DBP formation kinetics in a simulated distribution system

2001 ◽  
Vol 35 (14) ◽  
pp. 3483-3489 ◽  
Author(s):  
Lewis A Rossman ◽  
Richard A Brown ◽  
Philip C Singer ◽  
John R Nuckols
2015 ◽  
Vol 15 (6) ◽  
pp. 1200-1206
Author(s):  
Hsien-chun Ke ◽  
Hsin-hsin Tung

Chloramine has often been used as a chlorine alternative for trihalomethane (THM) and haloacetic acid (HAA) control. However, nitrogenous disinfection byproduct (N-DBP) formation and nitrification in distribution have always been major concerns in chloramination practices. On Kinmen Island, the high organic nitrogen content in raw water may increase the nitrogenous DBP formation. Simulated distribution system tests were conducted to explore the DBP formation kinetics in the distribution system. Lower haloacetonitrile (HAN4) formation (0.26 μg L−1) with chloramination than with chlorination (10.48 μg L−1) was observed from the 24 hours of reaction time. The nitrogen sources contributing to the dichloroacetonitrile (DCAN) formation kinetics were explored with 15N-chloramination. The results showed that nitrogen sourced from organic nitrogen was more dominant in DCAN formation with low chloramine dosage. This suggests that chloramine contributes to less DCAN formation in practice, especially for short distribution systems. In summary, the results provide evidence that simultaneous post-chloramination and pre-chlorination would be a feasible disinfection strategy applied to control regulated THM and HAA formation on Kinmen Island.


2017 ◽  
Vol 15 (6) ◽  
pp. 942-954 ◽  
Author(s):  
Parul Gulati ◽  
Moushumi Ghosh

Sphingomonas paucimobilis, an oligotroph, is well recognized for its potential for biofilm formation. The present study explored the biofilm forming ability of a strain isolated from municipal drinking water on plumbing materials. The intensity of biofilm formation of this strain on different plumbing materials was examined by using 1 × 1 cm2 pieces of six different pipe materials, i.e. polyvinyl chloride (PVC), polypropylene (PP), polyethylene (PE), aluminium (Al), copper (Cu) and rubber (R) and observing by staining with the chemical chromophore, Calcofluor. To understand whether biofilm formation occurs under flow through conditions, a laboratory-scale simulated distribution system, comprised of the above materials was fabricated. Biofilm samples were collected from the designed system at different biofilm ages (10, 40 and 90 hours old) and enumerated. The results indicated that the biofilm formation occurred on all plumbing materials with Cu and R as exceptions. The intensity of biofilm formation was found to be maximum on PVC followed by PP and PE. We also demonstrated the chemical chromophore (Calcofluor) successfully for rapid and easy visual detection of biofilms, validated by scanning electron microscope (SEM) analysis of the plumbing materials. Chlorination has little effect in preventing biofilm development.


2019 ◽  
Vol 145 (4) ◽  
pp. 04019011
Author(s):  
Mongkolaya Rungvetvuthivitaya ◽  
Rengao Song ◽  
Mark Campbell ◽  
Eric Zhu ◽  
Tian C. Zhang ◽  
...  

1999 ◽  
Vol 40 (9) ◽  
pp. 249-256 ◽  
Author(s):  
R. Vahala ◽  
V.-A. Långvik ◽  
R. Laukkanen

A pilot plant study in four parallel filter runs was performed in order to determine the effect of ozonation and two-step granular activated carbon (GAC) filtration on the removal of disinfection by-product (DBP) precursors. The results showed that ozonation significantly decreased the adsorbable organic halogens (AOX) (35%), simulated distribution system (SDS) AOX (37%) and SDS trihalomethanes (THM) (76%) from chemically treated and sand-filtered lake water, but did not decrease either short-term or the long-term chlorine demand. Biofiltration with exhausted GAC had a minor importance in the precursor removal (0-20%). The performance of adsorptive GAC filtration was strongly dependent on the age of the GAC filter bed, which was also seen as a strong correlation between the natural organic matter (NOM) measurements and DBP formation potential. Disinfection with chloramine produced lower THM, AOX, mutagenicity and MX (Z-3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone) levels compared to chlorine disinfection.


