An unusual high-Mg garnet–spinel orthopyroxenite from southern India: evidence for ultrahigh-temperature metamorphism at high-pressure conditions

2006 ◽  
Vol 143 (6) ◽  
pp. 923-932 ◽  
Author(s):  
K. SAJEEV ◽  
M. SANTOSH

We report here a garnet–spinel orthopyroxenite in close association with an ultrahigh-temperature (UHT) granulite from the central part of the Madurai Granulite Block in southern India. The garnet–spinel orthopyroxenite is almost entirely composed of orthopyroxene, spinel and rare garnet in a granular texture. Spinels in the rock are characterized by high Mg (XMg = 0.69–0.71) with low Cr and Fe3+, consistent with compositions reported from spinels occurring within xenoliths in kimberlites and high pressure–temperature (P–T) Alpine complexes. The orthopyroxenes have high Al content (Al2O3 up to 4.85 wt%), typical of equilibration under high P–T conditions. The P–T estimates derived for the garnet–spinel orthopyroxenite indicate temperatures of around 1000°C and pressures exceeding 17 kbar. The data indicate that UHT metamorphism in this locality traversed from above 17 kbar to 11 kbar prior to the final stage of isothermal decompression. Our study reports the highest pressures obtained by far, for extreme crustal metamorphism in southern India and elsewhere in Gondwana. The multi-stage decompression observed in the UHT rocks associated with the high P–T garnet–spinel orthopyroxenite could be correlated to extension of the crust and possibly of the lithospheric mantle and/or its delamination, with the asthenospheric mantle as the ultimate heat source, during the final stage of amalgamation of the Gondwana supercontinent.

2009 ◽  
Vol 147 (1) ◽  
pp. 42-58 ◽  
Author(s):  
T. TSUNOGAE ◽  
M. SANTOSH

AbstractSapphirine-bearing Mg–Al granulites from Rajapalaiyam in the southern part of the Madurai Block provide critical evidence for Late Neoproterozoic–Cambrian ultrahigh-temperature (UHT) metamorphism in southern India. Poikiloblastic garnet in quartzo-feldspathic and pelitic granulites contain inclusions of fine-grained subidioblastic to xenoblastic sapphirine associated with quartz, suggesting that the rocks underwent T > 1000°C peak metamorphism. Quartz inclusions in spinel within garnet are also regarded as clear evidence for a UHT condition. Inclusions of orthopyroxene within porphyroblastic garnet in the sapphirine-bearing rocks show the highest Al2O3 content of up to 10.3 wt%, suggesting T = 1050–1070°C and P = 8.5–9.5 kbar. Temperatures estimated from ternary feldspar and other geothermometers (T = 950–1000°C) further support extreme thermal metamorphism in this region. Xenoblastic spinel inclusions in sapphirine coexisting with quartz suggest that the spinel + quartz assemblage pre-dates the sapphirine + quartz assemblage, probably implying a cooling from T ~ 1050°C or an anticlockwise P–T path. The FMAS reaction sapphirine + quartz + garnet → orthopyroxene + sillimanite indicates a cooling from the sapphirine + quartz stability field after the peak metamorphism. Corona textures of orthopyroxene + cordierite (± sapphirine), orthopyroxene + sapphirine + cordierite, and cordierite + spinel around garnet suggest subsequent near-isothermal decompression followed by decompressional cooling toward T = 650–750°C and P = 4.5–5.5 kbar. The sapphirine–quartz association and related textures described in this study have an important bearing on the UHT metamorphism and exhumation history of the Madurai Block, as well as on the tectonic evolution of the continental deep crust in southern India. Our study provides a typical example for extreme metamorphism associated with collisional tectonics during the Late Neoproterozoic–Cambrian assembly of the Gondwana supercontinent.


