RETRACTED: Fretting and galvanic corrosion behaviors and mechanisms of Co–Cr–Mo and Ti–6Al–4V alloys

Wear ◽  
2001 ◽  
Vol 249 (10-11) ◽  
pp. 883-891 ◽  
Author(s):  
Daxiong He ◽  
Tiancheng Zhang ◽  
Yinshun Wu
Metals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 3
Author(s):  
Huiling Zhou ◽  
Fanglian Fu ◽  
Zhixin Dai ◽  
Yanxin Qiao ◽  
Jian Chen ◽  
...  

The 6061-T6 aluminum alloy welding joints were fabricated using gas metal arc welding (GMAW) of various laser powers, and the effect of laser power on the microstructure evolution of the welding joints was investigated. The corrosion behaviors of 6061-T6 aluminum alloy welding joints were investigated in 3.5 wt% NaCl solution using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The results showed that the micro-galvanic corrosion initiation from Mg2Si or around the intermetallic particles (Al-Fe-Si) is observed after the immersion test due to the inhomogeneous nature of the microstructure. The preferential dissolution of the Mg2Si and Al-Fe-Si is believed to be the possible cause of pitting corrosion. When the laser power reached 5 kW, the microstructure of the welded joint mainly consisted of Al-Fe-Si rather than the Mg2Si at 2 kW. The relatively higher content of Al-Fe-Si with increasing in laser power would increase the volume of corrosion pits.


2013 ◽  
Vol 702 ◽  
pp. 140-144
Author(s):  
Ping An Shi ◽  
Hong Liang Zhou

The Uranium and Titanium corrosion rates are described by a Tafel’s relationship, and the cathodic protection of Uranium is a function of a Wagner number. A numerical simulation of galvanic corrosion of Uranium surface under thin layer electrolyte is presented. The model considered that the effect of a circular defect and oxygen reduction and corrosion in the Uranium surface, the effect of electrolyte thickness and conductivity and defect radius on corrosion current distribution of Uranium with is investigated. The results shows that the corrosion rate at the center is non-uniform, and it could lead to the formation of a hemispherical-shaped pit. And the effect of radius is to increase the importance of the electrode kinetics relative to ohmic resistance, and to increase the potential difference between the center and edge of the Uranium surface, resulting in non-uniform corrosion current distribution.


2014 ◽  
Vol 1033-1034 ◽  
pp. 829-833 ◽  
Author(s):  
Xiao Fei Yao ◽  
Wei Tian ◽  
Ling Wu

Electrochemical methods were employed to investigate galvanic corrosion behaviors of super13Cr and P110 couples in NaCl solution at different temperature. Corrosion morphologies and products of the couples were analyzed by SEM, EDS and XRD. The results showed that there were potential difference distinctly between super 13Cr and P110 steel in NaCl solution at different temperature, when its contacted, galvanic corrosion of super 13Cr-P110 steel couples will occurred. P110 was accelerated to corrode as anode and super 13Cr was protected as cathode in the coupling. Super 13Cr-P110 steel couples could not be used as P110 without any protection in NaCl solution at 20 °C to 80 °C. Corrosion current density and galvanic corrosion of super13Cr-P110 steel couples increased with increasing temperature in NaCl solution, of which corrosion products are Fe3O4.


2020 ◽  
Vol 58 (9) ◽  
pp. 610-616
Author(s):  
Jae-Won Lee ◽  
Se-Young Oh ◽  
Bora Park ◽  
Min-Suk Oh ◽  
Sung Jin Kim

To clearly understand the effect of the eutectic structure in the Zn-Al-Mg alloy coating on the corrosion behaviors in chloride containing aqueous environments, a bulk Zn-MgZn<sub>2</sub> sample was fabricated by diffusion bonding process, and a variety of experiments, such as electrochemical polarization and galvanic corrosion measurements, salt spray tests, and cyclic corrosion tests, were carried out. This study revealed that the corrosion potential values of MgZn<sub>2</sub> and Zn samples exposed to a 5 wt.% of NaCl solution were approximately -1.5 and -1 VSCE, respectively, and the MgZn<sub>2</sub> showed a higher corrosion current density than Zn at the early stage of corrosion. The continued dissolution of MgZn<sub>2</sub> phase from the eutectic structure in the coating layer provides not only sacrificial protection, but also environmental conditions for the co-formation of two types of corrosion products (simonkoleite (Zn<sub>5</sub>(OH)<sub>8</sub>Cl<sub>2</sub>·H<sub>2</sub>O) and hydrotalcite (ZnAl<sub>2</sub>(OH)<sub>6</sub>Cl<sub>2</sub>·H<sub>2</sub>O)) which have an inhibiting effect on the outer surface. The formation areas and kinetics of the two products on the coating surface were different, and they were greatly dependent upon the types of eutectic structures in the coating layer. Based on the results, a modified anti-corrosion mechanism of Zn-Al-Mg alloy coated steel sheet in chloride containing aqueous environment was proposed.