2019 ◽  
Vol 68 (6) ◽  
pp. 390-398 ◽  
Author(s):  
Sandhya Rao Poleneni ◽  
Enos C. Inniss

Abstract The Stage 2 Disinfectant and Disinfection By-Product (D/DBP) regulations of the United States force water utilities to be more concerned with their distributed water quality. Improved compliance requires understanding of reaction kinetics and wall effects of different distribution materials used on DBP formation. To validate results in a full-scale system, effect of different materials, wall effects, bulk reactions, and water movement is analyzed using simulated distribution system (SDS) tests, material specific simulated distribution system (MS-SDS) tests, pipe loop, and pipe section reactor (PSR); all built using materials from the city of Columbia, Missouri's distribution system. On average, the choice of polyvinyl chloride (PVC) and ductile iron can account for as much as 36% difference in trihalomethane (TTHM) formation and 60% difference in chlorine residual decay over time irrespective of the prediction model and operational strategy used. In the case of ductile iron, pipe effect (PE) is <1, which shows that in the ductile iron pipe systems there is a net loss of TTHM yield due to non-TTHM forming chlorine demand imposed by the pipe environment, whereas in PVC pipe, PE is >1. In PVC systems there is an overall increase in TTHM formation as a result of pipe wall surface reactions.


2017 ◽  
Vol 186 ◽  
pp. 186-192
Author(s):  
Chrysoula Sfynia ◽  
Tom Bond ◽  
Nafsika Ganidi ◽  
Rakesh Kanda ◽  
Michael R. Templeton

2010 ◽  
Vol 10 (6) ◽  
pp. 877-886 ◽  
Author(s):  
Junzhi Zhang ◽  
Wei An ◽  
Lanhe Song ◽  
Jianwei Yu ◽  
Yongjing Wang ◽  
...  

The formation potentials of five haloacetic acids (HAA5FP) in 13 surface water samples taken from eight cities from northeast to south China were evaluated using the simulated distribution system (SDS) chlorination method. These samples showed a wide range of HAA5FP levels (20 to 443 μg L−1). Four pre-oxidation methods were evaluated for their performance in enhancing HAA5FP removal from six water samples by coagulation. Pre-Cl2 and pre-KMnO4 were not effective. While pre-ClO2 showed some enhancing effects for all samples, pre-O3 exhibited markedly higher effects without producing perceptible oxidation by-products such as bromate and formaldehyde. An enhancement factor (EF) value of 13–17% was achieved at an ozone dose of 0.5 mg L−1 and the maximum EF values were 16–25% at an ozone dose of 1.5–2.0 mg O3 L−1 (0.3–0.7 mg O3/mg dissolved organic carbon (DOC)). A 3D contour plot was applied to interpret the effects of two independent variables (DOC and specific ultraviolet absorbance (SUVA254)) on the formation potential of HAA5 using a quadratic smoothing technique, and it was found that the enhancing effect on the removal of HAA5FP by pre-ozonation was attributed to the destruction of reactive sites of organic compound, which could be expressed by the changes of SUVA254.


2005 ◽  
Vol 97 (2) ◽  
pp. 69-81 ◽  
Author(s):  
Hèléne Baribeau ◽  
Stuart W. Krasner ◽  
Russell Chinn ◽  
Philip C. Singer

2013 ◽  
Vol 13 (2) ◽  
pp. 447-461 ◽  
Author(s):  
C. Pluchon ◽  
J. B. Sérodes ◽  
C. Berthiaume ◽  
S. J. Charette ◽  
Y. Gilbert ◽  
...  

Haloacetic acids (HAAs) are disinfection by-products formed as a result of the reaction between chlorine and natural organic matter found in water. HAA concentrations have been observed to decrease at distribution system extremities. This decrease is associated with microbiological degradation by pipe wall biofilm. The objective of this study was to evaluate HAA degradation in a drinking water system in the presence of a biofilm and to identify the factors that influence this degradation. Degradation of dichloracetic acid (DCAA) and trichloroacetic acid (TCAA) was observed in a simulated distribution system. The results obtained showed that different parameters came into play simultaneously in the degradation of HAAs, including retention time, water temperature, biomass, composition of organic matter, and pipe diameter. Seasonal variations had a major effect on HAA degradation and biomass quantity was lower by 1 to 2 logs in the winter and spring compared with the fall. HAA removal decreased with increasingly large pipe diameters. The specific effects of each of these factors were difficult to isolate from each other owing to interactions.


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