scholarly journals Solvo-osmotic flow in electrolytic mixtures

2017 ◽  
Vol 819 ◽  
Author(s):  
Sela Samin ◽  
René van Roij

We show that an electric field parallel to an electrically neutral surface can generate flow of electrolytic mixtures in small channels. We term this solvo-osmotic flow, since the flow is induced by the asymmetric preferential solvation of ions at the liquid–solid interface. The generated flow is comparable in magnitude to the ubiquitous electro-osmotic flow at charged surfaces, but for a fixed surface charge density, it differs qualitatively in its dependence on ionic strength. Solvo-osmotic flow can also be sensitively controlled with temperature. We derive a modified Helmholtz–Smoluchowski equation that accounts for these effects.

2019 ◽  
Vol 29 (12) ◽  
pp. 4895-4924
Author(s):  
Simona Di Fraia ◽  
P. Nithiarasu

Purpose This study aims at developing a comprehensive model for the analysis of electro-osmotic flow (EOF) through a fluid-saturated porous medium. To fully understand and exploit a number of applications, such a model for EOF through porous media is essential. Design/methodology/approach The proposed model is based on a generalised set of governing equations used for modelling flow through fluid saturated porous media. These equations are modified to incorporate appropriate modifications to represent electro-osmosis (EO). The model is solved through the finite element method (FEM). The validity of the proposed numerical model is demonstrated by comparing the numerical results of internal potential and velocity distribution with corresponding analytical expressions. The model introduced is also used to carry out a sensitivity analysis of the main parameters that control EOF. Findings The analysis carried out confirms that EO in free channels without porous obstruction is effective only at small scales, as largely discussed in the available literature. Using porous media makes EO independent of the channel scale. Indeed, as the channel size increases, the presence of the charged porous medium is essential to induce fluid flow. Moreover, results demonstrate that flow is significantly affected by the characteristics of the porous medium, such as particle size, and by the zeta potential acting on the charged surfaces. Originality/value To the best of the authors’ knowledge, a comprehensive FEM model, based on the generalised equations to simulate EOF in porous media, is proposed here for the first time.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ramin Zakeri

AbstractOne of the unresolved issues in physiology is how exactly myosin moves in a filament as the smallest responsible organ for contracting of a natural muscle. In this research, inspired by nature, a model is presented consisting of DPD (dissipative particle dynamics) particles driven by electro-osmotic flow (EOF) in micro channel that a thin movable impermeable polymer membrane has been attached across channel width, thus momentum of fluid can directly transfer to myosin stem. At the first, by validation of electro-osmotic flow in micro channel in different conditions with accuracy of less than 10 percentage error compared to analytical results, the DPD results have been developed to displacement of an impermeable polymer membrane in EOF. It has been shown that by the presence of electric field of 250 V/m and Zeta potential − 25 mV and the dimensionless ratio of the channel width to the thickness of the electric double layer or kH = 8, about 15% displacement in 8 s time will be obtained compared to channel width. The influential parameters on the displacement of the polymer membrane from DPD particles in EOF such as changes in electric field, ion concentration, zeta potential effect, polymer material and the amount of membrane elasticity have been investigated which in each cases, the radius of gyration and auto correlation velocity of different polymer membrane cases have been compared together. This simulation method in addition of probably helping understand natural myosin displacement mechanism, can be extended to design the contraction of an artificial muscle tissue close to nature.


Author(s):  
Mohammed Abdulhameed ◽  
Garba Tahiru Adamu ◽  
Gulibur Yakubu Dauda

In this paper, we construct transient electro-osmotic flow of Burgers’ fluid with Caputo fractional derivative in a micro-channel, where the Poisson–Boltzmann equation described the potential electric field applied along the length of the microchannel. The analytical solution for the component of the velocity profile was obtained, first by applying the Laplace transform combined with the classical method of partial differential equations and, second by applying Laplace transform combined with the finite Fourier sine transform. The exact solution for the component of the temperature was obtained by applying Laplace transform and finite Fourier sine transform. Further, due to the complexity of the derived models of the governing equations for both velocity and temperature, the inverse Laplace transform was obtained with the aid of numerical inversion formula based on Stehfest's algorithms with the help of MATHCAD software. The graphical representations showing the effects of the time, retardation time, electro-kinetic width, and fractional parameters on the velocity of the fluid flow and the effects of time and fractional parameters on the temperature distribution in the micro-channel were presented and analyzed. The results show that the applied electric field, electro-osmotic force, electro-kinetic width, and relaxation time play a vital role on the velocity distribution in the micro-channel. The fractional parameters can be used to regulate both the velocity and temperature in the micro-channel. The study could be used in the design of various biomedical lab-on-chip devices, which could be useful for biomedical diagnosis and analysis.


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