engines, its sulfur content must be lowered to 10 to 15 ppm. Though conventional hydrodesulfurization is suitable for the removal of sulfur from tire pyrolysis oil, its high cost provides an avenue for alternative desulfurization technologies to be explored. In this study, oxidative desulfurization (ODS), a low-cost technology, was explored for the desulfurization of tire pyrolysis oil. Two categories of titanium-incorporated mesoporous supports with 20 wt% loaded heteropoly molybdic acid catalyst (HPMo/Ti-Al2O3 and HPMo/Ti-TUD-1) were developed and tested for ODS of tire pyrolysis oil at mild process conditions. Catalysts were characterized by X-ray diffraction, BET-N2 physisorption, and X-ray photoelectron spectroscopy (XPS). The incorporation of Ti into Al2O3 and TUD-1 frameworks was confirmed by XPS. The surface acidity of catalysts was studied by the temperature-programmed desorption of NH3 and pyridine FTIR analyses. HPMo/Ti-Al2O3 and HPMo/Ti-TUD-1 catalysts contained both Lewis and Brønsted acid sites. The presence of titanium in catalysts was found to promote the ODS activity of phosphomolybdic acid. The Ti-TUD-1-supported catalysts performed better than the Ti-Al2O3-supported catalysts for the ODS of tire pyrolysis oil. Hydrogen peroxide and cumene peroxide were found to be better oxidants than tert-butyl hydroperoxide for oxidizing sulfur compounds of tire pyrolysis oil. Process parameter optimization by the design of experiments was conducted with an optimal catalyst along with the catalyst regeneration study. An ANOVA statistical analysis demonstrated that the oxidant/sulfur and catalyst/oil ratios were more significant than the reaction temperature for the ODS of tire pyrolysis oil. It followed the pseudo-first-order kinetics over HPMo/Ti-TUD-1.

scholarly journals High sulfur content polymers: The effect of crosslinker structure on inverse vulcanization

2018 ◽  
Vol 56 (16) ◽  
pp. 1777-1781 ◽  
Author(s):  
Jessica A. Smith ◽  
Xiaofeng Wu ◽  
Neil G. Berry ◽  
Tom Hasell
Keyword(s):  
Sulfur Content ◽  
High Sulfur Content

Study on the Segmental Pigging Process for the Wet Gas Gathering and Transportation Pipelines of the Puguang Gas Field

2021 ◽  
Author(s):  
Wu Liu ◽  
Jianfeng Shang ◽  
Hongsong Wang ◽  
Donghui Zhao ◽  
Yu Zou
Keyword(s):  
Sulfur Content ◽  
Slug Flow ◽  
Operating Parameter ◽  
Time Duration ◽  
Time Intervals ◽  
Gas Field ◽  
Wet Gas ◽  
High Sulfur Content ◽  
Puguang Gas Field

Abstract The gathering and transportation pipeline known as Line 1 of Puguang gas field havs the characteristics of wet gathering and transportation containing high sulfur content, large drops and effusion in low-lying areas. In the process of one pigging operation on the site, the surge volume provided by the No. 1 separator in the master gas gathering station was not effectively utilized and the time intervals for the neighboring pipeline sections were too long. In this paper, we designed several pigging proposals. OLGA was applied to analyze the operating parameter changes for the gathering and transportation pipeline Line 1, which finally determined a reasonable pigging sequence. We designed and selected the "critical pigging proposal", which the time duration for the pigging operation of the seven pipeline sections was decreased to 16.91h. Guided by the "critical pigging proposal", the downstream pipeline sections will be challenged by the risks of ice blockage. The ground eddy device was improved in the article, for the purpose of draining effusions in low-lying areas in the Puguang gas field and controlling the slug flow. In addition, the application effects of the device were analyzed.

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