Determination of stages of thermal degradation of solid fuels according to thermogravimetric analysis data

2002 ◽  
Vol 43 (3) ◽  
pp. 165
2018 ◽  
Vol 37 (1) ◽  
pp. 544-557 ◽  
Author(s):  
Alejandra Saffe ◽  
Anabel Fernandez ◽  
Germán Mazza ◽  
Rosa Rodriguez

The use of energy from biomass is becoming more common worldwide. This energy source has several benefits that promote its acceptance; it is bio-renewable, non-toxic and biodegradable. To predict its behavior as a fuel during thermal treatment, its characterization is necessary. The experimental determination of ultimate analysis data requires special instrumentation, while proximate analysis data can be obtained easily by using common equipment but, the required time is high. In this work, a methodology is applied based on thermogravimetric analysis, curves deconvolution and empirical correlations for characterizing different regional agro-industrial wastes to determine the high heating value, the contents of moisture, volatiles matter, fixed carbon, ash, carbon, hydrogen, oxygen, lignin, cellulose and hemicellulose. The obtained results are similar to those using standard techniques, showing the accuracy of proposed method and its wide application range. This methodology allows to determine the main parameters required for industrial operation in only in one step, saving time.


2017 ◽  
Vol 68 (2) ◽  
pp. 317-322
Author(s):  
Anca Mihaela Mocanu ◽  
Constantin Luca ◽  
Alina Costina Luca

The purpose of this research is to synthetize, characterize and thermal degradation of new heterolytic derivates with potential biological properties. The derivates synthesis was done by obtaining new molecules with pyralozone structure which combine two pharmacophore entities: the amidosulfonyl-R1,R2 phenoxyacetil with the 3,5-dimethyl pyrazole which can have potential biological properties. The synthesis stages of the new products are presented as well as the elemental analysis data and IR, 1H-NMR spectral measurements made for elucidating the chemical structures and thermostability study which makes evident the temperature range proper for their use and storage. The obtained results were indicative of a good correlation of the structure with the thermal stability as estimated by means of the initial degradation temperatures as well as with the degradation mechanism by means of the TG-FTIR analysis.


2020 ◽  
Vol 70 (12) ◽  
pp. 4594-4600

The purpose of this study was to characterize some types of biomass wastes resulted from different activities such as: agriculture, forestry and food industry using thermogravimetric and ICP-MS analyses. Also, it was optimized an ICP-MS method for the determination of As, Cd and Pb from biomass ash samples. The ICP-MS analysis revealed that the highest concentration of metals (As, Cd, Pb) was recorded in the wood waste ash sample, also the thermogravimetric analysis indicated that the highest amount of ash was obtained for the same sample (26.82%). The biomass wastes mentioned in this study are alternative recyclable materials, reusable as pellets and briquettes. Keywords: ash, biomass, ICP-MS, minor elements, TG


Vaccines ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 211
Author(s):  
Anna Malkova ◽  
Dmitriy Kudlay ◽  
Igor Kudryavtsev ◽  
Anna Starshinova ◽  
Piotr Yablonskiy ◽  
...  

According to an analysis of published data, only 20% of patients with the new coronavirus infection develop severe life-threatening complications. Currently, there are no known biomarkers, the determination of which before the onset of the disease would allow assessing the likelihood of its severe course. The purpose of this literature review was to analyze possible genetic factors characterizing the immune response to the new coronavirus infection that could be associated with the expression of angiotension-converting enzyme 2 (ACE-2) and related proteins as predictors of severe Corona virus disease 2019 (COVID-19). We analyzed original articles published in Medline, PubMed and Scopus databases from December 2019 to November 2020. For searching articles, we used the following keywords: New coronavirus infection, Severe acute respiratory syndrome-related coronavirus 2 (SARS-CoV-2), COVID-19, severe course, complications, thrombosis, cytokine storm, ACE-2, biomarkers. In total, 3714 publications were selected using the keywords, of which 8 were in congruence with all the criteria. The literature analysis of the association of immunogenic characteristics and the expression of ACE-2 and related proteins with the development of severe COVID-19 revealed following genetic factors: HLA-B*46:01 genotype, CXCR6 gene hypoexpression, CCR9 gene expression, TLR7, rs150892504 mutations in the ERAP2 gene, overexpression of wild-type ACE-2, TMPRSS2 and its different polymorphisms. Genes, associated with the severe course, are more common among men. According to the analysis data, it can be assumed that there are population differences. However, the diagnostic significance of the markers described must be confirmed with additional clinical studies.


2016 ◽  
Vol 10 ◽  
pp. 00109 ◽  
Author(s):  
Robert Wróblewski ◽  
Bartosz Ceran

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