2012 ◽  
Vol 531-532 ◽  
pp. 220-225
Author(s):  
Zhen Pu ◽  
Qing Fu Wang ◽  
Mao Bin Shuai ◽  
Ding Mu Lang

Individual corrosion and galvanic corrosion behaviors of depleted uranium (DU) and 40Cr steel were investigated by electrochemical analyzing technologies in 3.5w.t%NaCl solution, including open circuit potential(OCP) test, linear polarization(LP) test, potentiodynamic polarizaition(PD) test, galvanic corrosion potential and corrosion current density test. The results reveal that the OCP of DU and 40Cr steel are around -790mV and -660mV, respectively. 40Cr has a higher linear polarization resistance than DU in galvanic corrosion. The dynamic processes of galvanic corrosion goes through an conversion in the whole test period. DU acts as anode with an accelerated corrosion rate, while the 40Cr steel behaves as cathode during the process of galvanic corrosion for DU/40Cr couple. The galvanic potential and current density of the DU/40Cr couple are -780mV and 17.5μA/cm-2, respectively.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Longfei Xie ◽  
Wenlong Zhou ◽  
Shiwen Zou ◽  
Xuesong Fu

Abstract This paper presents a research on the corrosion behavior of Ti-15-3 alloy overlapped with aluminized PVC film in salt spray. It was found that severe corrosion occurred on aluminized PVC film in the coupled regions because of crevice corrosion and/or galvanic corrosion whereas Ti-15-3 alloy in the coupled regions experienced minor corrosion. Scanning electron microscope and Energy-dispersive X-ray spectroscopy analyses demonstrated the corrosion products adhered to the surface of Ti-15-3 alloy within the crevice. To evaluate the effect of aluminized PVC film on the crevice corrosion of Ti-15-3 alloy in salt spray condition, it is necessary to compare with the corrosion resistance of Ti-15-3 overlapped with polytetrafluoroethylene (PTFE) in different neutral salt spray. Further, the tests were performed by electrochemical impedance spectroscopy and potentiodynamic polarization. Combining the graphical model, an in-depth understanding of the crevice and galvanic corrosion mechanism of Ti-15-3 alloy overlapped with aluminized PVC film has been revealed.


2018 ◽  
Vol 24 (1) ◽  
pp. 67-72 ◽  
Author(s):  
SeKwon Oh ◽  
YoungJun Kim ◽  
KiMin Jung ◽  
MiSeok Park ◽  
MinYoung Shon ◽  
...  

2013 ◽  
Vol 750-752 ◽  
pp. 467-472 ◽  
Author(s):  
Ling Wu ◽  
Fa Qin Xie ◽  
Xiao Fei Yao

Electrochemical method was employed to investigate galvanic corrosion behaviors of super13Cr and N80 couples in 5% NaCl solution at different temperature. Corrosion morphologies and products of the couples were analyzed by SEM, EDS and XRD. The results show that there existed distinct potential difference between super13Cr and N80 with different degree of corrosion in 5% NaCl solution at different temperature. N80 was accelerated to corrode as anode, however, super 13Cr was protected as cathode when their coupling. In order to avoid galvanic corrosion, the super 13Cr-N80 couples could not be used without any protection of N80 from 25°C to 80°C. Corrosion current density of the super13Cr-N80 couples increased with increasing temperature in 5% NaCl solution, as well as the more serious corrosion of N80, of which corrosion products are Fe3O4.


2007 ◽  
Vol 544-545 ◽  
pp. 359-362
Author(s):  
J.H. Hong ◽  
Seung Ho Ahn ◽  
Jung Gu Kim

Multilayered coatings of WC-Ti and WC-Ti1-xAlxN were deposited to form a wear- and corrosion-resistant surface. The cathodic arc deposition (CAD) method was used to deposit WC-Ti1- xAlxN coatings with variable Al content onto high speed steel (HSS). Three kinds of WC-Ti1-xAlxN coatings, each with and without interlayer (Ti/TiN), were prepared. The corrosion behaviors of WCTi1- xAlxN coatings in a deaerated 3.5% NaCl solution were investigated by galvanic corrosion test and potentiodynamic polarization test. The porosity of the coatings, both with and without interlayer, generally decreased with increasing Al content. The multilayer coating with a Ti/TiN interlayer was responsible for the increased corrosion resistance due to its lower porosity and higher adhesion strength than the multilayer coatings without interlayer.


2009 ◽  
Vol 16 (01) ◽  
pp. 43-47
Author(s):  
DA-QUAN ZHANG ◽  
YOUNG WOO PARK ◽  
KANG YONG LEE

This paper investigated the corrosion behaviors of the Nd: YAG laser-gas metal arc (GMA) AA5052-H32 weldments comparing with the base alloy. The corrosion susceptibility of weldments was higher than that of the base alloy. The weld fusion zone (WFZ) suffered the severe pitting in acidic chloride media. The zones adjacent to the weld fusion boundary showed less corrosion tendency. A corrosion cracking was associated with pitting in the weldments. The surface morphology observation and composition analysis were investigated by the scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) spectroscopy. At the WFZ/HAZ interface and the HAZ/base alloy interface, the galvanic corrosion coupling existed. From the comparison, the WFZ showed anodic behavior, the zone adjacent to the weld fusion boundary showed cathodic behavior. The corrosion of WFZ was progressed by the formation of the galvanic couples.


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