2008 ◽  
Vol 33 (5-6) ◽  
pp. 395-413 ◽  
Author(s):  
Toshiaki Tsunogae ◽  
M. Santosh ◽  
Hiroyuki Ohyama ◽  
Kei Sato

Proceedings ◽  
2020 ◽  
Vol 70 (1) ◽  
pp. 2
Author(s):  
Jolanta Małajowicz ◽  
Aleksandra Jedlińska ◽  
Katarzyna Samborska ◽  
Amr Edris

Microencapsulation is a technique that is increasingly used to encapsulate fragrances. It offers a valuable method to protect aromas against degradation in technological processes and during storage, which extends the usefulness of the aroma in the production and processing of food products. The aim of this research was to develop a microencapsulation method of gamma-decalactone, a cyclic ester with the scent of peach, which is used as a food additive. The carrier used for microencapsulation was an emulsion consisting of rapeseed oil, maltodextrin and gum Arabic. In this work, optimization of the carrier composition was performed in order to obtain a stable emulsion. The effect of inlet air temperature (80 °C, 180 °C) during spray drying on the powder quality parameters was then analyzed. In the final stage, the gamma-decalactone content in the obtained powders was evaluated. The results showed that emulsions based on colza oil and gum Arabic are a good carrier for the microencapsulation of gamma-decalactone. The use of high pressure during homogenization results in better fragmentation and homogenization of the emulsion. Drying at a higher inlet air temperature (180 °C) contributes to a more efficient microencapsulation process in that more aroma is encapsulated inside the capsules with less adhering to their surface.


2021 ◽  
Author(s):  
Ebikebena M. Ombe ◽  
Ernesto G. Gomez ◽  
Aldia Syamsudhuha ◽  
Abdullah M. AlKwiter

Abstract This paper discusses the successful deployment of Multi-stage Fracturing (MSF) completions, composed of novel expandable steel packers, in high pressure, high temperature (HP/HT) horizontal gas wells. The 5-7/8" horizontal sections of these wells were drilled in high pressure, high temperature gas bearing formations. There were also washed-outs & high "dog-legs" along their wellbores, due to constant geo-steering required to keep the laterals within the hydrocarbon bearing zones. These factors introduced challenges to deploying the conventional MSF completion in these laterals. Due to the delicate nature of their packer elastomers and their susceptibility to degradation at high temperature, these conventional MSF completions could not be run in such hostile down-hole conditions without the risk of damage or getting stuck off-bottom. This paper describes the deployment of a novel expandable steel packer MSF completion in these tough down-hole conditions. These expandable steel packers could overcome the challenges mentioned above due to the following unique features: High temperature durability. Enhanced ruggedness which gave them the ability to be rotated & reciprocated during without risk of damage. Reduced packer outer diameter (OD) of 5.500" as compared to the 5.625" OD of conventional elastomer MSF packers. Enhanced flexibility which enabled them to be deployed in wellbores with high dog-leg severity (DLS). With the ability to rotate & reciprocate them while running-in-hole (RIH), coupled with their higher annular clearance & tolerance of high temperature, the expandable steel packers were key to overcoming the risk of damaging or getting stuck with the MSF completion while RIH. Also, due to the higher setting pressure of the expandable steel packers when compared to conventional elastomer packers, there was a reduced risk of prematurely setting the packers if high circulating pressure were encountered during deployment. Another notable advantage of these expandable packers is that they provided an optimization opportunity to reduce the number of packers required in the MSF completion. In a conventional MSF completion, two elastomer packers are usually required to ensure optimum zonal isolation between each MSF stage. However, due to their superior sealing capability, only one expandable steel packer is required to ensure good inter-stage isolation. This greatly reduces the number of packers required in the MSF completion, thereby reducing its stiffness & ultimately reducing the probability of getting stuck while RIH. The results of using these expandable steel packers is the successful deployment of the MSF completions in these harsh down-hole conditions, elimination of non-productive time associated with stuck or damaged MSF completion as well as the safe & cost-effective completion in these critical horizontal gas wells.


1975 ◽  
Vol 27 (1) ◽  
pp. 111-121 ◽  
Author(s):  
A. Schauer ◽  
M. Roschy ◽  
W. Juergens

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